• 한국콘텐츠학회논문지
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• 제17권7호
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• pp.294-302
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• 2017

본 연구에서는 잠재지문이 유류되어 있는 비다공성 또는 반다공성 검체를 CA 훈증하여 지문을 현출한 후 현출된 지문을 증강하기 위해 Rhodamine 6G를 사용하였다. 각기 다른 용매를 기반으로 조제한 두 종류의 Rhodamine 6G 용액 중 어떤 것이 더욱 효과적으로 지문을 증강할 수 있는지 알아보고자 하였다. 실험에 사용한 일곱 종류의 표면 모두 유기용매 기반 Rhodamine 6G보다 수용성 기반 Rhodamine 6G를 사용하였을 때 지문이 잘 증강되고 배경 염색도 적었다. 그러나 실제 현장에서 수집되는 감식 대상은 다양한 표면 재질과 색상을 가지는 한계점이 있으므로 이를 바탕으로 추후 연구가 필요할 것으로 사료된다.

• 한국염색가공학회지
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• 제24권3호
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• pp.158-164
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• 2012

Rhodamine dyes belong to xanthene family has excellent photostability and photophysical properties. In rhodamine dyes, Rhodamine 6G and its precursors also have xanthene chromophore and it shows high fluorescent quantum yield. Rhodamine 6G derivates are simple to synthesis and its high sensitivity and water solubility are suitable as good chemosensor. In this regard, Rhodamine 6G derivates which have selectivity to specific metal cation can used to detect various heavy metal ions. In this study, rhodamine 6G derivatives were synthesized by reaction of rhodamine 6G hydrazide and glyoxal and 4-phenyl thiosemicarbazide and it showed colorimetric and fluorescence sensing toward $Hg^{2+}$ ion. This novel chemosensor was analyzed and measured on UV-Vis and fluorescence spectrophotometer. HOMO/LUMO values were also calculated by computational calculation.

• Bulletin of the Korean Chemical Society
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• 제30권6호
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• pp.1252-1256
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• 2009

A simple, selective and sensitive fluorescence quenching method was developed to the determination Cr(VI). The method is based on the oxidation of $I^-\;to\;{{I_3}^-}$ by Cr(VI) in sulfuric acid solution followed by immediate formation of ion association compound between I3 − and rhodamine 6G in Tween-80 micellar media at room temperature. The influence of several surfactants on rhodamine 6G fluorescence signal was studied; particular attention was paid in the aggregation behavior of rhodamine 6G–Tween-80 system. The experimental parameters (e.g., type of surfactant, reagent concentration) were studied and the optimal conditions were established. The linear calibration graph was obtained in the range 2.0 - 100.0 ng m$L^{-1}$ Cr(VI). The detection limit of the method was 0.37 ng m$L^{-1}$. The relative standard deviation (R.S.D.) is less than 5% (n = 5). The efficiency of the method for the determination of Cr(VI) in the presence of Cr(III) in the sample was investigated. The method was applied successfully to the determination of Cr(VI) and total Cr in water, and liver tissue samples.