• Title/Summary/Keyword: Water leaching

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A study on Bacterical Leaching of Low-Grade Copper Mineral(III) (저품위 동광석의 세균침출에 관한 연구 3)

  • 이강순;민봉희;장정순
    • Korean Journal of Microbiology
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    • v.11 no.2
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    • pp.69-78
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    • 1973
  • In order to investigate the distribution of an iron-oxidizing bacterium, Ferrobacillus ferrooxidans in Korea, the authors had carried out the chemical and microbiological analysis of mine water. The results obtained were as follows : 1. Ferrobacillus ferrooxidans concerned to leaching was isolated from 10 copper mine water out of 46 sites in Korea. 2. As the results of bacterial oxidation, the contents of sulfuric acid, ferric sulphate and copper in the bacteria-bearing solutions were higher than those in bacteria-free solutions.

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Estimation of Nitrate Leaching Rates for a Small Rural Watershed Using a Distributed Watershed Model (분포형 유역모델을 이용한 농촌지역 소유역의 질산성 질소 지하침출량 평가)

  • Park, Min-Hye;Park, Sunhwa;Kim, Hyun-Koo;Hwang, Jong-Yeon;Kim, Tae-seung;Chung, Hyen Mi;Cho, Hong-Lae;Lee, Taehwan;Koo, Bhon K.;Park, Yun Hee
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.661-669
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    • 2017
  • A distributed watershed model CAMEL (Chemicals, Agricultural Management and Erosion Losses) was applied to a small rural watershed where intensive livestock farming sites are located to estimate nitrate leaching rates from soil to groundwater. The model was calibrated against the stream flows, and T-N and $NO_3-N$ concentrations were observed at the watershed outlet for three rainfall events in 2014. The simulation results showed good agreement with the observed stream flows ($R^2=0.67{\sim}0.93$), T-N concentrations ($R^2=0.40{\sim}0.58$) and $NO_3-N$ concentrations ($R^2=0.43{\sim}0.65$). The estimated annual nitrate leaching rate of the watershed was 33.0 kg N/ha/yr. The contributing proportions of individual activities to the total nitrate leaching rate of the watershed were estimated for livestock farming, applications of chemical fertilizer, and manure. The simulation results showed that the highest contributor to the nitrate leaching rate of the watershed was chemical fertilizer applications. The simulation period was for one year only, however, and results may vary depending on different conditions. Gathering input data over a longer period of time and monitoring data for calibration is needed. When this has been accomplished, it is expected that this model can be applied to small rural watersheds for evaluating temporal and spatial variations of nitrogen transformations and transport processes.

Characteristics of phosphorus leaching from sewage sludge ash by acid and alkali (산과 알카리에 의한 슬러지 소각재의 인 침출 특성)

  • Battsooj, Munkhjargal;Lee, Minsu;Kim, Dong-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.5
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    • pp.571-577
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    • 2016
  • Phosphorus is an essential and irreplaceable element for all living organisms and its resource is limited. Significant amount of used phosphorus is collected in sewage treatment plant as sludge. Sludge ash after incineration contains about 10% of phosphorus in dry mass basis, which is comparable to phosphate rocks, and it is an important source of phosphorus recovery. Acid and alkali were used to leach phosphorus from sludge ash and compared for their leaching kinetics and performance. Phosphorus leaching by NaOH was fast and 0.2 N and 2 N NaOH leached 49% and 56% of the total phosphorus in the sludge ash at the L/S ratio of 100. Phosphorus leaching by sulphuric acid and hydrochloric were very fast and most of the phosphorus was leached in 5 minutes. In case of sulphuric acid 95% of the total phosphorus in the sludge ash was leached by 0.2 N at the L/S ratio of 100 and 93% was leached by 1 N at the L/S ratio of 10. 1 N hydrochloric acid leached 99% of the total phosphorus at the L/S ratio of 10. The results showed acids were more effective than alkali for phosphorus leaching from sludge ash and hydrochloric acid leached more phosphorus than sulphuric acid.

