• Title/Summary/Keyword: Water sorption

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A Study on the Pore Structure of Hardened Alumina Cement Pste by Water Vapor Sorption ($H_2O$ 증착법에 의한 알루미나 시멘트 경화체의 기공구조 연구)

  • 임용무;장복기
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.273-278
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    • 1993
  • Using water vapor (de)sorption isotherm, pore structure analyses were performed for hardened cement pastes by a combination of the "MP-method" for the micropores and the "corrected modelless method" for the wide pores. This work was carried out to investigate the pore structure and to understand the microstructural basis of alumina cement developing much higher strength than Portland cement. Alumina cement shows extremely low microporosity and its wide pores are also composed mainlyof pores with very small radii. And the pore structure analysis results are consistent with the high strength property of alumina cement.y of alumina cement.

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The Effect of Lactic-fermentation on the Quality of Peanut Milk (젖산발효가 땅콩유의 품질에 미치는 영향)

  • Lee, Chan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.3
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    • pp.439-443
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    • 2001
  • The effect of fermentation of peanut milk with lactic acid bacteria on n-hexanal content was investigated. Changes in pH, titratable acidity and viable cell populations indicated that Streptococcus salivarius subsp. thermophilus was adapted better than Lactobacillus delbrueckii subsp. bulgaricus during fermentation. Analysis of headspace volatiles revealed that n-hexanal, which is one of the compounds responsible for undesirable green/beany flavor in peanut milk, completely disappeared as a result of fermentation. S. salivarius subsp. thermophilus was more effective than L. delbrueckii subsp,. bulgaricus in reducing the n-hexanal content. No significant difference was found in water sorption between fermented and unfermented peanut milk.

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Effect the of Sugar on Physical Properties of Ginseng Ted Granules (첨가당류가 인삼차 과립의 물리적 특성에 미치는 영향)

  • 양재원;성현순
    • Journal of Ginseng Research
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    • v.5 no.2
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    • pp.132-138
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    • 1981
  • The effect of sugars, mixing ratio between a sugar and ginseng extract, and moisture content on the physical properties of ginseng tea granules such as water sorption and coagulation phase were investigated The physical Properties of granule were significantly affected by the moisture cogent, a kind of sugars and amount of ginseng extract used in the preparation. The granules contained less than 1.0%moisture and 14.0% of ginseng extract were not affected on the properties, however, it was significantly affected when the moisture content was 1.5 ${\pm}$ 0. 2 % and the ginseng extract was more than 18%. In the preparation with simple sugar, it was significantly decreased water sorption and coagulation phase when lactose used instead of anhydrous glucose. It was also observed that the Properties were decreased as the amount of lactose increased in the preparation of granules with mixing sugars.

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Characteristics of arsenic sorption on furnace slag in groundwater

  • S. R. Kanel;Saurabh Sharma;Park, Hechul
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.96-98
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    • 2002
  • Furnace slag, a steel industry waste, has been converted into an inexpensive and efficient adsorbent. The product obtained has been utilized for the removal of arsenic from ground water. Kinetic studies have bepn described with the mechanism of adsorption The results from batch studies showed that the As(III) can be removed from the ground water within the pH range 3-7 However the maximum removal was experienced at pH 7.0. Equilibrium was attained within 24 hours. Adsorption data of arsenic correlate well with the Freundlich and Langmuir adsorption models. The maximum sorption capacity as calculated using Freundlich adsorption isotherm was found to be of 0.004 mg g-1 at pH 7 and $25^{\circ}C$.

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A Study on the Adsorption of Organophosphorus Pesticides Applying Sewage Sludge to Soil Amendment (하수슬러지의 토양개량재 적용시 유기인계 농약의 흡착 능력에 관한 연구)

