• Title/Summary/Keyword: Weathering environment

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Initial Stage of Atmospheric Corrosion of Carbon and Weathering Steels in Thailand Climate

  • Nii, K.;Bhamornsut, C.;Chotimongkol, L.;Vutivat, E.;Nakkhuntod, R.;Jeenkhajohn, P.;Suphonlai, S.
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.183-188
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    • 2003
  • Corrosion of carbon and weathering steels were evaluated under 3 environmental exposures in Thailand (urban, rural and marine) for a year. The seasonal study was designed to determine different corrosion mechanisms by 6 months of dry season and 6 months of rainy season in a year. The sheltered exposure racks were used to determine the washing effect of min. At each site, climatic and pollutants analyses were carried out. The present study showed that the difference in corrosion rates of carbon and weathering steels was not so distinguished in both rural (AIT) and urban (TISTR) environments. The corrosion rate of weathering steel was somewhat lower than that of carbon steel and the decreasing tendency of corrosion rate with time was slightly higher for weathering steel than for carbon steel. In marine (Rayong) environment, the corrosion rate was higher and the effect of wet and dry seasons was observed. The corrosion rate in 6 dry months was higher for direct exposure than for sheltered exposure. However, in 6 rainy months. the corrosion rate of sheltered exposure was higher than that of direct exposure. In direct exposure for I year, that is, the first 6 dry months and the next 6 rainy months, the corrosion rate decreased with time. but in sheltered exposure, the corrosion rate did not decrease with time. instead, increased in the next 6 rainy months. This indicated that the protect ive layer formed in the first 6 dry months could be destroyed by high deposition of chloride to r sheltered exposure in the next 6 rainy months; whereas the rust layer for direct exposure could be kept sound due to washing effect in rainy season, even though the deposition rate of chloride was almost the same for direct and sheltered exposures. In marine environment, the weathering steel showed higher corrosion resistance than carbon steel but its corrosion rate was higher than those in other environments.

Weathering Characteristics of Rock under Natural Environment and Strength Evaluation of Weathered Rock (자연환경하에서 암석의 풍화특성과 풍화암석의 강도평가)

  • Kang, Dae-Wan;Obara, Yuzo;Hirata, Atsuo;Kang, Seong-Seong
    • Tunnel and Underground Space
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    • v.21 no.6
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    • pp.460-470
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    • 2011
  • Wave velocity was measured to define the weathering characteristics of rock and the strength evaluation of weathered rock on a target of the Aso gravestones with various sizes under the natural environment. As a result, the size correction method which was changed sample of the different size to one of the same size for evaluating wave velocity was proposed, and also suggested the NET (Normalized Elapsed Time) as a new weathering index of rock. In addition, the strength of the weathered rock was estimated from the weathering classification of rock using the NET. Wave velocity of welded tuff was high and didn't show velocity degradation, on the other hand, one of andesite was low and showed velocity degradation. The degree of weathering between rocks of the different size is considered to be comparable, applying the NET based on the on the $V_p/V_o$-NET curve. Furthermore, the classification of rock weathering stages using the NET based on the $S_c/S_o$-NET curve was available, and the estimation of strength for the weathered rock was also possible.

Analysis of Rock Surface Roughness and Chemical Species Generation by Freeze-Thaw Experiments (동결융해 실험을 통한 암석 표면 거칠기 및 화학종 생성에 관한 분석)

  • Choi, Junghae
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.299-311
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    • 2022
  • Rocks exposed to the surface are subject to long-term weathering, and such effects weaken their engineering stability. Especially as weathering progresses, the surface of rocks will be changed by weathering, and such surface changes will affect the engineering safety of the rock mass. In addition, the chemical species produced in the weathered rock have a direct effect on the surrounding environment or on the structure. In areas where rocks are exposed, such as mining areas, chemical species produced by weathering can have a serious impact on the surrounding natural environment. In this study, accelerated weathering experiments using freeze/thaw system were conducted on rocks that had already been weathered and fresh rocks, and surface changes of each rock were observed with confocal laser scanning microscope (CLSM), and chemical species were analyzed using IC/ICP-MS. As the weathering progressed, the surface roughness decreased, and the amount of chemical species produced increased. The results of this study can be used as basic data for evaluating engineering/environmental safety in areas where rocks are exposed.

Effects of Evaporation on the Weathering Rate and Chemical Composition of Iranian Heavy Crude Oil (이란산 원유의 증발에 따른 풍화율 및 화학적 성상 변화)

  • Kim, Beom;Kim, Gi-Beum;Sim, Won-Joon;Yim, Un-Hyuk
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.3
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    • pp.238-246
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    • 2012
  • Once oil is spilled into marine environment, it experiences various weathering processes among which evaporation is the most dominant process in the initial stage of weathering. This study aimed to elucidate the effects of evaporation on the physicochemical properties of spilled oil using standardized laboratory experiments. Laboratory evaporation process was successfully reproduced using controlled rotary evaporation method. In case of Iranian Heavy crude (IHC), evaporation rate after 48 hours was $29.3{\pm}0.4%$ (n=40, p<0.001). Evaporation was simulated using ADIOS2 weathering model and the result was in agreement with laboratory experiment. Chemical composition changes of petroleum hydrocarbons including alkanes, polycyclic aromatic hydrocarbons (PAHs) and biomarkers by evaporation rate were also analyzed. As oil evaporated, low molecular weight alkanes and PAHs decreased, while biomakers showed conservative characteristics. Among biomarkers, $17{\alpha}(H)$, $21{\beta}(H)$-hopane was used for calculation of weathering rates, which matched with evaporative mass losses. Weathering rate calculation using hopane showed that stranded oils of weathering stage I (28.9%) and mesocosm oil weathering experiment till 5 days (26.5%) were mainly affected by evaporation process.