Characteristics of Calcium Leaching Resistance for Concrete Mixed with Mineral Admixture (광물질 혼화재를 혼합한 콘크리트의 칼슘용출 저항 특성)

  • Choi, So-Yeong;Choi, Yoon-Suk;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.59-67
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    • 2016
  • Concrete is a very useful construction material for the sealing disposal of hazardous substances. In general, mass concrete is applied to these structures. And, the mineral admixtures are recommended for the long term performance. Calcium leaching could be happened due to the contact with pure water in underground structures. Thus, it is needed to evaluate the resistance of calcium leaching for concrete mixed with mineral admixtures. From the test results, the mineral admixtures are effective to the improvement of long term compressive strength and chloride diffusion coefficient in concrete members. When calcium leaching is happened, however, the reduction of compressive strength and chloride penetration resistance is severe than OPC case, the micro pore distribution is adversely affected. Consequently, when the mineral admixtures are applied to underground structures which is exposed to calcium leaching environment, it is desirable to reduce water-to-binder ratio, to expose after the sufficient pozolanic reaction, and to use BFS than FA.

Assessment of applicability on Solidification/Stabilization of Arsenic in contaminated Soil According to the Revised Korean Standard Leaching Test for Soil (개정 토양용출시험법에 따른 비소오염토양의 고형화/안정화 공법 국내 적용성 평가)

  • Hong, Seong-Hyeok;Park, Hye-Min;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.1
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    • pp.1-5
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    • 2011
  • Arsenic is one of the most abundant contaminant found in waste mine tailings and soil around refinery, Because of its carcinogenic property, the countries like United States of America and Europe have made stringent regulations which govern the concentration of arsenic in soil. The study focuses on solidification/stabilization for removal of arsenic from soil. Cement was used to solidify/stabilize the abandoned soil primarily contaminated with arsenic (up to 68.92 mg/kg) in and around refinery. Solidified/stabilized (s/s) forms in the range of cement contents 5-30 wt % were evaluated to determine the optimal binder content. Revised Korean standard leaching tests (KSLT), toxicity characteristic leaching procedures (TCLP), Old Korea standard leaching test and revised Korea standard leaching test were used for chemical characterization of the S/S forms. The addition of 10 % cement remarkably reduced the leachability of arsenic in contaminated soil. The concentration of As in leachate of TCLP, KSLT, and old KSLT for soil are below the standard. However that in leachate of revised KSLT is above the standard. Because of extraction fluid used in revised KSLT is very strong acid. It is arsenic in s/s with binder should be exhaustingly leached. Therefore S/S process would not be available for As treatment in soil in Korea.

Characteristic of Leaching with Incineration Fly Ash of Industrial Solid Wastes (산업폐기물 소각장에서 발생된 소각비산회의 침출특성)

  • 양종규;김종화;서명교;고태규
    • Resources Recycling
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    • v.8 no.1
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    • pp.18-22
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    • 1999
  • In order to utilize incineration fly ash of industrial wastes as resources, we present the recovery and separation of metals included in the fly ash by leaching with aqueous solution A great quantity of Cu, Pb, and Zn as well as a small amount oftoxic heavy metals are contained in the leach liquor of the fly ash, and the concentration of the ingredients of the fly ash depends on the industrial wastes which are fed into incinerators. In this paper, sequential Ieachiog operations are conducted using $H_2O$, $H_2SO_4$, $(NH_4)_2CO_3$ and NaOH as Icachants. Water soluble copper salt was leached by $H_2O$, Zn and Pb were separated by the NaOH leach liquor, and water insoluble copper was selectively leached as chelate ion with the $(NH_4)_2CO_3$ leach liquor of the third Ieaehant. Results show that the reduction percent of the fly ash in the leaching steps using $H_2O$, $H_2SO_4$, and $(NH_4)_2CO_3$ is 77%, and the other leaching procedures lose the weight of fly ash by above 60%.

