• Title/Summary/Keyword: Water treatment agent

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A study of struvite control using CO2 in sewage treatment process (하수처리공정에서 이산화탄소를 이용한 스트러바이트 제어에 관한 연구)

  • Han, Keumseok;Hong, Seongho;Choi, Youngjune
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.3
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    • pp.261-268
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    • 2018
  • Sludge transporting pipes in wastewater treatment plant are easy to be clogged with struvite when the digested sludge and dehydrated filtrate are transported through the pipes, which lowers the efficiency of sludge treatment system in a WWTP. pH is one of the most important factors in struvite formation, and carbon dioxide separated from biogas can be used to control pH and struvite formation. By controlling pH, the amount of dehydrating agent can be reduced by about 10%, which saves the budget for facility maintenance. As $CO_2$ is reused and dehydrating chemicals are saved, the approach can contribute to global warming gas reduction.

Evaluation of Corrosion Product Behavior in NPP Secondary System with Complex Amine (복합아민 적용에 따른 원전 2차 계통 부식생성물 거동평가)

  • JUNG, Hyunjun;RHEE, In Hyoung;Kim, Young In
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.96-99
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    • 2014
  • The aim of the study was to evaluate the water treatment of pressurized water reactor secondary side by the mixed amine of ammonia and ethanolamine, from the standpoint of corrosion control, as compared with all volatile treatment of ammonia. The pressurized water reactor systems have switched a secondary side pH control agent to minimize the corrosion in the moisture separator/reheater and feedwater heater systems and the transport of corrosion products into steam generator. As results of field test, pH was increased in the steam generator and the wet steam area of moisture separator/reheater and the concentration of Fe were decreased by more than 50% as compared with water treatment of ammonia.

Water Absorption of Wood Flour-Polypropylene Composites: Effects of Wood Species, Filler Particle Size and Coupling Agent (목분-폴리프로필렌 복합재의 수분흡수율 : 목재수종, 충진제 입자크기 및 상용화제의 영향)

  • Kang, In-Aeh;Lee, Sun-Youn;Doh, Geum-Hyun;Chun, Sang-Jin;Yoon, Seung-Lak
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.4
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    • pp.298-305
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    • 2010
  • The effects of wood species, chemical components, filler loading level, filler particle size, and coupling agent on the water absorption property of the wood flour filled polypropylene (PP) composites were investigated in this study. After 500, 1,000, 1,500, 2,000, 2,500 and 3,000 hr water immersion, Quercus (Quercus accutisima Carr.) and Maackia (Maackia amuresis Rupr. et Maxim) showed significantly lower water absorption properties compared to Larix (Larix kaempferi Lamb.). As wood flour loading increases from 10 to 50 wt%, most wood species showed increased water absorption after a given immersion period. Particle size of wood flour proved to have very significant effects on water absorption of the composites. The effect of coupling agent was positive in terms of lowering water absorption of the composites. As the treatment level of coupling agent increases, the water absorption of the composites decreases. The lowest water absorption was obtained at the lower wood flour loading (Maackia), smaller particle size and by the addition of coupling agent. Thickness swelling of the composites shows close dependency on water absorption.

Study on the Removal of Fluorescent Whitening Agent by Pretreatment Ozone Oxidation for MBR Process Application (MBR 공정 적용을 위한 전처리 오존산화에 의한 형광증백제 제거 연구)

