• 한국수자원학회논문집
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• 제33권5호
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• pp.527-536
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• 2000

본 연구는 금강의 주요지류인 미호천 유역에 소재하고 있고 주요 텔레미터 수위표가 위치한 4개의 지점을 선정하여 유출량과 오염부하량의 상관성 분석을 통해 각 소유역의 전체 오염부하량을 추정하였다. 본 연구에서는 대상유역의 유량측정 지점을 중심으로 평·갈수시 및 홍수시의 유출량 및 수질을 분석하였다. 분석된 유출량 및 수질자료를 통해 유역의 수위-유량관계곡선과 농도변화를 분석하였다. 그리고, 유출량과 수질항목간의 상관관계를 분석하였고, 단위면적당 유출량 변화에 따른 단위면적당 오염부하량과의 상관관계 분석을 통해 유역별 상관식을 도출하였다. 이 관계식은 미호천 유역에서의 유출량 변화에 따른 오염부하량의 산정에 이용될 수 있을 것이다.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2001년도 학술발표회 발표논문집
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• pp.460-465
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• 2001

Pollutant load using unit load method is calculated by simply equation, especially, very useful in the area that didn't exist about water quality data. However, it takes long time to calculate pollutant load with area in which there is various pollutants and if the boundary of a basin altered, the work of calculation about pollutant load must be begun from the first again. Therefore, a Total Daily Load Program(TDLP) was developed to calculate pollutant load automatically in rural area. The TDLP includes a geographic information system(GIS), relational database system(RDBS), User Interface. This Program can provide user with creating a boundary of the basin that user is concerned with to satisfy the water quality regulations and calculating daily load for various pollutants. The effort was conducted to apply the developed TDLP to calculating pollutant load in rural basin called Bok-ha river.

• 환경위생공학
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• 제14권3호
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• pp.1-9
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• 1999

In the estimation of pollution load in water basin, a data information has generally used from surveyed data. A Geographic Information System(GIS) was adopted to evaluate the amount of pollution load in Anyang stream basin which is one of the major tributaries in the Han river flows through urban area. The digital maps of administrative boundary, stream network, sub-basin, soil type, and land-use for spatial data as well as attribute data were generated. And the database of sub-basins and pollution source was structured to estimate pollution load in Anyang stream basin by an Arc/Info GIS.As the results of this investigation, the pollution load of Mokgam-chun sub-basin was the highest amount. And that of Hagi-chun sub-basin and the fourth main stream sub-basin were also high amount in Anyang stream basin. In general, it was found that the pollution load generated from the upstream area in Kyunggi province was higher than that from downstream area in Seoul. Because the point and non-point source pollution load played very significant role in the deterioration of the water quality of the Anyang stream, an integrated approach to water quality management should be required for the sub-basins of high pollution load amount.

• 한국물환경학회지
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• 제28권6호
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• pp.786-795
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• 2012

Water quality management should be focused on the pollution concentrated area so that the improvement of water quality can be achieved effectively for the management of Total Maximum Daily Loads (TMDLs). It is necessary to consider discharge characteristics in the TMDL plan. This study analysed discharge characteristics such as pollution generation and discharge load density, and reduction potential by each unit watershed, and categorized the unit watershed into four groups according to its discharge load characteristics. This analysis can be used as helpful information for the prioritization of pollution reduction area and selection of pollution reduction measures in the development of TMDL plans.

• 설비공학논문집
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• 제21권12호
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• pp.695-702
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• 2009

Dynamic behavior of Libr-water absorption system using low-temperature hot water was investigated numerically. Thermal-hydraulic model of single-effect/double-lift 100 RT chiller was developed by applying transient conservation equations of total mass, Libr mass, energy and momentum to each component. Transient variations of system properties and transport variables were analysed during start-up operation. Numerical analysis were performed to quantify the effects of bulk concentration and part-load operation on the system performance in terms of cooling capacity, coefficient of performance, and time constant of system. For an absorption chiller considered in the present study, optimum bulk concentration was found to exist, which resulted in the minimum time constant with stable cooling capacity. COP and time constant increased as the load decreased down to 40%, below which the time constant increased abruptly and COP decreased as the load decreased further.

• 한국물환경학회지
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• 제26권5호
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• pp.860-870
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• 2010

Long term monthly monitoring data showed that the water quality of streams flowing into Lake Paldang has been improved by various strategy for water. However, the effect of quality on Lake Paldang is still insufficient because of nonpoint source from watershed. In order to evaluate quantifying methods for pollution source and make a suggestion on improvements, Storm Water Management Model (SWMM) was constructed by using data set from the water quality and streamflow monitoring network in the Kyoungan watershed for Total Maximum Daily Loads (TMDLs). Load duration curve (LDC) based on the result of the Kyoungan watershed SWMM indicated that the water quality criterion on $BOD_5$ was often exceeded in up-stream than down-stream. From flowrate-load correlation curve, SS load significantly increased as streamflow increases. 75.3% of streamflow and 62.1% of $BOD_5$ loads is discharged especially in the zone of high flows, but monitoring data set didn't provide proper information about the conditions and the patterns associated with storm events. Therefore, it is necessary to acquire representative data set for comparing hydrograph and pollutograph through monitoring experimental watershed and to establish methods for quantifying point and nonpoint source pollutant loads.