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Analysis of Electrical Conductivity during Desalinization of Reclaimed Tidal Lands (간척지 토양의 제염과정 중 전기전도도 분석)

  • 구자웅;최진규;손재권;윤광식;이동욱;조경훈
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.4
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    • pp.37-49
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    • 2001
  • This study was performed in order to produce the basic data for developing prediction techniques of desalinization to be applicable to reclaimed tidal lands at the beginning stage. the desalinization experiments were carried out by two water management practices, namely, the leaching method by subsurface drainage and the rinsing method by surface drainage. The 5 soil samples used in this study were collected in 4 tidal land reclamation projects. Regression equations were obtained in order to investigate the changes of electrical conductivity during the desalinization of reclaimed tidal lands and to estimate water requirements for desalinization. The results obtained from this study were summarized as follows: 1. According to USDA Salinity Laboratory classification system of salt affected soils the reclaimed tidal land soils used in this study were saline-sodic soils with the high electrical conductivity and the high exchangeable sodium percentage. 2. With the increase of the water requirements for desalinization the electrical conductivity was decreased with high degree of correlationships and the desalinization effects were remakable in both the leaching method and the rinsing method. 3. In case of the leaching method the electrical conductivity had been reduced below the classification value of salt affected soils when the depth o water leached per unit depth of soil (Dwl/Ds) was 0.3 and the desalinization effects showed a tendency to be much the same in each treatment.

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The Recovery of Alumina from Water Treatment Plant Sludge by Chlorination (정수장 슬러지로부터 염소화 반응에 의한 알루미나 회수)

  • Yeon, Ik-Jun;Lee, Sang-Woo;Kim, Kwang-Yul
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.211-216
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    • 1999
  • This study was conducted to recover the aluminum from water treatment plant sludge containing alumina. The optimum reaction conditions about chlorination of sludge with $NH_4Cl$ are as follows: the weight ratio of sludge to $NH_4Cl$ is 4, the reaction time is 60min, and the temperature is $300^{\circ}C$. And the result of leaching time test showed that the highest yield of alumina at $160^{\circ}C$ was 96% but the result of leaching test at $160^{\circ}C$ was little better than that of leaching test at $100^{\circ}C$ while the leaching concentration of HCl was 4N. The optimum reaction conditions of chlorinated sludge with $NH_4Cl$, gave the highest yield of 95.41% based on aluminum.

Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form (방사성고화체로 부터의 Co, Cs침출에 대한 표준시험법의 상호비교)

  • Kim, Gi-Hong;Yoo, Yeong-Geol;Jeong, Gyeong-Gi;Hong, Gwon-Pyo;Lee, Rak-Hui;Jeong, Ui-Yeong;Koh, Deok-Jun;Kim, Heon
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.21-31
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    • 2003
  • IAEA, FT-04-020, and ANS 16.1, standard leaching test methods, were evaluated comparatively with their test results. Leaching index of Co-60 and Cs-137 for all waste forms were above 6.0. Their leaching behavior were contrary according to the type of matrix and leachant. Leachability of Co in cement waste form was higher in simulated seawater than demi. water, and higher in demi. water in paraffin waste form. Leachability of Cs was contrary to Cs. Cumulative fraction leached of Co was higher such as IAEA>ANS>FT in cement waste form.

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Effect of Copper Retention on Copper Leaching in Wood Treated with Copper-based Preservatives

  • Ra, Jong-Bum;Kang, Sung-Mo;Kang, Shin-Kwon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.5
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    • pp.421-425
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    • 2009
  • This research investigates the effect of copper retention on copper leaching in wood treated with copper-based preservatives. Radiata pine (Pinus radiata D. Don) sapwood samples were ground in a Wiley mill equipped with a 20-mesh screen. The ground wood was vacuum-treated with various concentrations of alkaline copper quat (ACQ), bis-(N-cyclohexyl-diazeniumdioxy)-copper (CB-HDO), and copper azole (CUAZ). The treated samples were conditioned at $70^{\circ}C$ and 100% RH for 72 hours. The samples were leached by using the distilled water for four weeks, and the copper contents in each sample were measured by X-ray spectroscopy. As expected, the copper leaching was increased with increasing of copper retention. The copper leaching from the ACQ and CB-HDO treated samples were gradually decreased with increasing copper retention: however, the copper losses from the CUAZ treated samples appeared to be proportionally increased with the increase in copper retention in all retention levels tested. The results indicate that at the conditions of the same copper retention ACQ and CB-HDO treated wood have a better leaching resistance compared to CUAZ treated wood.