• Journal of Soil and Groundwater Environment
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• v.22 no.3
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• pp.10-17
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• 2017

In this study, the evolution and origin of major dissolved constituents of crystalline bedrock groundwater in a coastal area were evaluated using multivariate statistical and groundwater quality analyses. The groundwater types mostly belonged to the $Na(Ca)-HCO_3$ and $Ca-HCO_3$ types, indicating the effect of cation exchange. Stable isotopes of water showed two areas divided by first and secondary evaporative effects, indicating a pattern of rapid hydrological cycling. Saturation indices of minerals showed undersaturation states. Thus, the degree of evolution of groundwater is suggested as in the low to intermediate stage, based on field and laboratory analytical conditions. According to the principal component analysis (PCA) results, the chemical components of EC, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $HCO_3{^-}$, $SO{_4}^{2-}$ (PCA 1), $F^-$ (PCA 3), $SiO_2$ (PCA 4), and $Fe^{2+}$ (PCA 5) are derived from various water-rock interactions. However, $NO_3{^-}$, $Na^+$, and $Cl^-$ (PCA 2) represented the chemical characteristics of both anthropogenic sources and natural sea spray.

• Economic and Environmental Geology
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• v.35 no.6
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• pp.533-544
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• 2002

In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).

• Economic and Environmental Geology
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• v.34 no.5
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• pp.447-460
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• 2001

The geothermal waters from the Busan area belong to Na-CI type and are characterized by much higher EC (921 ~6,520${\mu}$S/cm) and TDS (608-3,390 mg/L) than other geothermal waters in Korea. The concentration of majorions shows a weakly positive relationship with temperature except for Mg ion. The concentrations of the major cat ions have the order of Na>Ca>K>Mg. Ca ion is enriched and Mg ion is depleted compared with seawater. All Br concentrations of geothermal water are lower than those of seawater, showing a positive relationship with temperature. Generally geochemical characteristics of geothermal waters of the Busan area indicate that these waters have relatively increased Ca and Sr contents and depleted Mg, Na and K contents caused by seawater interaction with wall rock at depth during deep circulation of seawater. Base on the relationship between major ions and temperature, saline geothermal waters are diluted and are cooled by mixing of groundwaters during ascent. Isotope study and reaction path modeling of the overall geochemical system are required in order to better quantify the evolution and origin of geothermal waters in the Busan area.

• The Journal of Engineering Geology
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• v.28 no.4
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• pp.565-582
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• 2018

We investigated the hydrochemical properties of ChusanYongchulso Spring located in Buk-myeon, Ulleung Island, focusing on the formation and characteristics of aquifers in and around the Nari caldera. Abundant pumice with high permeability and numerous fractures (including faults and joints) that formed as a result of caldera subsidence are widely distributed in the subsurface, favoring the formation of aquifers. Because of the presence of porous pyroclastic rocks with a high internal surface area, the water type of the springs is characterized by $NaHCO_3$, with upper stream waters and the upper spring being characterized by $NaHCO_3$ and NaCl, respectively. Components with a high coefficient of determination with EC are $HCO_3$, Na, F, Ca, Mg, Cl, $SiO_2$, and $SO_4$. The high concentrations of Na and Cl might be attributable to the main lithologies in the area, given that alkaline volcanic rocks are distributed extensively across Ulleung Island. Eh and pH, which are considered to be important indicators of water-rock interaction, are unrelated to most components. According to the results obtained from factor analysis, the variance explained by factor 1 is 54% and by factor 2 is 25.8%. Components with a high loading on factor 1 are F, Na, EC, Cl, $HCO_3$, $SO_4$, $SiO_2$, Ca, $NO_3$, and Mg, whereas components with a high loading on factor 2 are Mg and Ca, along with K, $NO_3$, and DO with negative loadings. It is suggested that the high concentrations of Na, Cl, F, and $SO_4$ are closely related to the presence of fine-grained alkaline pyroclastic rocks with high permeability and porosity, which favorintensewater-rock interaction. However, a wide-ranging investigation that encompasses methods such as geophysical prospecting and geochemical analysis (including isotope, trace-element, and tracer techniques) will be necessary to gain a better understanding of the groundwater chemistry, aquifer distribution, and water cycling of Ulleung Island.

