• Title/Summary/Keyword: Water quality characterization

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High performance pervaporative desalination of saline waters using Na-X zeolite membrane

  • Malekpour, Akbar;Nasiri, Hamed
    • Membrane and Water Treatment
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    • v.8 no.5
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    • pp.437-448
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    • 2017
  • A high quality Na-X zeolite membrane was synthesized on a seeded ${\alpha}-alumina$ disc by the secondary growth method. Structural characterization was done by X-ray spectroscopy, FT-IR spectroscopy, SEM and AFM imaging. The performance evaluation of the membrane was firstly tested in separation of glucose/water solutions by pervaporation process. There was obtained a separation factor $182.7{\pm}8.8$, while the flux through the membrane was $3.6{\pm}0.3kg\;m^{-2}\;h^{-1}$. The zeolite membrane was then used for desalination of aqueous solutions consisting of $Na^+$, $Ca^{2+}$, $Cs^+$ and $Sr^{2+}$ because of the importance of these ions in water and wastewater treatments. The effects of some parameters such as temperature and solution concentration on the desalination process were studied for investigating of diffusion/adsorption mechanism in membrane separation. Finally, high water fluxes ranged from 2 up to $9kg\;m^{-2}\;h^{-1}$ were obtained and the rejection factors were resulted more than 95% for $Na^+$ and $Ca^{2+}$ and near to 99% for $Cs^+$ and $Sr^{2+}$. Based on the results, fluxes were significantly improved due to convenient passage of water molecules from large pores of NaX, while the fouling was declining dramatically. Based on the results, NaX zeolite can efficiently use for the removal of different cations from wastewaters.

Risk assessment of wastewater reuse for Irrigation water (하수처리수의 관개용수 재이용을 위한 위해성 평가)

  • Han, Jung-Yoon;Yoon, Chun-Gyeong;Jung, Kwang-Wook;Jang, Jae-Ho
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.661-666
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    • 2005
  • Wastewater reuse are exposed public health risk by pathogens. Therefore, this study was examined for microbial risk assessment after irrigation as treated wastewater in paddy rice plots. Five treatments were used: biofilter effluent, UV disinfected water, pond treatment, wetland treatment and conventional irrigation water. Risk assessment was calculated based on the beta-Poisson model by concentration of E. coli from 2003 to 2005. Monte-Carlo simulation (n=10,000) was used to estimate the risk characterization of uncertainty. The risk range was from $10^{-5}$ to $10^{-8}$ except biofilter effluent was $10^{-4}$ in June. The USEPA(1992) has recommended that risk of < $10^{-4}$ is acceptable level of safety for potable waters. In 2005, risk value was lower than 2003, 2004 because of the first irrigation for plowing water is lower E. coli concentration used tap water. It is shown that the first irrigation water quality was important for wastewater irrigation in paddy. UV disinfection and natural treatment used pond and wetland were thought to be an effective for wastewater reuse.

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Characterization of Combined Sewer Overflows from a Small Urban Watershed and Determination of Optimum Detention Volume (소규모 도시유역 합류식 하수관거 월류수 특성화 및 최적 저류지 용량 결정)

  • Jo, Deokjun;Kim, Geonha
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.314-320
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    • 2006
  • Diffuse pollution from an urban area contributes to the significant pollution loading to a receiving water body. In this paper, rainfall runoffs from an urban basin with combined sewer systems located in the city of Daejeon were monitored to measure the rainfall runoff discharge rates and pollutant concentrations. Strong first flush effects were observed for all monitored rainfall runoffs. The first flush effects were closely related to rainfall intensity, while suspended solids were closely related to pollutant constituents. The observed averaged Event Mean Concentrations (EMCs) of Combined Sewer Overflows (CSOs) were 536.1 mg SS/L, 467.7 mg CODcr/L, 142.7 mg BOD/L, 16.5 mg TN/L, and 13.5 mg TP/L. Storage volumes for containing the first flush to improve water quality of the receiving stream can be estimated based on suspended solid concentration. In this study, retainment of the first flush equivalent to 5mm of precipitation could reduce diffuse pollution loading induced by CSOs to a receiving water body by up to 80% of suspended solid loading.