A Study on the Strength Degradation of Weathered Granite Soil by Freezing and Thawing (동결융해에 의한 화강풍화토의 강도저하에 관한 연구)

  • Kim, Yong-Soo;Jung, Soo-Jung
    • Journal of the Korean Geosynthetics Society
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    • v.6 no.3
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    • pp.1-7
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    • 2007
  • The property of weathered soil cannot but have a possibility of having a limit when its precise approaching due to the various weathering environment, and the peculiarity of its conduct affected by the weathering degree and effect factors. Especially most domestic or international researches are concentrated on the sedimentary soil, trying to analyze the mechanical behavior of weathered soil from the viewpoint of sedimentary soil. Therefore, it's difficult to judge if those results meet the actual conduct of weathered soil. This study suggested a way of weathering degree changing experiment as an early stage in an experiment of artificially changing weathering degree. In order to find out the property of strength change by the change of weathering degree, indoor mechanical experiment was made using soil sample after freezing and thawing. Under the weathering degree, characteristic change is watched by country rock and region of weathered granite soil.

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A Study on Corrosion Failure of a Weathering Steel Weldment with Various Applied Potentials in Acid-chloride Solution (산-염소이온 분위기의 인자전위에 따른 내후성강 용접부의 부식파괴에 관한 연구)

  • 최윤석;김정구;김종집;이병훈
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.97-105
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    • 2000
  • The stress corrosion cracking(SCC) and hydrogen embrittlement cracking(HEC) characteristics of a weathering steel weldment were investigated in aerated acid-chloride solution. The electrochemical properties of weldment were investigated by polarization test and galvanic corrosion test. Weathering steel did not show passive behavior in the acid-chloride solution. Galvanic corrosion between the weld metal and the base metal was not observed because the base metal was anodic to the weld metal. The slow-strain-rate tests(SSRT0 were conducted at a constant strain rate o 7.87×{TEX}$10^{-7}${/TEX}/s at corrosion potential, and at potentiostatically controlled anodic and cathodic potentials. The weldment of weathering steel was susceptible to both anodic dissolution SCC and hydrogen evolution HEC.

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통계분석을 이용한 소규모 유역내 하천수 수질과 지질과의 상관관계 해석

  • 고경석;김재곤;이진수;김용제;조춘희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.311-314
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    • 2004
  • To identify the effect of geology and land use, the hydrogeochemical and multivariate statitstical analysis were executed for stream water collected in headwater region of Daecheong reservoir. Hydrogeochemical analysis was showed the effect of weathering process such as dissolution of calc-silicate minerals to hydrochemistry of stream water with contrasting geology. Cluster and principal components analysis can also help to identify the source of dissolved components in stream water.

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Atmospheric Corrosion Process for Weathering Steel

  • Nagano, Hiroo;Yamashita, Masato
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.119-124
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    • 2008
  • Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.

Research of stone pagoda weathering degree from contaminated distribution analysis of 10-storied pagoda in the temple of Kyoungchunsa (경천사십층석탑의 오염물분포별 현황조사를 통한 석탑 풍화도에 관한 연구)

  • Kim, Jin-Hyoung;Lee, Joo-Wan;Kang, Dai-Ill
    • 보존과학연구
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    • s.25
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    • pp.75-92
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    • 2004
  • The conservation treatments of 10-storied pagoda in the temple of Kyoungchunsa is progressed favorably to come to the finish since 1995. Most of all, the important conservation treatments are stone crack, exfoliation and partial form modification. This pagoda has been made up a complicated structure constructed using 142 stones. Therefore, the stone crack and exfoliation have been occurred as very varied forms. Especially, the stylobate of the pagoda has 19 substitution stones of 48 stones, which is40% of modern stone substitution. It is supposed that there is serious weathering on the stones. The other stones, which are no substitution stones, have some kinds of weathering and so we carried out inside replenishment and partial outside reconstruction of crack stones using high molecular resin and substitution stone. The stone of each storey has also partial difference, but the condition of serious weathering on the whole. We can detect general degree through treatment of high molecule resin or distribution research of contaminated material on 10-storied pagoda in the temple of Kyoungchunsa. Especially, we are able to analyze general weathering degree and know details weathering of each storey or direction for the difference of replenishment quantity and different pattern of stone crack degree. Also, the distribution research will accomplish very important parts of examining environment effects and use as research data of cultural heritage conservation field.

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The Influence of Weathering Conditions on the Outer Membrane of Biogas with Plasticized PVC : A Study using Non-destructive Tests

  • Kim, Changhwan;Ki, Wootae;Kim, SangMyung;Shin, Jinyong
    • Journal of the Korean institute of surface engineering
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    • v.47 no.2
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    • pp.57-62
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    • 2014
  • The biogas holder is composed of an outer membrane and an inner membrane which are subject to outdoor exposure and gas exposure respectively. The influence of weathering conditions on the photo-degradation of a biogas holder was investigated. Tests were performed under three different methods - outdoor exposure tests (Seosan, Arizona), accelerated tests (Xenon-are lamp) with the outer-membrane of biogas. Moreover, the changes in the aging process were monitored using color difference, gloss, the contact angle and an optical microscope. Changes in physical properties, such as decrease reduction in gloss, decrease in the contact angle, increase in color difference were observed in the aging process. The comparison between membrane 3B, 4B and membrane 5B under xenon-arc were discussed. Membrane 5B was very sensitive to ultraviolet (UV) ray. There were many difficulties in the outdoor exposure test due to acid rain, dust, and stain resistance.