  • Choi, Jang-Seung;Ryu, Seung-Han;Shin, Dong-Hun;Lee, Jae-Hun;Lee, Soo-Chol;Kim, Sung-Gi;Ryu, Jae-Young;Shin, Won-Sik;Lee, Seul-Ki;Park, Min-Soo
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.11-17
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    • 2017
  • In this study, ozone oxidation experiment was carried out for the removal of fluorescent whitening agent which is widely used in textile dyeing and paper industry. The stilbene fluorescent whitening agent has been industrialized since the earliest, and the amount of current production is the highest. Due to the characteristics of the fluorescent whitening agent that can not be removed by conventional wastewater treatment methods, the fluorescent whitening agent in wastewater treatment has difficulty in using as recycled water in the process. Pre-treatment ozone oxidation experiment was conducted prior to the introduction of Membrane Bio Reactor(MBR) treatment process by converting biodegradable materials into biodegradable materials. The removal efficiencies of fluorescent whitening agents, a diaminostilbenedisulfonic acid derivative by ozone oxidation were evaluated by $UV_{254}$ Scan, $COD_{Mn}$, T-N and color using a synthetic wastewater sample ($COD_{Mn}=433.0mg/{\ell}$) and paper and paper mill wastewater ($COD_{Mn}=157.2mg/{\ell}$).

Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(II) - Application Methods of Chemicals for Improving Water and Moisture Resistance of Corrugated Boards - (농산물 저온유통용 내수 골판지 상자의 제조(제2보) - 골판지의 내수 및 내습성 향상을 위한 약품 적용 방법 -)

  • Jo, Jung-Yeon;Min, Choon-Ki;Shin, Jun-Seop
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2004.04a
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    • pp.192-210
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    • 2004
  • Application methods of chemicals were investigated tn minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stain hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stain hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

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Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(II). -Application Methods of Chemicals for Improving Water and Moisture Resistance of Corrugated Boards- (농산물 저온유통용 내수 골판지 상자의 제조(제2보) - 골판지의 내수 및 내습성 향상을 위한 약품 적용 방법 -)

  • 조중연;민춘기;신준섭
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.2
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    • pp.60-69
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    • 2004
  • Application methods of chemicals were investigated to minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stein hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stein hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

Improvement of Water Treatment Efficiency by pH Decreasing Agent (H2SO4) for Droughty Seasons (갈수기 정수장운영관리 사례 - 갈수기 pH저감제(황산)투입에 의한 정수처리효율 향상)

  • Ka, Gilhyun;Kim, Yunyung;Lee, Junho;Ahn, Chihwa;Han, Ihnsup;Min, Byungdae
    • Journal of Korean Society on Water Environment
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    • v.24 no.4
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    • pp.415-422
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    • 2008
  • Drinking water treatment is enhanced by coagulant dosages and chlorine injection because of pH increase in raw water in droughty seasons such as spring and fall. But water quality deterioration is occurred by increase in residual aluminium and disinfection by-products. Coagulation process can be used to control natural organic matter (NOM) during water treatment. The effect of coagulation process appeared to depend on the pH of water rather than coagulant dosages. In this study, for water treatment in high pH season $H_2SO_4$ was applied for pH adjustment at full scale. Before and after pH adjustment by $H_2SO_4$ injection, water quality of drinking water was evaluate. In the result of investigation of total organic carbon (TOC) removal in high pH season, TOC was removed approximately 30~40%, which showed decrease in water treatment efficiency. Also, it is increased both particle numbers and residual Al concentration in the water. After $H_2SO_4$ injection for adjustment to pH<7.5 in settled water, treated water turbidity decreased in 0.047 NTU from 0.059 NTU, and particle numbers of filtered water decreased in 20/mL from 90/mL. On the other side, TOC removal efficiency increased in approximately 10% after adjustment of pH. In the result of decrease in pH in raw water through more coagulants and prechlorine without $H_2SO_4$ injection, trihalomethanes (THMs) concentration increased in $16{\mu}g/L$ from $8{\mu}g/L$.

Mechanical Properties of Carbon Fiber/Nylon 6 Composite Introducing Coupling Agent (II) -Increasing Interfacial Strength of Composite- (카플링제를 도입한 탄소섬유/나일론 6 복합재료의 기계적 성질(II) -복합재료의 계면강도 증가-)