  • 임은진;이재영
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.95-103
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    • 2004
  • This study has been assessed the influence of applying sewage sludge to soil amendments on the sorption properties, and leaching potential of three commonly used organophosphorus pesticides, Diazinon, Fenitrothion, and Chlorpyrifos. A sandy soil with a low content of organic carbon was treated with sewage sludge with a ratio sandy soil sludge ratio of 30:1. The sorption was determined with the batch equilibrium technique. The sorption isotherms could be described by Freundlich equation. The Freundlich constant, K value which measures sorption capacity, were 3.97, 9.94, 22.48 for Diazinon, Fenitrothion, Chlorpyrifos in non-amended soil. But in amended soil, K value was 12.58, 28.47, and 61.21 for Diazinon, Fenitrothion, and Chlorpyrifos. The overall effect of sewage sludge addition to soil was to increase pesticides adsorption, due to the high sorption capacity of the organic matter. The effect of sludge on the leaching of pesticides in the soil was studied using packed soil columns. Total recoveries of pesticides in soil and leachate with leaching in soil column, were in the range of about 73∼84%, was reduced with the passage of time. Diazinon moved more rapidly than Chlorpyrifos in the unamended soil due to greater sorption and lower water solubility of Chlorpyrifos. Total amounts of pesticides leached from the sewage sludge amended soils were significantly reduced when compared with unamended soils. This reduction may be mainly due to and increase in sorption in amended soils, as a consequence of the increase in the organic matter content.

The Interference of Organic Matter in the Characterization of Aquifers Contaminated with LNAPLs by Partitioning Tracer Method (LNAPLs 오염 지반에 분배성 추적자 시험법 적용 시 유기물질의 영향에 관한 연구)

  • Khan, Sherin Momand;Rhee, Sung-Su;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.24 no.9
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    • pp.13-21
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    • 2008
  • Partitioning tracer method is a useful tool to characterize large domains of the aquifers contaminated with light nonaqueous phase liquids (LNAPLs). Sorption of the partitioning tracers to the organic matter content of soil can potentially influence the efficacy of partitioning tracer method. LNAPL-water partitioning coefficients of tracers ($K_{nw}$), measured by static method, showed linear relationship. Sorption isotherm tests were conducted to evaluate the sorption capacity of the soils packed in the columns and the results were appropriately represented by Freundlich sorption isotherm. The sorption of tracers proportionally increased with the increase of the organic matter content of the soil. Laboratory experiments were conducted in four columns each packed with soils of different organic matter contents to determine the potential interference effects of sorption to soil organic matter content and correction factors for the errors in estimation of LNAPLs by partitioning tracer method. Though there were no contaminants added, breakthrough curves from columns packed with mixture of Jumunjin standard sand and organic matter showed separation of tracers. Columns were then contaminated to residual saturation with kerosene and breakthrough curves were obtained. The results show that sorption of tracers to soil organic matter leads to an increase in the retardation factor (R) and hence, to an overestimation of the saturation of LNAPLs. A relation between the percentage of organic matter content and the corresponding percentage error in the estimation of NAPLs has been developed.

Adsorption and Transfer of Trace Elements in Repellent Soils (토양 소수성에 따른 미량원소의 흡착 및 이동)

  • Choi, Jun-Yong;Lee, Sang-Soo;Ok, Yong-Sik;Chun, So-Ul;Joo, Young-Kyoo
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.204-208
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    • 2012
  • Water repellency which affects infiltration, evaporation, erosion and other water transfer mechanisms through soil has been observed under several natural conditions. Water repellency is thought to be caused by hydrophobic organic compounds, which are present as coatings on soil particles or as an interstitial matter between soil particles. This study was conducted to evaluate the characteristics of the water repellent soil and transport characteristics of trace elements within this soil. Capillary height of the water repellent soil was measured. Batch and column studies were accompanied to identify sorption and transport mechanism of trace elements such as $Cu^{2+}$, $Mn^{2+}$, $Fe^{2+}$, $Zn^{2+}$ and $Mo^{5+}$. Difference of sorption capacity between common and repellent soils was observed depended on the degree of repellency. In the column study, the desorption of trace elements and the spatial concentration distribution as a function of time were evaluated. The capillary height was in the repellency order of 0% > 15% > 40% > 70% > 100%. No water was absorbed in soil indicating >70% repellency. Using trace elements, $Fe^{2+}$ and $Mo^{5+}$ showed higher sorption capacity in the repellent soil than in non-repellent soil. The sorption performance of $Fe^{2+}$ was found to be in the repellency order of 40% > 15% > 0%. Our results found that transfer of $Mo^{5+}$ had similar sorption tendency in soils having 0%, 15% and 40% repellency at the beginning, however, the higher desorption capacity was observed as time passes in the repellent soil compared to in non-repellent soils.

