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Characteristics of NiO films prepared by atomic layer deposition using bis(ethylcyclopentadienyl)-Ni and O2 plasma

  • Ji, Su-Hyeon;Jang, Woo-Sung;Son, Jeong-Wook;Kim, Do-Heyoung
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2474-2479
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    • 2018
  • Plasma-enhanced atomic layer deposition (PEALD) is well-known for fabricating conformal and uniform films with a well-controlled thickness at the atomic level over any type of supporting substrate. We prepared nickel oxide (NiO) thin films via PEALD using bis(ethylcyclopentadienyl)-nickel ($Ni(EtCp)_2$) and $O_2$ plasma. To optimize the PEALD process, the effects of parameters such as the precursor pulsing time, purging time, $O_2$ plasma exposure time, and power were examined. The optimal PEALD process has a wide deposition-temperature range of $100-325^{\circ}C$ and a growth rate of $0.037{\pm}0.002nm$ per cycle. The NiO films deposited on a silicon substrate with a high aspect ratio exhibited excellent conformality and high linearity with respect to the number of PEALD cycles, without nucleation delay.

Effect of Gd Substitution for the Ca Site in the Bi1.84Pb0.34Sr1.91 ({Ca1-xGdx)2.03Cu3.06O10+δ(x=0.0~0.06) Superconductors

  • Lee, Min-Soo
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.405-409
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    • 2003
  • The effect of substitution of Gd ions for Ca ions in the B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$(C $a_{1-x}$ G $d_{x}$)$_{2.03}$ C $u_{3.06}$ $O_{ 10+{\delta}}$/ (x=0.0~0.06) was investigated by measuring x-ray diffraction patterns, lattice constants, do resistivity and Hall effect. We found the solubility limit of Gd in the 110 K phase to be x < 0.015. Within the solubility limit, the c-axis seemed to decrease with increasing x. In the region of the 110 K single phase, the critical temperature $T_{c}$ gradually decreased with an increasing the Gd concentration x, corresponding to a small change of the carrier concentration.

Preparation, Characterization and Photoluminescence Properties of Ca1-xSrxS:Eu Red-emitting Phosphors for a White LED

  • Sung, Hye-Jin;Cho, Young-Sik;Huh, Young-Duk;Do, Young-Rag
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1280-1284
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    • 2007
  • A series of Ca1-xSrxS:Eu (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) phosphors were synthesized by solid-state reactions. The Ca1-xSrxS:Eu phosphors have a strong absorption at 455 nm, which corresponds to the emission wavelength of a blue LED. The emission peak of Ca1-xSrxS:Eu is blue shifted from 655 to 618 nm with increasing Sr content. The characteristics of Ca1-xSrxS:Eu phosphors make them suitable for use as wavelengthtunable red-emitting phosphors for three-band white LEDs pumped by a blue LED. In support of this, we fabricated a three-band white LED by coating SrGa2S4:Eu and Ca0.6Sr0.4S:Eu phosphors onto a blue LED chip, and characterized its optical properties.

Changes in Stanniocalcin-2 and Hypoxia-Inducible Factor-1α mRNA Expression in Medaka Oryzias dancena Exposed to Acute Hypoxia (저산소환경에 의한 송사리(Oryzias dancena)의 Stanniocalcin-2와 Hypoxia-Inducible Factor-1α mRNA 발현의 변화)

  • Shin, Ji Hye;Sohn, Young Chang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.1
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    • pp.70-76
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    • 2013
  • Some fish live in aquatic environments with low or temporally changing $O_2$ availability. Variation in dissolved oxygen (DO) levels requires behavioral, physiological, and biochemical adaptations to ensure the uptake of sufficient $O_2$. Several species are relatively well adapted to tolerate low $O_2$ partial pressures (hypoxia). The medaka (Oryzias dancena ) is an important model organism for biomedical research that shows remarkable tolerance to hypoxia. We investigated the regulation and role of hypoxia-inducible factor-1 (HIF-$1{\alpha}$) as a general hypoxia-response gene and stanniocalcin-2 (STC2), which is one of the genes regulated by HIF-$1{\alpha}$ in mammals under hypoxia. We subjected adult male medaka to the following three acute hypoxia regimes: 1, 24, and 72 h at DO = $1.8{\pm}0.5$ ppm. The changes in STC2 and HIF-$1{\alpha}$ mRNA were monitored using quantitative real-time reverse-transcription PCR. We found strong upregulation of HIF-$1{\alpha}$ mRNA in the livers of fish exposed to hypoxia. Hypoxia rapidly upregulated STC-2 mRNA expression in muscle, but not in the brain, gills, liver, or intestine. Therefore, unlike in mammals, hypoxia might regulate O. dancena STC-2 expression in an HIF-$1{\alpha}$-independent manner.