Characterization of Agarose Product from Agar Using DMSO

  • Jeon, You-Jin;Athukorala, Yasantha;Lee, Je-Hee
    • ALGAE
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    • v.20 no.1
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    • pp.61-67
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    • 2005
  • Agar was extracted from Gelidium amansii, which was harvested at the shores of Jeju Island in South Korea. As a unique solvent, the ability of dimethyl sulfoxide (DMSO) was used to separate agarose from agar by removing agaropectine and quality of the resultant agarose was characterized for chromatography purposes. Agar sample was agitated by motor-driven stirrer with DMSO in a water bath (at 70$^{\circ}C$ for 2 h) and centrifuged (3,000 rpm for 20 min). Resultant upper agarose layer was gelled, washed, dried and milled. The quality of agarose was evaluated by the analysis of proximate chemical composition, sulfate content, gelling strength and DNA migration. In this study, the separated agarose showed low sulfate amount (0.28%) and showed high gel strength (1190 g ${\cdot}\;cm^{-2}$). The resolution power and the ligase activities gave clear picture about the suitability of the present agarose for practical purposes.

Comparison of hydrochemical informations of groundwater obtained from two different underground storage systems

  • Lee, Jeonghoon;Kim, Jun-Mo;Chang, Ho-Wan
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.110-113
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    • 2002
  • Statistical- based, principal component analysis (PCA) was applied to chemical data from two underground storage systems containing LPG to assess the usefulness of such technique at the initial stage (Pyeongtaek) or middle stage (Ulsan) of hydrochemical studies. For the first case, both natural and anthropogenic contamination characterize regional groundwater. Saline water buffered by Namyang lake affects as a natural factor, whereas cement grouting influence as an artificial factor. For the second study area, contaminations due to operation of LPG caverns, such as disinfection activity and cement grouting effect, deteriorate groundwater quality. This study indicates that principal component analysis would be particularly useful for summarizing large data set for the purpose of subsurface characterization, assessing their vulnerability to contamination and protecting recharge zones.

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Potential Use of Biopolymer-based Nanocomposite Films in Food Packaging Applications

  • Rhim, Jong-Whan
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.691-709
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    • 2007
  • Concerns on environmental waste problems caused by non-biodegradable petrochemical-based plastic packaging materials as well as consumer's demand for high quality food products has caused an increasing interest in developing biodegradable packaging materials using annually renewable natural biopolymers such as polysaccharides and proteins. However, inherent shortcomings of natural polymer-based packaging materials such as low mechanical properties and low water resistance are causing a major limitation for their industrial use. By the way, recent advent of nanocomposite technology rekindled interests on the use of natural biopolymers in the food packaging application. Polymer nanocomposites, especially natural biopolymer-layered silicate nanocomposites, exhibit markedly improved packaging properties due to their nanometer size dispersion. These improvements include increased mechanical strength, decreased gas permeability, and increased water resistance. Additionally, biologically active ingredients can be added to impart the desired functional properties to the resulting packaging materials. Consequently, natural biopolymer-based nanocomposite packaging materials with bio-functional properties have huge potential for application in the active food packaging industry. In this review, recent advances in the preparation and characterization of natural biopolymer-based nanocomposite films, and their potential use in food packaging applications are addressed.

Characterization of Beef Transcripts Correlated with Tenderness and Moisture

  • Kee, Hyun-Jung;Park, Eung-Woo;Lee, Cheol-Koo
    • Molecules and Cells
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    • v.25 no.3
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    • pp.428-437
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    • 2008
  • To identify transcriptional markers for beef traits related to meat tenderness and moisture, we measured the transcriptome of the Longissimus dorsi skeletal muscle in 10 Korean native cattle (KNC). We analyzed the correlation between the beef transcriptome and measurements of four different beef traits, shear force (SF), water holding capacity (WHC), cooking loss (CL), and loin eye area (LEA). We obtained non-overlapping and unique panels of genes showing strong correlations (${\mid}r{\mid}$ > 0.8) with SF, WHC, CL, and LEA, respectively. Functional studies of these genes indicated that SF was mainly related to energy metabolism, and LEA to rRNA processing. Interestingly, our data suggested that WHC is influenced by protein metabolism. Overall, the skeletal muscle transcriptome pointed to the importance of energy and protein metabolism in determining meat quality after the aging process. The panels of transcripts for beef traits may be useful for predicting meat tenderness and moisture.