• Journal of Soil and Groundwater Environment
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• v.16 no.2
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• pp.61-76
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• 2011

This study was objected to provide suggestions for best management practices to restore the cultural and historical values of the wells in Palaces as well as their water qualities. Water resources in the five Palaces in Seoul Metropolitan, including Gyeongbokgung, Changdeokgung, Changgyeonggung, Jongmyo Shrine, and Deoksugung, were surveyed for their physical flows and chemical compositions from April to July in 2010. Ground waters in most wells were found at depths within 5 m from the ground surface, showing typical water-table aquifer systems. Hydraulic gradients indicate water resources in Gyeongbokgung, Changdeokgung, and Changgyeonggung flowing toward south, and toward east in Deoksugung area. Especially, water-level fluctuation data at S-10 in Deoksugung implied the influence of groundwater discharge facility. In Jongmyo Shrine, water was not detected in wells, indicating the water level was lower than the well depth. Based on the water chemistry and stable isotope analyses, water resources and their qualities appeared to be formed by the water-rock interaction along the groundwater paths. S-10 (Deoksugung) and S-14 (Changgyeonggung) samples were contaminated with nitrate ($NO_3$) in levels of higher than Korean drinking water standard, 10 mg/L as $NO_3$-N, but once in four sampling campaigns. In the situation that water resources in Palaces still maintain natural characteristics, the materials that will be used for the restoration and improvement of the Palace water supplies should be carefully selected not to disturb the natural integrity. In addition, because the wells are located in the center of metropolitan area, a systematic monitoring should be applied to detect and to manage the potential impacts of underground construction and various pollution sources.

• Journal of Ocean Engineering and Technology
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• v.31 no.6
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• pp.388-396
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• 2017

A Lagrangian approach based computational fluid dynamics (CFD) was used to simulate large and/or sharp deformations and fragmentations of interfaces, including free surfaces, through tracing each particle with physical quantities. According to the concept of the particle-based CFD method, it is possible to apply it to both fluid particles and solid particles such as sand, gravel, and rock. However, the presence of more than two different phases in the same domain can make it complicated to calculate the interaction between different phases. In order to solve multiphase problems, particle interaction models for multiphase problems, including surface tension, buoyancy-correction, and interface boundary condition models, were newly adopted into the moving particle semi-implicit (MPS) method. The newly developed MPS method was used to simulate a typical validation problem involving dam breaking. Because the soil and other particles, excluding the water, may have different viscosities, various viscosity coefficients were applied in the simulations for validation. The newly developed and validated MPS method was used to simulate the mobile beds induced by broken dam flows. The effects of the viscosity on soil particles were also investigated.

• Journal of Soil and Groundwater Environment
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• v.22 no.5
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• pp.71-81
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• 2017

The hydrogeochemical characteristics of groundwater in the small waterworks are examined with 81 groundwater samples in Ulju region, Ulsan. The pH ranged in 6.3-8.2 and did not exceed the drinking water standards. Electrical conductivity ranged from $50{\mu}S/cm$ to $1,719{\mu}S/cm$. It indicated that the electrical conductivities in groundwaters at the study area are relatively low, compared with other groundwaters in Ulsan area. The calcium concentrations in groundwaters ranged from 3.55 to 113.01 mg/L, and sodium concentrations ranged from 2.02 to 65.50 mg/L. Nitrate concentrations ranged from 0 to 100.56 mg/L and potassium concentrations ranged from N.D (not detected) to 2.50 mg/L. Major cations and anions were mainly derived from the water-rock interaction involving feldspar, gypsum and calcite. The groundwaters were mainly the $Ca-(Na)-HCO_3$ type, classified as the early stage of groundwater evolutions. The correlation between electrical conductivities and Ca concentrations in groundwaters was relatively high ($R^2=0.74$). In the correlations between ions, the correlation coefficient between $SO_4$ and Ca was 0.65 and between Mg and $HCO_3$ was 0.65.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.4
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• pp.273-281
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• 2007

