• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.211-211
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• 1999

Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

• Journal of Ecology and Environment
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• v.48 no.1
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• pp.17-23
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• 2024

Background: Honey bees play a crucial role in pollination and ecological balance. Apis mellifera L. colonies, especially those located in specific geographic regions, such as the palm garden in Eastern Thailand, are susceptible to potential threats from microbial contaminants. Understanding and detecting microbial organisms in these beehives is essential for the preservation of bee health, honey production, and the broader ecosystem. However, the problem of microbial infection and antibiotic-resistant bacteria is more severe and continuously increasing, resulting in a health, economic, and social crisis. The purpose of this study is to determine the prevalence of microorganisms in A. mellifera beehives in palm gardens in Rayong province, Eastern Thailand. Results: Ten swabs in transport media were swabbed and obtained from different parts of each beehive (1 swab per beehive), for a total of 10 hives. Traditional microbial culture-based methods, biochemical tests, and antimicrobial susceptibility (disc-diffusion) tests were used to detect microbial organisms and antibiotic resistance in bacteria. The swab tests from nine beehives resulted in the detection of Gram-positive bacteria (63.64%), Gram-negative bacteria (27.27%), and fungi/yeast (9.09%). These microorganisms are classified as a group of coagulase-negative Staphylococcus spp. and made up 40.91% of the bacteria discovered. Other bacteria found were Coryneform bacteria (13.64%), Pantoea spp. (13.64%), Bacillus spp. (9.09%), yeast (9.09%), glucose non-fermentative Gram-negative bacilli (9.09%), and Pseudomonas spp. (4.55%). However, due to the traditional culture-based and 0biochemical tests usually used to identify the microbial organisms in clinical specimens and the limitation of identifying some environmental microbial species, the results of the antimicrobial susceptibility test cannot reveal if the organism is resistant or susceptible to the drug. Nevertheless, drug-sensitive inhibition zones were formed with each antibiotic agent. Conclusions: Overall, the study supports prevention, healthcare, and public health systems. The contamination of microorganisms in the beehives may affect the quality of honey and other bee products or even the health of the beekeeper. To avoid this kind of contamination, it is therefore necessary to wear personal protective equipment while harvesting honey and other bee products.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.195-214
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• 2000

The high-speed steel (shorten as HSS) consists of Fe and several kinds of transition metal carbides. The cutting tools or wear-resistant materials made from HSS experience relatively high thermal shock because a coolant such as water or oil is flowed over the surface of heated HSS. The purpose of this research is to increase the hardness, strength, fracture toughness and thermal shock resistance of HSS. A possible strategy is to incorporate a hard ceramic material with high strength in HSS matrix. This paper describes the processing, microstructure and mechanical properties of the oriented unidirectional mullite fiber/HSS composite. The unidirectional mullite fibers of 10${\mu}{\textrm}{m}$ diameter were dispersed by the ultrasonic irradiation of 38 kHz in an ethylenglycol suspension containing HSS powder of 11${\mu}{\textrm}{m}$ median size. The dried green composites with 4-68 vol% fibers were hot-pressed for 2h at 100$0^{\circ}C$ in Ar atmosphere under a pressure of 39 MPa. The higher density was achieved in the composite with a lower content of fibers. The oriented unidirectional fibers were well dispersed in the HSS matrix. The average distance between the center of fibers in the cross section was close to the value calculated from the fiber fraction. No reaction occurred at the interfaces between HSS and mullite fibers in the composites. The composite with 13.6 vol% fibers showed 100 MPa of four point flexural strength at room temperature. The thermal expansion of composite with heating was influenced by the orientation of mullite fibers.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.12
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• pp.1267-1271
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• 2012

Demand for optical glass device used for lighting could increase rapidly because of LED lighting market growth. The optical glass devices that have been formed by hot press molding process the desired optical performance without being subjected to mechanical processing such as curve generation or grinding. EL-Max material has been used for many engineering applications because of their high wear resistance, high compressive strength, corrosion resistant and very good dimensional stability. EL-Max is very useful for a glass lens mold especially at high temperature and pressure. The performance and reliability of optical components are strongly influenced by the surface damage of EL-Max during grinding process. Therefore, the severe process condition optimization shall be necessary for the highly qualified EL-Max glass lens mold. To get the required qualified surface of EL-Max, the selection of type of the diamond wheel is also important. In this paper, we report best grinding conditions of ultra-precision grinding machining. The grinding machining results of the form accuracy and surface roughness have been analyzed by using Form Talysurf and NanoScan.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.231.1-231.1
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• 2015

Surface energy, being an important material parameter to control its interactions with the other surfaces plays a key role in bio-related application. Carbon films are found very promising due to their characteristics such as wear and corrosion resistant, high hardness, inert, low resistivity and biocompatibility. The present work deals with the deposition of carbon films using unbalanced facing target magnetron sputtering technique. The discharge characteristics were studied using optical emission spectroscopy and correlated with the film properties. Surface energy was investigated through contact angle measurement. The ID/IG ratio as calculated from Raman spectroscopy data increases with the increase in power density due to the higher number of sp2 clusters embedded in the amorphous matrix. The deposited films were smooth and homogeneous as observed by Atomic force microscopy having RMS roughness in the range of 1.74 to 2.25 nm. It is observed that electrical resistivity and surface energy varies in direct proportionality with operating pressure and has inverse relation with power density. The surface energy results clearly exhibited that these films can have promising applications in cell cultivation.

