• Title/Summary/Keyword: Water layer

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Characteristics of composition and surface morphology of soil particles influenced by inorganic acids with different acidity (산해리도가 다른 무기산에 의한 토양 입자 표면 특성)

  • Lee, Dong-Sung;Lee, Kyo-suk;Shin, Ji-Soo;Lee, Jae-Bong;Joo, Ri-Na;Lee, Myong-Youn;Min, Se-Won;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.42 no.3
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    • pp.191-199
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    • 2015
  • We conducted this research to observe the changes of surface morphology and composition of clay minerals influenced by various concentrations of fluoric acid. Hydrofluoric acid (HA), a solution of hydrogen fluoride (HF) in water, is a colourless solution that is highly corrosive, capable of dissolving many materials, especially oxides. To do this, we treated several concentrations of HA on the ground soil samples collected from the agricultural experimental station located at Chungnam National University to observe the influence of fluoric acid on the changes of surface structures and elemental composition of clay particles. Generally, microscopic examination showed that the HA can not only attack an edge of clay particles but also start at any point where structural defects and weaknesses predisposed sites to acid. The orderly flake arrangement of clay minerals may reflect certain crystal symmetry elements. The ESEM-EDS results of element composition of clay particles influenced by HA indicated the changes of structures of clay minerals. It is also clear from the formation of etch figures and element composition of clay particles that the product layer at least partially dissolved or disintegrated in the presence of acid. Conclusively, the clay structures can be strongly influenced by concentrations of HA, resulting in changes of physical and chemical properties that can determine the behavior of solute transport as well as mobility of ions in soils.

Robust 1D inversion of large towed geo-electric array datasets used for hydrogeological studies (수리지질학 연구에 이용되는 대규모 끄는 방식 전기비저항 배열 자료의 1 차원 강력한 역산)

  • Allen, David;Merrick, Noel
    • Geophysics and Geophysical Exploration
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    • v.10 no.1
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    • pp.50-59
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    • 2007
  • The advent of towed geo-electrical array surveying on water and land has resulted in datasets of magnitude approaching that of airborne electromagnetic surveying and most suited to 1D inversion. Robustness and complete automation is essential if processing and reliable interpretation of such data is to be viable. Sharp boundaries such as river beds and the top of saline aquifers must be resolved so use of smoothness constraints must be minimised. Suitable inversion algorithms must intelligently handle low signal-to-noise ratio data if conductive basement, that attenuates signal, is not to be misrepresented. A noise-level aware inversion algorithm that operates with one elastic thickness layer per electrode configuration has been coded. The noise-level aware inversion identifies if conductive basement has attenuated signal levels so that they are below noise level, and models conductive basement where appropriate. Layers in the initial models are distributed to span the effective depths of each of the geo-electric array quadrupoles. The algorithm works optimally on data collected using geo-electric arrays with an approximately exponential distribution of quadrupole effective depths. Inversion of data from arrays with linear electrodes, used to reduce contact resistance, and capacitive-line antennae is plausible. This paper demonstrates the effectiveness of the algorithm using theoretical examples and an example from a salt interception scheme on the Murray River, Australia.

Evaluation of Various Soil Stiffness Test Equipments as Construction Control Tools (다양한 지반강성 평가장치를 이용한 현장 다짐도 예비 평가)

  • Kim, Ju-Hyong;Yoo, Wan-Kyu;Kim, Byoung-Il;Chae, Kwang-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.636-643
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    • 2008
  • The objective of this paper is to assess the potential use of the geogauge and the light falling weight deflectometer (LFWD) and the soil impact hammer as quality control/quality assurance $Q_C/Q_A$ devices for compacted soil layers. A comprehensive field experimental program considering variation of number of compaction, water contents and thickness of compaction layer was conducted on compacted layers of gravel sand. The geogauge, LFWD, the soil impact hammer and static load test (PLT) as a reference test were performed for the compacted layers. The geogauge elastic modulus, $E_G$, the LFWD dynamic modulus, ELFWD, empirical soil stiffness, $K_{30}$, obtained from soil impact hammer and soil stiffness directly obtained from PLT, $K_{30}$, were correlated with increasing number of compaction. The results of this study show that the geogauge, LFWD and the soil impact hammer, which are very simple to test, can be used as substituting devices for static PLT which is a conventional quality control/quality assurance $Q_C/Q_A$ devices for compacted soil layers.

