• Title/Summary/Keyword: Water-rock interaction

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Mineralogical Study of the Granite Weathering in the Seoul Area: Water-Rock Interaction in the Namsan Granite (남산 화강암의 풍화 및 광물-물 반응에 관한 연구)

  • Lee, Soo-Jae;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.40-48
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    • 1994
  • The weathering of the Namsan granite was studied in terms of sorption process. The Namsan granite consists mainly of quartz, alkali feldspar, plagioclase (${Ab_{85}An_{15}}-Ab_{100}$ and biotite with small amounts of sericite, magnetite and ilmenite. The kinetic factors for altering the granite body are the proton and hydroxyl ions derived from the reaction of water and mineral. There are two different types of pH variation curves for rocks of different mineral assemblages. when powdered granite was dispersed in distilled water under ambient condition. The sorption-process proceeds by three steps for fresh granite; (1) the initial rapid pH-rise to 10 by the uptake of proton by negatively charged mineral surfaces, (2) the gradual pH-down, and (3) the stable pH tail between 7.1-7.5. For somewhat weathered granites, the sorption proceeds; (1) the initial rapid pH-down to 4.8, (2) the slight pH-rise and slow ph-down, and (3) the stable pH tail between 5.0-5.3. The reaction rate is controlled by the density of adsorbable sites, the solubility of the mineral, pH of the system and formation of amorphous gel and gibbsite. Amorphous gel floates on the surface of the solution while stirring the powdered granite and then is transformed into gibbsite in an hour or so. The pH saturation values for -325 mesh fresh granite from 5 m depth is about pH 10 when rock/water ratio is over 10g/200 ml.

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Geochemical Modeling on Water-caprock-gas Interactions within a CO2 Injected in the Yeongil Group, Pohang Basin, Korea (포항분지 영일층군 내 이산화탄소 주입에 의한 물-덮개암-가스 반응에 대한 지화학적 모델링)

  • Kim, Seon-ok;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.54 no.1
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    • pp.69-76
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    • 2021
  • This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

Development of Revegetation Measures using Boring Technique in Rock Slopes - Focus on Lespedeza cyrtobotrya - (암반비탈면에 있어서 천공기법에 의한 녹화공법의 개발 - 참싸리를 중심으로 -)

  • Ma, Ho-Seop;Kang, Won-Seok;Park, Jin-Won
    • Journal of Korean Society of Forest Science
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    • v.100 no.4
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    • pp.558-564
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    • 2011
  • This study was conducted to evaluate the effects of early revegetation by analyzing the characteristics of germination and growth of Lespedeza cyrtobotrya using boring technique in rock slopes. After making up a growing basis of approximately 20 cm depth and 10 cm diameter by using a boring machine, the surface of rock slopes was planted with vegetation-plant. The number of germinating populations by soil media was 23 in H.s, 22 in T.s, 12 in M.s, and 1 in M.g.s. The germination rate (%) by soil media was 19.2% in H.s, 18.3% in T.s, 10.0% in M.s and 0.8% in M.g.s. In monthly changes of growth rate, the aspect was northwest direction, the soil media was M.s, and the treatment was microorganism plot. The main factors affecting survivorship and growth of population were soil media and treatment plot. The interaction between each factor had a good effects in bearing ${\times}$ soil media, bearing ${\times}$ treatment plot, soil media ${\times}$ treatment plot. but, it is recommended that the mulching of vegetation plant is highly needed to help the germination of seed and growth of vegetation because of loss of seed and soil media occurred due to rainfall. Therefore, The result suggests that the revegetation technique using boring in rock slope was very efficient in respect of the early revegetation and the landscape.

Numerical Formulation of Thermo-Hydro-Mechanical Interface Element (열-수리-역학 거동 해석을 위한 경계면 요소의 수식화)

  • Shin, Hosung;Yoon, Seok
    • Journal of the Korean Geotechnical Society
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    • v.38 no.9
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    • pp.45-52
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    • 2022
  • Because discontinuity in the rock mass and contact of soil-structure interaction exhibits coupled thermal-hydromechanical (THM) behavior, it is necessary to develop an interface element based on the full governing equations. In this study, we derive force equilibrium, fluid continuity, and energy equilibrium equations for the interface element. Additionally, we present a stiffness matrix of the elastoplastic mechanical model for the interface element. The developed interface element uses six nodes for displacement and four nodes for water pressure and temperature in a two-dimensional analysis. The fully coupled THM analysis for fluid injection into a fault can model the complicated evolution of injection pressure due to decreasing effective stress in the fault and thermal contraction of the surrounding rock mass. However, the result of hydromechanical analysis ignoring thermal phenomena overestimates hydromechanical variables.