• Journal of the Korean Ceramic Society
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• v.35 no.9
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• pp.939-944
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• 1998

The formation microstructure and properties of novel ceramic composite materials by active filler con-trolled polymer pyrolysis were investigated. Polymethlsiloxane filled with W is of particular interested be-cause of the formation of ceramic bonded hard materials (WC-$W_{2}C$-$S_{1}OC$) for wear resistant applications. Highly metal-filled polymer suspensions were prepared and their conversion to ceramic composites by an-nealing in $N_{2}C$ atmosphere at 1000-$1600^{\circ}C$ were studied. Dimensional change porosity and phase distribution (filler network) were analyzed and correlated to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded in a silicon oxycarbide glass matrix were produced. De-pending on the pyrolysis conditions ceramic composites with a density up to 95 TD% a hardness of 7-8.8GPa Yong's modulus of 220-230 GPa a fracture toughness of 6-6.8$MPam^{1/2}$ and a flexual strength of 380-470 MPa were obtained.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.23 no.3
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• pp.250-258
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• 2014

Due to recent industrial growth and development, there has been a high demand for light and highly durable materials. Therefore, a variety of new materials has been developed. These new materials include carbon fiber reinforced plastic (CFRP or CRP), which is a wear-, fatigue-, heat-, and corrosion-resistant material. Because of its advantageous properties, CFRP is widely used in diverse fields including sporting goods, electronic parts, and medical supplies, as well as aerospace, automobile, and ship materials. However, this new material has several problems, such as delamination around the inlet and outlet holes at drilling, fiber separation, and tearing on the drilled surface. Moreover, drill chips having a fine particulate shape are harmful to the work environment and engineers' health. In fact, they deeply penetrate into machine tools, causing the reduction of lifespan and performance degradation. In this study, CFRP woven and unidirectional prepregs were formed at $45^{\circ}$ and $90^{\circ}$, respectively, in terms of orientation angle. Using a high-speed steel drill and a TiAIN-coated drill, the two materials were tested in three categories: cutting force with respect to RPM and feed speed; shape changes around the input and outlet holes; and the shape of drill chips.

• Journal of Powder Materials
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• v.11 no.1
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• pp.8-15
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• 2004

The basic concept of functionally gradient materials (FGM) is to fabricate materials type having possibilities of applications in various fields by changing their intrinsic properties with continuous gradient. The present communication has reviewed the developments and applications of various FGMs designed for improved thermo-mechanical properties, in which the thermal protective and wear resistant materials are especially focused. Effects of thermo-mechanical properties and limits of FGMs designed for high temperature applications were mainly understood in terms of residual stress evolved from the design and fabrication. In addition, FGMs applied in structural parts were also introduced and discussed in terms of typical fabrication method for FGMs.

• Journal of Powder Materials
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• v.24 no.3
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• pp.235-241
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• 2017

Titanium alloys have high specific strength, excellent corrosion and wear resistance, as well as high heat-resistant strength compared to conventional steel materials. As intermetallic compounds based on Ti, TiAl alloys are becoming increasingly popular in the aerospace field because these alloys have low density and high creep properties. In spite of those advantages, the low ductility at room temperature and difficult machining performance of TiAl and $Ti_3Al$ materials has limited their potential applications. Titanium powder can be used in such cases for weight and cost reduction. Herein, pre-forms of Ti-Al-xMn powder alloys are fabricated by compression forming. In this process, Ti powder is added to Al and Mn powders and compressed, and the resulting mixture is subjected to various sintering temperature and holding times. The density of the powder-sintered specimens is measured and evaluated by correlation with phase formation, Mn addition, Kirkendall void, etc. Strong Al-Mn reactions can restrain Kirkendall void formation in Ti-Al-xMn powder alloys and result in increased density of the powder alloys. The effect of Al-Mn reactions and microstructural changes as well as Mn addition on the high-temperature compression properties are also analyzed for the Ti-Al-xMn powder alloys.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 1995.04a
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• pp.515-528
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• 1995

Slips and falls are the major causes of the pedestrian injuries in the industry and the general community throughout the world. With the awareness of these problems, the friction coefficients of the interface between floorings and footwear have been measured for the evaluation of slip resistant properties. During this measurement process, the surface texture has been shown to be substantially effective to the friction mechanism between shoe heels and floor surfaces under various types of walking environment. Roughness, either of the floor surface or shoe heels, provides the necessary drainage spaces. This roughness can be designed into the shoe heel but this is inadequate in some cases, especially a wear. Therefore, it is essential that the proper roughness for the floor surface coverings should be provided. The phenomena that observed at the interface between a sliding elastomer and a rigid contaminated floor surface are very diverse and combined mechanisms. Besides, the real surface geometry is quite complicate and the characteristics of both mating surfaces are continuously changing in the process of running-in so that a finite number of surface parameters can not provide a proper description of the complex and peculiar shoe - floor contact sliding mechanism. It is hypothesised that the interface topography changes are mainly occurred in the shoe heel surfaces, because the general property of the shoe is soft in the face of hardness compared with the floor materials This point can be idealized as sliding of a soft shoe heel over an array of wedge-shaped hard asperities of floor surface. Therefore, it is considered that a modelling for shoe - floor contact sliding mechanism is mainly depended upon the surface topography of the floor counterforce. With the model development, several surface parameters were measured and tested to choose the best describing surface parameters. As the result, the asperity peak density (APD) of the floor surface was developed as one of the best describing parameters to explain the ambiguous shoe - floor interface friction mechanism. It is concluded that the floor surface should be continuously monitored with the suitable surface parameters and kept the proper level of roughness to maintain the footwear slip resistance. This result can be applied to the initial stage of design for the floor coverings.