Hyperalkaline groundwater formed by groundwater-cement components and its reaction with bedrock in a nuclear waste repository were simulated by geochemical modeling. The result of groundwater-cement components reaction showed that the pH of water was 13.3 and the precipitated minerals were Brucite, Katoite, Calcium Silicate Hydrate(CSH1.1), Ettringite, Hematite, and Portlandite. The result of interaction between such minerals and groundwater sampled in Gyeongju area also showed that the pH of groundwater reached 12.4. Interaction between such hyperalkaline groundwater and granite was simulated by kinetic model during $10^3$ years. This result showed that the final pH of groundwater reached 11.2 and the variation of pH was controlled by dissolution/precipitation of silicate and CSH minerals. Groundwater quality was also determined by dissolution/precipitation of silicate, CSH, oxide minerals. Our results show that geochemical modeling of long-term hyperalkaline groundwater and rock interaction can contribute to the safety assessment of engineered barrier by predicting geochemical condition in repository site.

• Water for future
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• v.16 no.4
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• pp.245-252
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• 1983

Recently river water pollution in Korea is given rise to serious problem in aspect of crop production, drinking well, water contamination and etc. Under these urgent situations, it is prime importance to protect water resources from pollutants. An environmental isotope survey of the groundwater form the shallow alluvial and the underlying crystalline rock aquifer of the Han River Basin has been undertaken, Analysis of the data has I) confirmed the hypothesis that the groundwater from the metropolitan area is recharged from the river whereas that form the non-urbanized region of the Basin is replenished by the infiltrating precipitation; ii) shown that crystalline rock aquifers are recharged by the ground water form the overlying alluvium. Old groundwater is a group of wells with tritium values in the range of 0 to 2 TU. These low values indicate that the water sampled was recharged much ealier, at least a few decades, than the other groundwater samples of higher tritium content. The low values in this region may, in fact, reflect the effect of the impermeable clay layers which impede infilteration from the surface. Stable isotope evidence confirmed that a recharge in the karst area occurs at a significantly greater elevation than that to the alluvial aquifer. An analysis of the tritium level collected over an annual cycle suggests that the residence time of groundwater is probably not more than a few months. There does not appear to be any correlation between the trace level of Zn, Mn and Pb in the groundwater and the mechanism of the recharge.

• Journal of Soil and Groundwater Environment
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• v.15 no.6
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• pp.9-16
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• 2010

Groundwater sampling was performed at 38 wells where they are located in the areas with high uranium and radon (marked as A and B, respectively) concentrations, which were based on the previous research results. In-situ parameters (temperature, pH, EC, Eh, DO) and natural radionuclides (uranium and radon) were analyzed to figure out the characteristics of groundwater environments. In-situ data did not show any relations to natural radionuclide data, which could be caused by groundwater mixing, depths of wells, and geological settings, etc. But the highest radon well presented relatively low temperature value and the highest uranium well presented relatively low pH values The highest uranium concentration ranging $1.14{\sim}188.19{\mu}g/L$ showed in the area of A region consisted of Jurassic two-mica granite. The areas of Jurassic biotite granite and Cretaceous granite in the A region have the uranium concentrations ranging $0.10{\sim}49.78{\mu}g/L$ and $0.36{\sim}3.01{\mu}g/L$, respectively. The uranium values from between wells of community water systems (CWSs) penetrating fractured bed-rock aquifers and personal boreholes settled in shallow aquifers near the wells of CWSs show big differences. It implies that the groundwaters of the two areas have evolved from different water-rock interaction paths that may caused by various types of wells having different aquifers. High radon activities in the area of B region composed of Precambrian gneiss showed ranging from 6,770 to 64,688 pCi/L. Even though the wells are located in the same geological settings, their rodon concentration presented different according to depth and distance.