Heavy Metal Contents of the Surface Water and Stream Sedi-ments from the Talc Mine Area, Western Part of Chungneam (충남 서부 활석광산 주변의 지표수 및 하상 퇴적물의 중금속 함량)

  • 송석환;김명희;민일식
    • Korean Journal of Environment and Ecology
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    • v.15 no.2
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    • pp.139-152
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    • 2001
  • 충남 서부 활석광산 주변의 수계에 대한 원소 함량특성에 대해 알아보고자 대흥 및 광천광산에 대해 수질 및 하상 퇴적물 시료와 함께 광산 주변 토양 및 모암 시료를 채취, 비교하였다. 대흥지역 퇴적물은 대부분 원소에서 SP가 GN에 비해 높았는데 이는 퇴적물 내 유색 및 무색광물 함량 차이로 판단된다. 절대 함량 비교에서 광물 결정구조 내 쉽게 Mg와 치환하는 원소는 낮은비율을, Fe와 치환하는 원소는 높은 비율을 보였는데 이는 퇴적물 내 주 구성광물내 원소 치환특성을 반영하기 때문으로 판단된다. 절대 함량의 감소 순서와 타원소들과 높은 상관관계(>0.85)의 빈도를 보이는 원소들 사이의 차이는 퇴적물 화학조성에 이차광물과 비정질 광물등의 조성도 반영되었음을 암시한다. 대흥지역 지표수는 대부분 원소에서 MSP가 SP와 GN의 중간값을, MSG는 LGN과 MSP의 중간값을 조여 수계의 혼합특성을반영하는 것으로 판단된다. 절대 함량관계에서는 SP는 GW1과 유사했고, GN은 LGN과 유사했으며, 절대함량은(Mg, Fe), (As, Sc), (Mo, V, Se) 순서로 낮아졌다. 광천지역은 갱내수가 천부 지하수에 비해 대부분 원소에서 높은 함량을 보였는데, 이는 갱내수가 더욱더 많은 물-암석반응을 거친 때문으로 판단된다. 절대 함량은 Mg, Br, Fe, (Sc, Cr), (An, Ni, V)순서로 감소하였다. 갱냉수의 지역간 원소 함량 차이는 사문암화가 우세한 광천지역과 활석화가 우세한 대흥지역 모암들 사이의물-암석 상화반응의 차이를 보여주는 것으로 판단된다 두 지역의 상부 토양 및 모암 조성에서 SP가 GN에 비해 높은 Mg 비, Ni, Cr, Co 등 함량을 보였는데, 이는 사문암 지역 내 Mg, Ni, Cr 등이 풍부한 광물들 탓으로 판단된다. 퇴적물과 수질 사이에서는 함량 경향을 뚜렷하지 않았고 원소에 따라 서로 다른 힘량 차이를 보였는데, 이는 퇴적물 원소 함량이 수계 조성을 반영하는 것이 아님을 나타낸다. 상부-토양-암석-수계의 조성관계에서 대흥지역 지표수 중 SP 조성이, 광천지역은 갱냉수가 지하수의 조성에 가까웠다.

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Geochemical Characteristics of Baengnyongdonggul Cave Water, Pyeongchang, Gangwon State (강원특별자치도 평창 백룡동굴 동굴수의 지구화학적 특성)

  • Youngyun Park;Lyoun Kim;Jonghee Lee;Mun Bok Choi
    • The Journal of Engineering Geology
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    • v.33 no.3
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    • pp.413-426
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    • 2023
  • This study presents the geochemical characteristics of cave water to evaluate its origin and flow path. From June 2022 to may 2023, river water was collected at two sites (WE1 and WE2) in the Donggang River around Baengnyongdonggul Cave, and cave water was collected at four sites (WE3 to WE6) inside Baengnyongdonggul Cave. Water samples were analyzed for major dissolved components. Both river and cave waters were classified as Ca-HCO3 type. All cave water samples were supersaturated in carbonate minerals, suggesting that carbonate minerals would precipitate within the cave. Due to differences in the source of cave water and the degree of water-rock interaction, the geochemical characteristics of water from sites where the flow of cave water is observed (WE3 and WE6) and rimstone pools (WE4 and WE5) could be clearly distinguished. The cave water at WE6 flows in from the Donggang River, then passes through WE3 and flows back out into the Donggang River. The cave water at WE4 and WE5 is supplied from precipitation, but the flow path of cave water at WE4 and WE5 is different.

Formation of Clay Minerals by Water-Rock Interaction in the Fracture of Gneiss (편마암 열극에서의 물-암석 상호반응에 의한 점토광물 생성)