The Effects of the Makgeolri on the Antioxidative Activity in the Endotoxin LPS-treated Rats (내독소인 LPS로 처치된 흰쥐에 대한 막걸리 항산화 활성효과)

  • Kwon, Ryun-Hee;Chae, Go-Yeon;Ho, Boe-Jin
    • Journal of Food Hygiene and Safety
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    • v.26 no.2
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    • pp.166-170
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    • 2011
  • Modem people have begun to have the nationwide interest in the rice wine called Makgeolri which is one of the traditional Korean alcoholic liquors. This study was performed to investigate the effects of San sung Makgeolri extract (SM) on antioxidation together with the determination of pH and dissolved oxygen (DO) in the progress of fermentation in the lipopolysaccharide(LPS)-treated rats. We examined the levels of SOD (superoxide dismutase), CAT (catalase), GPx (glutathione peroxidase) in liver homogenates and the histopathological observations in liver tissue. LPS-treated group markedly decreased the levels of SOD, CAT and GPx. But SM + LPS-treated group significantly increased the levels of them. Furthermore, the antioxidative effects of SM were supported by the histopathological observations in liver tissue which showed severe inflammation and necrosis in LPS-treated group, compared to the attenuated inflammation and necrosis in SM + LPS-treated group. This results suggested that SM could be a candidate of antioxidative material in spite of alcoholic liquors.

Development of Larvae and Juveniles of the Liobagrus mediadiposalis from Daeseocheon Stream in Yeongdukosipcheon (영덕오십천 소하천인 대서천에 서식하는 자가사리 Liobagrus mediadiposalis의 자치어 형태발달)

  • Jae Min Park;Kyeong Ho Han
    • Korean Journal of Ichthyology
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    • v.35 no.2
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    • pp.75-82
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    • 2023
  • The samples used in this study were collected on two occasions (April 21 and May 16, 2021) from Liobagrus mediadiposalis and spawned egg masses located under rocks in Daeseocheon, Yeongdeok-gun, Gyeongsangbuk-do. Fertilized eggs ranged in size from 3.30~3.92 (average 3.57±0.19) mm (n=30), and it took 152~155 hours to hatch at water temperatures of between 17.0 and 20.0℃. Newly hatched larvae immediately post-hatching had a total length of 6.43~6.67 (6.55±0.07) mm (n=30), and were characterized by the retention of a yolk sac and an incompletely open mouth and anus, consistent with the yolk. On the 9 days post-hatching, the postflexion larvae had grown to length of between 11.0~13.8 (12.3±0.70) mm (n=30), and the caudal bone at the tip of the tail was bent upwards at an angle of 45°, thereby indicating the transition to the late larval growth stage. On the 16 days post-hatching, the total length of juvenile had increased to between 15.8~18.2 (16.8±0.77) mm (n=30), and the number of fins reached a fixed number of 8 dorsal, 17 anal, and 8 pelvic fins. On the basis of the findings of this study, we were able to confirm differences in the size of hatching larvae and fin mottle patterns in the early life history of related species.

Efficacy of Cooling Vest for Auxiliary Body Cooling in Hot Environments(2) - Comparison in Terms of Thermophysiological Properties Between New Cooling Vest and Standard Cooling Vest - (고온환경 하에서 착용하는 인체냉각 보조도구로서의 Cooling Vest연구(2) - 개발제품의 온열생리학적특성 -)

  • Kwon, Oh-Kyung;Kim, Tae-Kyo;Kim, Jin-A
    • Fashion & Textile Research Journal
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    • v.2 no.4
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    • pp.346-352
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    • 2000
  • The purposes of this study are finding out thermophysiological properties throughout wearing experiment with standard cooling vest as well as providing data in order to design and apply more comfortable cooling vest. To do this study, we produced cooling vest newly. 1. Rectal temperature was ascended approximately from $37.2^{\circ}C$ to $38.05^{\circ}C$ in lab, but wearing cooling vest, the temperature was descended 0.2 while wearing developed product compare with existing product. Mean skin temperature which was showed distribution from $32.8{\sim}36.5^{\circ}C$, it was descended $1.0{\sim}1.1^{\circ}C$, while wearing cooling vest and comparing with existing product, wearing developed product was lower $0.5^{\circ}C$. 2. While wearing developed cooling vest, it was found that they had lower tendency than standard cooling vest. Specifically in case of temperature within clothing (chest) $0.2{\sim}2.0^{\circ}C$ in case of humidity within clothing 2~8%RH. Facts from above we confirmed that clothing microclimate had been improved and space was happened between body and garment in order to control. 3. In subjective sensation, standard cooling vest made negative response during experiment period from participants, but new cooling vest was nearing to comfortable area. It was con finned from above conclusions that wearing developed product is more effective in terms of comfort and reduction of heat stress in situation of working in hot environment.

