• 대한가정학회지
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• 제35권3호
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• pp.275-286
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• 1997

The effects of water-and oil-repellent finishes on the surface characteristics of polyester fabrics were investigated in this study. Three kinds of fluoropolyment were selected as water=and oil-repellent finishing agents. The effects of water-and oil-repellent finishes were determined by the water repellency and oil repellency. The surface properties of untreated and treated polyester fabrics were evaluated with respects to crease resistance, contact angle and wicking time. The results of this study were as follows: 1. The polyester fabrics treated with fluoropolymers showed much higher water repellency and oil repellency than those of untreated polyester fabrics. Water-and oil-repellency of fabrics were increased with the crystallinity and the hydrophobic-hydrophillic components of fluoropolymers. 2. Water repellency of fabrics treated with fluoropolymer with hydrophobic components was the highest. Oil repellency of fabrics treated with fluoropolymer with high crystallinity was the highest. Water-and oil-repellency of fabrics treated with fluoropolymer with hydrophyllic components was low comparatively. 3. The crease resistance of polyester fabrics treated with fluoropolymer nearly approached to that of untreated polyester fabric. 4. The water-and oil-repellent finishes improved contact angle markedly. Especially the contact angle of ployester fabric treated with fluropolymer with hydrophobic component was the biggest. 5. The wicking time of polyester fabric treated with fluropolymer with hydrophobic component was the longest.

• 한국의류산업학회지
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• 제22권1호
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• pp.112-118
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• 2020

This paper examined the water repellency, water proofing and water vapor permeability of twelve types of woven fabrics for sports wear clothing. Their physical properties were compared and discussed with the fabric structural parameters and surface finishing effect. A water repellent property of 100% was obtained in the coated or laminated water repellent finished fabrics; in addition, cotton/nylon breathable composite fabrics treated with a laminated finishing and with low fabric density showed a 90% water repellency. Water proofing fabric above 6,000 mm H₂O hydraulic pressure was achieved by coated or laminated finishing; however, high density fabric or medium-level coated fabrics exhibited 100% water repellent and low water proofing characteristics. Superior water vapor permeability characteristics with good water repellency and proofing properties were achieved at the 2.5 layered low density and with 0.7 - 0.9 cover factor nylon fabrics treated with hydrophilic laminated finishing. The regression analysis for examining the effects of fabric structural parameters and surface finishing such as coating and laminating to the water vapor permeability exhibited a high determination coefficient of fabric structural parameters of 63.5%; in addition,, main factors among fabric structural parameters appeared to be cover factor and fabric thickness per weight. Coating and Laminating factors exhibited determination coefficient of water vapor permeability parameters of 36.5%.

• 한국의류산업학회지
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• 제3권5호
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• pp.486-491
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• 2001

The purpose of this study was to examine the effects of chemical finishes on performance characteristics of microfiber blend fabrics. A 60% polyester microfiber/40% cotton blend woven fabric was finished by ten chemicals: three silicone softeners, one fluorochemical, and their mixtures. Performance characteristics examined were abrasion resistance, and oil/water repellency. Chemical finishes containing dimethylpolysiloxane silicone performed better in fabric abrasion resistance than other chemicals. The correlation between abrasion wear and instrumental measures of fabric hand indicated that the breaking strength loss by abrasion related negatively to the coefficient of friction. This implied that the finished fabrics with lower surface frictional coefficient (slipperier) had higher breaking strength loss by abrasion. The microfiber structure of polyester did not appear to help in oil/water repellency due to the larger surface areas of the microfibers. The fluorochemical finished fabric had the most significant improvement on oil/water repellency. The silicone-only finishes, however, did not improve oil/water repellency. When mixed with the fluorochemical, silicone finishes showed improved oil/water repellency.

• 한국의류학회지
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• 제19권2호
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• pp.317-328
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• 1995

The objective of this study was to determine the effects of low temperature plasma on the surface properties of polyester fabric with respect to wettability and water repellency. Highly wettable polyester fabric surfaces were obtained by oxygen treatment. The improved wettabililty of oxygen plasma treated fabrics decreased with aging time up to 30 days, and then the wettability remained relatively constant and still exhibited significant improvement compared to that of untreated polyester. Water repellency was significantly improved by tetratfluorocarbon plasma treatment. Such an improvement appears due to introduced fluo\ulcornerrine atoms or a thin fluorocarbon film on the fiber surface. Water repellency remained constant in fact, even after 150 days.

• 폴리머
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• 제31권1호
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• pp.31-36
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• 2007

플라스마 표면처리는 전체적인 물성은 유지하고 표면의 특성만을 변화시킨다고 전해지고 있다. 이번 연구에서는 플라스마 처리에 의해 높은 발수성을 나타내는 나일론 6 섬유로의 개질을 시도하였다. 발수성을 나타내는 나일론 섬유는 가스 종류, 처리시간, 인가 파워를 변수로 하여 RF 진공 플라스마 시스템에서 처리되었다. 플라스마 처리된 섬유의 표면을 scanning electron microscopy(SEM)과 atomic force microscopy(AFM)으로 모폴로지 변화를 살펴보았으며, 기계적 특성과 고분자 고유의 특성을 인장강도와 Differential scanning calorimetry(DSC), thermo-gravimetric analysis (TGA)로 각각 분석하였다. 또한 나일론 섬유의 발수성 평가는 물방울 흡수시간으로 테스트를 실시하였다. 이러한 결과들은 플라스마 표면처리로 인해서 나일론 섬유의 발수성이 향상됨을 나타내었다.