  • Park, Chan Hun;Lee, Yang Hun;Shin, Eun Joo
    • Textile Coloration and Finishing
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    • v.9 no.4
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    • pp.47-53
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    • 1997
  • To improve the interfacial bonding of carbon fiber-nylon 6 composite, carbon fiber(CF) were oxidized by nitric acid treatment, and two types of graft polymer(GP) of nylon 6-g-polyacrylamide (PAAm) -water dispersable GP(WDGP) and m-cresol solu ble GP(CSGP) were treated as coupling agents. Introduction of polar groups such as -COOH, -OH, etc, on the surface of the oxidized CF was confirmed by IR spectra. The stem polymer of nylon 6 in the coupling agent (GP) could be compatible with'matrix nylon 5, and the grafted branch of PAAm on GP could react to the polar groups on the oxidized CF in composite. The interfacial strength was measured by the transverse tensile test to the fiber direction for single CF embedded nylon 6 film especially prepared and by the pull-out test method. The interfacial strength of the composite reinforced with oxidized CF is greater than that reinforced with unoxidized CF. The interfacial strength of the composite was increased by treatment of coupling agents(GPs) considerably, and the increasing tendency by the WDGP is greater than that by the CSGP. The optimum conditions of coupling agent treatment are as follows: the concentration, adsorption tlme of GP, and curing temperature are 2%, 20 minutes, and $170^{\circ}$, respectively.

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Material Properties of Ultra Rapid Hardening Mortar for Repairing Sewage Treatment Concrete Pipes (콘크리트 하수관거 보수용 초속경 수중불분리 모르타르의 재료적 특성)

  • Lee, Byungjae;Lee, Sunmok;Bang, Jin-wook;Kim, Yun-yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.57-62
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    • 2020
  • Among the sewage pipes installed in Korea, the length of concrete pipes exceeding 20 years is 66,334 km (42.5%). Deteriorated concrete sewer pipes need to be repaired due to the leakage of internal sewage, which causes problems such as sink holes by expanding the cavity around the pipeline. In this study, we tried to apply anti-washout underwater mortar with ultra rapid hardening cement and segregation reducing agent to sewage pipe repair. As a result of the setting time test, the final set time was delayed by up to 172% by incorporating segregation reducing agent. In the test for measuring the degree of mortar segregation in water, it was measured at pH 12 or less under all mixing conditions. In addition, the suspension amount was measured to be 50 mg / l or less to satisfy the KCI-AD102 standard by incorporating a segregation reducing agent. In terms of the average value of mortar compressive strength, by incorporating segregation reducing agent, the strength of the specimens produced in air was more than 80% of that of the specimens produced in water. Conversely, the bond strengths of the specimens produced in water were measured to be higher than those of the specimens produced in air. Water resistance was evaluated by measuring water absorption and water permeability. Water absorption and water permeability were reduced by 42.6% and 36.6%, respectively, by mixing segregation reducing agent.

Chemical cleaning effects on properties and separation efficiency of an RO membrane

  • Tu, Kha L.;Chivas, Allan R.;Nghiem, Long D.
    • Membrane and Water Treatment
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    • v.6 no.2
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    • pp.141-160
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    • 2015
  • This study aims to investigate the impacts of chemical cleaning on the performance of a reverse osmosis membrane. Chemicals used for simulating membrane cleaning include a surfactant (sodium dodecyl sulfate, SDS), a chelating agent (ethylenediaminetetraacetic acid, EDTA), and two proprietary cleaning formulations namely MC3 and MC11. The impact of sequential exposure to multiple membrane cleaning solutions was also examined. Water permeability and the rejection of boron and sodium were investigated under various water fluxes, temperatures and feedwater pH. Changes in the membrane performance were systematically explained based on the changes in the charge density, hydrophobicity and chemical structure of the membrane surface. The experimental results show that membrane cleaning can significantly alter the hydrophobicity and water permeability of the membrane; however, its impacts on the rejections of boron and sodium are marginal. Although the presence of surfactant or chelating agent may cause decreases in the rejection, solution pH is the key factor responsible for the loss of membrane separation and changes in the surface properties. The impact of solution pH on the water permeability can be reversed by applying a subsequent cleaning with the opposite pH condition. Nevertheless, the impacts of solution pH on boron and sodium rejections are irreversible in most cases.