Microbiological Characterization and Chlorine Treatment of Buckwheat Sprouts (메밀 새싹채소의 주요 내재미생물 분석 및 염소처리에 따른 품질변화)

  • Lee, Hyun-Hee;Hong, Seok-In;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.452-457
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    • 2009
  • In order to secure microbiological safety and quality of commercial vegetable sprouts, buckwheat seeds and sprouts were investigated for their microbiological flora and for the effect of chlorine treatment on quality. Microbiological analyses showed that major inherent bacteria including Enterobacter, Sphingomonas, and Klebsiella were found in commercial buckwheat sprouts with a population size ranging from $10^5$ to $10^7$ CFU/g. In addition, buckwheat seeds had a similar microbial flora to sprouts. Foodborne pathogenic bacteria such as Escherichia coli O157:H7, Staphylococcus aureus, Salmonella Typhimurium, and Listeria monocytogenes were not detected in the sprout or in the seed samples. Chlorine treatment with 50-150 ppm sodium hypochlorite noticeably reduced viable bacteria cell counts of the sprouts by about 1 log. However, no significant difference was observed among the different chlorine concentrations. After storage for 7 days at $5^{\circ}C$, the sprouts treated with 100-150 ppm chlorine showed higher sensory scores in visual quality than the others (p<0.05). The results indicated that proper pretreatment, such as dipping in chlorinated water, could confer a beneficial effect on the microbiological safety and visual quality of buckwheat sprouts.

The development of near infrared calibrations for assessing grass herbage quality

  • Sharma, Hss;Mellon, R.;Johnson, D.;Fletcher, H.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1611-1611
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    • 2001
  • The main selection parameters used by forage grass (rye and Italian rye grass) breeders are dry-matter yield, seasonal growth, persistency, disease resistance, heading date, and heading. These characteristics can all be identified usually in the segregating F2 population, however characteristics such as soluble carbohydrate level, protein, lipid and digestibility cannot be identified. The emphasis of this work is to introduce a quantitative selection process for characterization of herbage quality e.g. protein, water-soluble carbohydrates, fiber fractions, dry matter digestibility. NIRS calibrations are currently being developed for identifying grass genotypes to assist the selection process, thereby allowing the opportunity to actively breed improved herbage quality. The changes in fibre fractions, associated components and digestibility of a number of grass clones at different growth stages are being assessed changes taking place during a growing season. This will provide a database of the major changes taking place during a growing season. Attempts to classify quality differences between genotypes will be carried out using multivariate analysis of the spectral data. I addition changes associated with maturity of grass will be considered in order to develop robust calibrations.

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Influence of Groundwater on the Hydrogeochemistry and the Origin of Oseepchun in Dogye Area, Korea (도계지역 오십천에서의 지하수 영향분석 - 수리지화학적 특성과 기원)

  • Hwang, Jeong Hwan;Song, Min Ho;Cho, Hea Ly;Woo, Nam C
    • Economic and Environmental Geology
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    • v.49 no.3
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    • pp.167-179
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    • 2016
  • Water quality of Oseepchun, Dogye area, was investigated quantitatively for its origin and hydrogeochemistry in relation to the influence of groundwater. Groundwater appears to be the principal source of Oseepchun from the water-quality monitoring data including redox potentials, composition of dissolved ions and their correlations, hydrogen and oxygen stable isotopic ratios, and the distribution and occurrence of contaminants. Water-quality type of the surface water was grouped by the water-rock interactions as $Ca-HCO_3$ type originated from carbonated bed-rocks in the Joseon Supergroup, (Ca, Mg)-$SO_4$ type related with dissolution of surfide minerals in coal beds of Pyeongan Supergroup, and (Ca, Mg)-($HCO_3$, $SO_4$) type of the mixed one. Locally water pollution occurs by high $SO_4$ from mine drainage and $NO_3$ from waste-treatment facility. Intensive precipitation in summer has no effect on the water type of Oseepchun, but increases the inflow of nitrate and chloride originated from land surface. Results of this study direct that groundwater-surface water interaction is intimate, and thus surface-water resource management should begin with groundwater characterization.