• 한국염색가공학회지
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• 제11권6호
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• pp.24-35
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• 1999

This study was carried out to investigate the changes of surface characteristics of polyester fabrics on the deposition and the removal of oily soils from polyester fabrics in detergency, The relations between the removal of soil and the changes of surface properties of polyester fabrics treated with water- and oil-repellent agents were discussed before and after various wash cycles. Two kinds of fluoropolymers were selected as water-and oil-repellent finishing agents. The effects of water- and oil-repellent finishes were determined by the water repellency and oil repellency. The surface properties of untreated and treated polyester fabrics were evaluated with respect to contact angle and wicking time. The treatment of polyester fabrics with fluoropolymers improved efficiently water repellency, oil repellency, contact angle and wicking time. But those properties were greatly decreased after 3 times of wash cycles in detergency The deposition of oily soils on the untreated fabrics was drastically increased with increasing of wash cycles. The deposition and the removal of oily soils from fabrics treated with fluoropolymer having hydrophobic components were very low after various wash cycles. The deposition and the removal of oily soils on the fabrics treated with fluoropolymer having hydrophilic components were high comparatively after various wash cycles. Even though the surface properties of treated fabrics were greatly decreased with the increasing of wash cycles, the remains of oily soils on the fabrics were lower than those of untreated fabrics in various wash cycles. But the remains of soils were drastically increased after 10 times of wash cycles in any cases.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.76-77
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• 2021

compared and reviewed the water repellency and strength characteristics by controlling the surface stamping size and fine aggregate ratio of cement mortar mixed with water repellent as a method to control the ecological imitation surface structure. As a result of measuring the contact angle, the higher the ratio of fine aggregate, the larger the contact angle. The contact angle increased when the surface structure was changed by stamping, and increased as the stamping size became smaller. In the surface stamping of mesh#150, the contact angle was particularly increased.

• 한국염색가공학회지
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• 제24권3호
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• pp.173-179
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• 2012

Silk fabric treated with fluorocarbon resins (Asahi Guard AG-7005 and AG-E061) were washed and subsequently heat treated varying the washing cycles and the temperature. After the processing, the water and oil repellencies, and contact angle to water were evaluated. The water and oil repellencies decreased by the washing and recovered by following heat treatment. Also ESCA measurement was carried out to investigate the surface chemical composition of the treated fiber. The $F_1s$ intensity of the treated fabric decreased by the washing and recovered by the subsequent heat treatment. On the other hand, the $O_1s$ intensity increased by the washing and decreased by following heat treatment. From the results, it is clear that change of the water and oil repellencies of the silk fabric treated with fluorocarbon resin occurred by the washing and subsequent heat treatment. Considering a change of the water repellency of the silk fabric treated with fluorocarbon resin, it seems likely that the fluoroalkyl group of the fluorocarbon resin rotates from surface to inside of the fiber by the washing to adapt to the hydrophilic circumstance, and the orientation of the fluoroalkyl groups of the resin disturbed by the washing recovers the orientation to the fiber surface after the subsequent heat treatment.

• 한국환경과학회지
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• 제13권10호
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• pp.947-953
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• 2004

Waterborne fluorinated acrylate copolymer (WFAC) for surface modification of textile was synthesized from perfluoroalkyl ethyl acrylate, octadecyl acrylate, glycidyl methacrylate, surfactant and 3,3 methyl-methoxy butanol. The structures of the synthesized WFAC were determinated by FT-IR and $^{19}F-NMR$ analysis. The thermal stability investigated with DSC and TGA was decreased with increasing the content of fluorinated acrylate in the copolymer. However, the particle sizes of WFAC were increased with increasing the content of fluorinated acrylate in the copolymer. The surface energies calculated by contact angles of WFAC were in the range of 29.80$\~$13.41 dyne/cm. On the observing SEM of the textile surface treated with WFAC, the textile was swollen and compacted with increasing the concentration of water repellency agent. WFAC synthesized in this study showed a good water repellency.

• 공업화학
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• 제33권6호
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• pp.588-593
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• 2022

MgO 입자 표면에 첨가된 P₂O₅의 가수분해, 발수성, 그리고 절연 거동에 미치는 영향을 조사하였다. MgO 표면에 첨가된 P₂O₅는 가수분해반응 억제와 발수성을 동시에 나타내기 때문에 독특한 절연거동을 나타내었다. 따라서 절연거동은 MgO의 표면수화반응에 의한 Mg(OH)₂와 OH^-전하 전달비와 친수성에 반비례하였다. 시효에 따른 MgO의 절연성은 표면수화반응, 첨가된 도펀트 종의 밴드갭, 그리고 도펀트의 친수성과 소수성에 강한 영향성과 의존성을 나타내었다. 마지막으로 친수성인 MgO의 표면수화반응을 억제하는 전기절연성을 발현하여 열전달매체 응용분야에서 큰 잠재력을 제공하는 것으로 나타났다.