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Exchange Bias Perpendicular Magnetic Anisotropy and Thermal Stability of (Pd/Co)N/FeMn Multilayer ((Pd/Co)N/FeMn 다층막에서의 교환바이어스 수직자기이방성과 열적안정성)

  • Joo, Ho-Wan;An, Jin-Hee;Kim, Bo-Keun;Kim, Sun-Wook;Lee, Kee-Am;Lee, Sang-Suk;Hwang, Do-Geun
    • Journal of the Korean Magnetics Society
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    • v.14 no.4
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    • pp.127-130
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    • 2004
  • Magnetic properties and thermal stability by exchange biased perpendicular magnetic anisotropy in (Pd/Co)$_{N}$FeMn multilayer deposited by do magnetron sputtering system are investigated. We measured the perpendicular magnetization curves of (Pd(0.8nm)/Co(0.8nm)$_{5}$FeMn multilayer as function of FeMn thickness and annealing temperature. As FeMn thickness increases from 0 to 21nm, the perpendicular exchange bias(Hex) obtained 127 Oe at FeMn thickness 15nm. As the annealing temperature increases to 24$0^{\circ}C$, the E$_{ex}$ increased from 115 Oe to 190 Oe and disappeared exchange biased perpendicular magnetic anisotropy effect at 33$0^{\circ}C$.

Analysis of reports on orphan lung diseases in Korean children

  • Jang, Sun-Jung;Seo, Hyun-Kyung;Yi, Sung-Jae;Kim, Kyong-Min;Jee, Hye-Mi;Han, Man-Yong
    • Clinical and Experimental Pediatrics
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    • v.53 no.6
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    • pp.711-717
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    • 2010
  • Purpose: Orphan lung diseases are defined as lung diseases with a prevalence of 1 or less in 2,000 individuals. Despite an increase in the numbers of patients with such diseases, few studies on Korean children have appeared. To obtain epidemiologic and demographic data on these diseases, we systematically reviewed reports on pediatric orphan lung diseases in Korea over the last 50 years. Methods: We reviewed 223 articles that have appeared since 1958 on orphan lung diseases in Korean children. These articles described a total of 519 patients aged between 0 and 18 years. We classified patients by year of publication, diagnosis, geographic region, and journal. Results: Of 519 patients, 401 had congenital cystic lung diseases and 66 had bronchiolitis obliterans. About 80% of patients were described in reports published in three journals, Pediatric Allergy and Respiratory Disease (Korea), the Korean Journal of Pediatrics, and the Korean Journal of Thoracic and Cardiovascular Surgery, in which papers on 157 (30.2%), 138 (26.6%), and 111 (21.4%) patients appeared, respectively. The frequency of publication of case reports has increased since 1990. Of the 519 patients, 401 (77.3%) were from Seoul/Gyeonggi-do and 72 (13.9%) from Busan/Gyeongsangnam-do. Conclusion: The prevalence of pediatric orphan lung disease has increased since 1990, and some provinces of Korea have a higher incidence of these diseases than do others. Studies exploring the incidence of pediatric orphan lung diseases in Korea are needed for effective disease management.

Mechanical Properties of Austempered Fe-2.0wt.%Si-0.3wt.%Mn Steel with various Carbon Contents (탄소함량 변화에 따른 오스템퍼드 Fe-2.0wt.%Si-0.3wt.%Mn 강의 기계적 성질)

  • Ha, Jong-Gyu;Shin, Sang-Yun;Lee, Do-Hoon;Ye, Byung-Joon
    • Journal of Korea Foundry Society
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    • v.35 no.1
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    • pp.1-7
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    • 2015
  • In this study, we investigated the effect of carbon on mechanical properties with different austempering conditions of high carbon(0.7~1.3wt.%C)-2.0wt.%Si steels. The specimens were austenitized at 850, 925 and $1020^{\circ}C$, and austempered at 260, 320 and $380^{\circ}C$ for the various period of time from 3 min to 300 min. After heat treatment, the evolution of stage I and stage II was identified with optical microscope, XRD and hardness test. When the austempering temperature was $260^{\circ}C$, the microstructure consisted of the lower ausferrite while the upper ausferrite micro-structure was formed at $380^{\circ}C$. As the austempering temperature increases from 260 to $380^{\circ}C$, the tensile strength decreases and elongation increases. In addition, when carbon content increases, tensile strength and elongation decrease.