  • Jeong, Chan-Ho;Kim, Soo-Jin;Koh, Yong-Kwon
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.49-61
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    • 1994
  • As the groundwater flows along the fractures of crystalline rocks, it will be in contact with the fracture walls mostly coated by secondary minerals which are quite different form those of host rocks. The presence of fracture-filling minerals in crystalline rocks is important on the view point of radioactive waste disposal because of their great surface reactivity. The Surichi drill hole of 200 m in depth in the Yugu area composed mainly of Precambrian gneiss was selected to study the formation process of clay minerals on the fracture wall of gneiss, and their relation with present groundwater. The water-rock interaction in fractures resulted in the formation of gibbsite and clay minerals. They are formed by two different processes : (1) Incongruent dissolution of feldspar by groundwater diffused from a fracture path into rock matrix produced smectite and illite in situ, (2) on the wall of fracture, gibbsite, kaolinite, smectite and illite are formed by precipitation of dissolved species in groundwater. They show the paragenetic sequence such as gibbsite${\leftrightarrow}$kaolinite${\leftrightarrow}$smectite or illite. The paragenetic sequence of fracture-filling minerals was controlled by increase of pH of groundwater, decrease of fracture permeability by precipitation of fillings, and immobility of alkali or alkaline earths in groundwater. The groundwater from the Surichi borehole is a $Na-HCO_{3}$ type with pH range of 8.6-9.2. The sodium and bicarbonate in groundwater would be supplied by the dissolution of albite and calcite, respectively. The saturation index of groundwater and surface water calculated by WATEQ4F indicates that gibbsite and kaolinite are under precipitation to equilibrium state, and that smectite and illite are under equilibrium to redissolution environment. The stability relation of clay minerals in the $Na_{2}O-Al_{2}O_{3}-SiO_{2}-H_{2}O$ system shows that kaolinite is stable for all waters.

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제주도 한라산 남북측 사면 용천수의 수리지구화학

  • 이광식;박원배;현승규;김용제;문덕철;김구영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.408-412
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    • 2004
  • A total of 23 springs distributed in the southern and northern sides of Mt. Hala in Jeju Island were seasonally sampled and analyzed for their major ion chemistry and oxygen and hydrogen isotope compositions to investigate their hydrogeochemical and isotopic characteristics. Dissolved ion concentrations of the south-side springs slightly increase with decreasing altitude. This indicates that dissolved ion concentrations of groundwater recharged at higher altitudes increase by water-rock interaction during the downgradient migration of groundwater through highly permeable volcanic aquifer. Dissolved ion concentrations of the north-side springs also slightly increase with decreasing altitude, but dramatically increase at ~300 m.a.s.l. This may indicate a sudden input of contaminants to the north-side groundwater system around ~300 m.a.s.l. Springs located in areas above ~300 m.a.s.l. have very low concentrations of dissolved ions, showing little seasonal variations. Whereas springs located in areas below ~300 m.a.s.l. show a big seasonal variation in the concentration of dissolved ions. Seasonal variation of oxygen isotope compositions of springs is ~3$\textperthousand$ for high-altitude springs (~1700 m.a.s.l.) and is ~2$\textperthousand$ near shore, indicating an attenuation of the variation through mixing with other groundwater bodies during migration.

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A study on ground surface settlement due to groundwater drawdown during tunnelling (터널 굴착시 지하수 저하로 인한 지반침하에 관한 연구)

  • Yoo, Chung-Sik;Kim, Sun-Bin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.4
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    • pp.361-375
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    • 2007
  • This paper presents the results of investigation on tunnelling-induced ground surface settlement characteristics in water bearing ground using finite element (FE) stress-pore pressure coupled analysis. Fundamental interaction mechanism of ground and groundwater lowering was first examined and a number of influencing factors on the results of the coupled FE analysis were identified. A parametric study was then conducted on the influencing factors such as rock type, thickness of soil layer, permeability of shotcrete lining, among others. The results indicate that the tunneling-induced groundwater drawdown results in a deeper and wider settlement trough than without groundwater drawdown, and that the Error function approach does not yield satisfactory result in predicting a settlement profile. The results of analysis are summarized so that the relationship between the settlement and the influencing factors can be identified.

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Chung Yakyong's View of Nature and the Meanings of His Garden, Tasanchodangwon (정약용의 자연관과 다산초당원의 의미)

  • 박희성;조정송
    • Journal of the Korean Institute of Landscape Architecture
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    • v.25 no.3
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    • pp.131-142
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    • 1997
  • As a study on a traditional garden with historical value, the objective of this study is to comprehensively understand the internal meanings of the garden in a designer's personal perspective. Tasanchodangwon was designed Chung Yakyong who is a scholar of Practical Learning in late Chosun Dynasty. Considering the features of him and basic approach of this study, the internal eanings of the Tasanchodangwon was approached with the focus on the view of nature of him, and through general review of physical components of the garden. Additionally the meanings of the garden were also reviewed in his personal situation. The result of the study may be summarized as followings. First, according to the view of nature of Chung Yakyong, his intention to enrich life practically by building separate structures for education for his residence, creating lake by having water supply, and creating vegetable garden relates with the view of nature in Primary confucianistic perspective. In addition, the place served as a ground to support Chung Yakyong's attitude to become a man of virtue, Second, his preference to enjoyu tea culture allowed an opportunity for him to accept circumstance positively and discover the self. Components related to farming reflects his Practical Learning. The man-made rock mountain in the pond is a specific technique for Yi-Jing. And third, literatures authored by Chung Yakyong show that internal meaning of Tasanchodangwon is to pursue an utopia. This is closely related to solving his conflicts felt in reality. In short, Tasanchodangwon is a form reflecting the spiritual world of Chung Yakyong, and through interaction with his life, served as a ground to culture his mind.

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