• 한국물환경학회지
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• 제32권6호
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• pp.670-699
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• 2016

In this study, 16 antibiotics were selected from among the top 30 veterinary antibiotics sold in South Korea in 2014, as well as from among the pharmaceuticals targeted by EPA method 1694, in order to review analytical methods for the detection of trace levels of antibiotics in environmental samples: surface water, soils, animal origin foods, and manures. LC-MS/MS was heavily used. In the chromatography for the detection of the selected antibiotics, the $C_{18}$ column was mostly used at the temperature of $30{\sim}40^{\circ}C$. Water and methanol/acetonitrile were commonly chosen as a nonpolar and a polar mobile phase, respectively. Gradient elution was applied to separate multiclass antibiotics. Volatile additives, such as formic acid, acetic acid, and ammonium acetate were mixed with the mobile phase to improve the ionization efficiency of analytes and the sensitivity in MS detection. Electrospray ionization (ESI) was widely used in the LC-MS/MS and positive ionization was preferred to determine the selected antibiotics. A protonated $[M+H]^+$ molecule was selected as a precursor ion, and its two transitions were analyzed, one for quantitative measurement and the other for confirmation. This study reviewed linearity of the calibration curve, recovery, repeatability, method detection limits (MDLs), and method quantification limits (MQLs) for each target compound used to validate the developed analytical methods.

• 한국물환경학회지
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• 제32권6호
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• pp.600-627
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• 2016

Korea is one of the countries with a large veterinary antibiotics market, although antimicrobial resistance in bacteria is becoming a serious issue in many countries. The Korean government started to take interest in estimating the effects of livestock manure on rivers and agricultural soils and in monitoring of heavy metals, organic pollutants and antibiotics in the ambient water and soil. In this paper, pre-treatment methods to separate the selected antibiotics from solid samples were reviewed. It is essential to select an efficient and appropriate procedure for pre-treatment due to the high proportion of proteins and organics in biosolid samples. Pre-treatment consists of extraction followed by clean-up. Initially, homogenized samples were extracted by sonication, mechanical agitation or pressurized liquid extraction with methanol/acetonitrile/water mixture under acidic/basic conditions depending on the compound. However, aminoglycosides and colistin were extracted with 5% trichloroacetic acid and HCl, respectively. Since the ${\beta}-lactams$ are easily decomposed in acidic and basic conditions, they were extracted in neutral pH. Filtration with a membrane (pore size, $0.2{\mu}m$) or solid phase extraction with HLB and methanol, as eluents, was normally applied for the clean-up. At least, three different pre-treatment procedures should be adopted to screen all the selected antibiotics in solid samples.

• 한국물환경학회지
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• 제30권2호
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• pp.148-158
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• 2014

In order to assess the effect of TMDLs management and improve that in the future, it is necessary to analyze long-term changes in water quality during management period. Therefore, long term trend analysis of BOD was performed on thirty monitoring stations in Geum River TMDL unit watersheds. Nonparametric trend analysis method was used for analysis as the water quality data are generally not in normal distribution. The monthly median values of BOD during 2004~2010 were analyzed by Seasonal Mann-Kendall test and LOWESS(LOcally WEighted Scatter plot Smoother). And the effect of Total Maximum Daily Loads(TMDLs) management on water quality changes at each unit watershed was analyzed with the result of trend analysis. The Seasonal Mann-Kendall test results showed that BOD concentrations had the downward trend at 10 unit watersheds, upward trend at 4 unit watersheds and no significant trend at 16 unit watersheds. And the LOWESS analysis showed that BOD concentration began to decrease after mid-2009 at almost all of unit watersheds having no trend in implementation plan watershed. It was estimated that TMDLs improved water quality in Geum River water system and the improvement of water quality was made mainly in implementation plan unit watershed and tributaries.

• 한국물환경학회지
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• 제29권6호
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• pp.762-776
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• 2013

Load duration curve was applied to determine important water quality parameter control term for improvement of Paldang lake water quality. Load duration curve was analyzed with long term data from 1985 to 2012 including water quality, flow rate and climate state of Paldang water environment. From the result of flow rate patterns of paldang lake, differences between high and low flow rate of each year showed tendency of increase because rainfall characteristics of paldang lake watershed were changed by climate exchange. Both of land use state of upper Paldang lake watershed and number of limit excess from load duration curve indicated that seasonal action related with land use such as agricultural fertilizer distribution in upper watershed affected Paldang lake water quality. So focused BOD (biological oxygen demand) management during spring season from march to June is required to control organic materials in Paldand lake. The main affecting factor of TOC (total organic carbon) increase in Paldang lake was initial rainfall after march. T-N (total nitrogen) kept increasing during research period, so enhancement of T-N standard is needed to T-N control. Initial rainfall and increase of temperature during spring season from March to June showed a positive correlation with TP (total phosphorus) and Chl-a, respectively.