Preparation and Swelling Properties of Poly(potassium acrylate-co-acrylamide) Superabsorbent Particles (폴리(아크릴산 포타슘-co-아크릴아마이드) 고흡수성 입자의 제조 및 팽윤 특성)

  • 손오건;심상준;이동현;이영관;김지홍;김덕준
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.18-23
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    • 2004
  • Superabsorbent poly(potassium acrylate-co-acrylamide)s were synthesized in particle form using inverse suspension polymerization technique. Mean diameter of the prepared polymer particles decreased from 300 to 50 $\mu\textrm{m}$ with increasing surfactant concentration. The dynamic and equilibrium swelling behaviors during water absorption and drying process were investigated by weight measurement. The swelling ratio of polymer particles in water changed according to not only polymer crosslinking density, but particle size, saline concentration of aqueous medium, and copolymer compositions. Water sorption amount was increased with decreasing particle size, crosslinking agent concentration, and ion concentration in bulk solution. Being different from the water sorption process, the drying process was not significantly affected by particle size, polymer composition, or crosslinking amount.

Removal of Cu (II) and Cd (II) Ions Onto Water Hyacinth Based Carbonaceous Materials

  • Amina, A. Attia;Shouman, Mona.A.;Khedr, S.A.;El-Nabarawy, Th.
    • Carbon letters
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    • v.7 no.4
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    • pp.249-258
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    • 2006
  • Treatment of water hyacinth with sulphuric acid produces carbonaceous materials that have been used to remove Cu(II) and Cd (II) ions from aqueous solutions. Untreated water hyacinth was also used for the subject of comparison. The textural properties of the carbonaceous materials were determined from nitrogen adsorption at 77 K. The optimum pH for the sorption of Cu (II) and Cd (II) ions on the investigated sorbents was determined. Dynamic adsorption measurements have been taken at 298 K whereas equilibrium measurements were carried out at 298, 313 and 323 K. The adsorption of nitrogen at 77 K on the untreated sample was too low and the surface areas of the treated samples 2, 3 and 4 were found between $70-208\;m^2/g$. The total pore volumes of these samples which were determined for the carbonaceous materials investigated were found to be 0.076-0.140 ml/g. The kinetic adsorption data of Cu (II) and Cd(II) were applicable to both pseudo - first and pseudo-second order but fit more the latter order. The equilibrium adsorption data were found to fit Freundlich and Langmiur equations. The values of DG, DH and DS are all negative indicating the feasibility and the spontaneous nature of the sorption of Cu (II) and Cd (II) ions by the sorbents investigated.

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PHYSICAL PROPERTIES OF RELINING DENTURE BASE RESINS WITH DIFFERENT POLYMERIZING METHODS (중합방법이 다른 의치상 이장용레진의 물리적 특성)

  • Cho Suck-Kyu;Song Kwang-Yeob;Yoon Soo-Yun;Kim Mun-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.4
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    • pp.386-395
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    • 2002
  • This study would like to measure and compare water sorption and solubility of acrylic resins, with 3 different polymerizing methods, and tensile strength between denture base resin and relining rosins. For this experiment, 3 different acrylic resins were used; heat polymerizing resin: Vertex (Dentmex, Zeist, Holland), autopolymerizing resin: Tokuso Rebase (Tokuyama Corp, Tokyo, Japan), and light curing resin: Mild Rebaron LC(GC Corp, Tokyo, Japan) The results were as follows ; 1. Tokuso Rebase showed the lowest water sorption. followed by Mild Rebaron LC and Vertex. Among resins, there were some signigicant differences (P<0.05). 2. Vertex showed the lowest solubility, followed by Mild Rebaron LC and Tokuso Rcbase. Among resins, there were some signigicant differences (P<0.05). 3. Intact Vertex showed the highest tensile strength, and Mild Rebaron LC had a more tensile strength than Tokuso Rebase. Between Vertex and the other resins, there were some signigicant differences (P<0.05) However, between Mild Rebaron LC and Tokuso Rebase, there was no statistical difference (P>0.05). About 50% of Rebaron LC showed cohesive fracture. 4. Tensile strength has more decreased after thermocycling than before, but there was no statistical difference (P>0.05).