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Effect of Wave-Induced Seepage on the Stability of the Rubble Mound Breakwater (동적 파랑에 의한 침투류가 사석경사식 방파구조물의 안정성에 미치는 영향)

  • Hwang, Woong-Ki;Kim, Tae-Hyung;Kim, Do-Sam;Oh, Myounghak;Park, Jun-Young
    • Journal of the Korean Geotechnical Society
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    • v.34 no.3
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    • pp.13-27
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    • 2018
  • To study how stable the rubble mound breakwaters are, one can look to the research of wave induced seepage flow through the pores of the rubble mound. Seepage flow is generally generated by the difference between the water level around the breakwater during a typhoon. The existing stability analysis method of the rubble mound is the static analysis which simply considers the force equilibrium taking into account the horizontal force acting on the concrete block induced by a wave (calculated by Goda equation) and the vertical force induced by the weight inclusive of the concrete block, quarry run, filter, and armor layer above the slipping plane. However, this static method does not consider the wave-induced seepage flow in the rubble mound. Such seepage may decrease the stability of the rubble mound. The stability of a rubble mound breakwater under the action of seepage was studied based on the results of CFD software (OpenFOAM) and Limit Equilibrium Method (GeoStudio). The numerical analysis result showed that the seepage flow decreased the stability of the rubble mound breakwaters. The results of the numerical analyses also revealed the stability of the rubble mound was varied with time. Especially, the most critical state happened at the condition of overtopping the concrete block, acting strong uplift pressure raising along side and underneath the concrete block, and generating high pore pressure inside rubble mound due to seepage flow. Therefore, it may be necessary to conduct a dynamic analysis considering the effect of wave-induce seepage flow together with the static analysis.

Effect of Microporous Structure of Al2O3/PVdF_HFP Ceramic Coating Layers on Thermal Stability and Electrochemical Performance of Composite Separators for Lithium-Ion Batteries (Al2O3/PVdF_HFP 세라믹코팅층의 미세기공구조가 리튬이차전지용 복합분리막의 열 안정성 및 전기화학특성에 미치는 영향)

  • Jeong, Hyun-Seok;Kim, Kyu-Chul;Lee, Sang-Young
    • Journal of the Korean Electrochemical Society
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    • v.12 no.4
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    • pp.324-328
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    • 2009
  • The internal short-circuit between cathodes and anodes has been known to be a critical concern for the safety failures of lithium-ion batteries, which is strongly influenced by the thermal stability of separators. In this study, to effectively suppress the internal short-circuit failures, we developed a new composite separator with the improved thermal stability compared to conventional polyolefin-based separators. The composite separators were prepared by introducing a ceramic coating layer ($Al_2O_3$/PVdF-HFP) onto both sides of a polyethylene (PE) separator. The microporous structure of ceramic coating layers is determined by controlling the phase inversion of coating solutions and becomes more developed with the increase of nonsolvent (water) content. This structural change of ceramic coating layers was observed to greatly affect the thermal stability as well as the electrochemical performance of composite separators, which was systematically discussed in terms of phase inversion.

Rheological Evaluation of Blast Furnace Slag Cement Paster over Setting Time (고로슬래그 혼합 시멘트 페이스트의 응결시간 경과에 따른 레올로지 특성)

  • Cho, Bong-Suk;Ahn, Jae-Cheol;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.505-512
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    • 2016
  • Even though high performance concrete was developed according to the trend of bigger and higher of reinforced concrete building, the rheological evaluations such as viscosity, yield stress are not enough to use as input data to accomplish the numerical analysis for the construction design. So there are many problems in the harden concrete such as poor compaction, rock pocket and crack, etc. in the field. In this study, consistency curves were measured by the viscometer as hydration reaction time passed. At the same time the slump flow test and Vicat setting test were carried out for comparing with the results of rheological properties. The fluidity of the W/B 30% decreased as the increase of replacement ratio of blast furnace slag. But in case of W/B 40%, the replacement ration did not significantly influenced to the slump flow value with the passage of hydration time. By the replacement of blast furnace slag to cement, initial setting was delayed and the time gap between initial and final setting became shorten. Through the regression analysis using Bingham model, there are a sudden changes of viscosity and yield stress around initial setting in case of low W/B 30%. The increase of workability by the change of free water in cement paste was offset by the coating effect of impermeable layer in case of W/B 40%.

Artificial Control of ZnO Nanorods via Manipulation of ZnO Nanoparticle Seeds (산화아연 나노핵의 조작을 통한 산화아연 나노로드의 제어)

  • Shin, Kyung-Sik;Lee, Sam-Dong;Kim, Sang-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.399-399
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    • 2008
  • Synthesis and characterization of ZnO structure such as nanowires, nanorods, nanotube, nanowall, etc. have been studied to multifunctional application such as optical, nanoscale electronic and chemical devices because it has a room-temperature wide band gap of 3.37eV, large exiton binding energy(60meV) and various properties. Various synthesis methods including chemical vapor deposition (CVD), physical vapor deposition, electrochemical deposition, micro-emulsion, and hydrothermal approach have been reported to fabricate various kinds of ZnO nanostructures. But some of these synthesis methods are expensive and difficult of mass production. Wet chemical method has several advantage such as simple process, mass production, low temperature process, and low cost. In the present work, ZnO nanorods are deposited on ITO/glass substrate by simple wet chemical method. The process is perfomed by two steps. One-step is deposition of ZnO seeds and two-step is growth of ZnO nanorods on substrates. In order to form ZnO seeds on substrates, mixture solution of Zn acetate and Methanol was prepared.(one-step) Seed layers were deposited for control of morpholgy of ZnO seed layers by spin coating process because ZnO seeds is deposited uniformly by centrifugal force of spin coating. The seed-deposited samples were pre-annealed for 30min at $180^{\circ}C$ to enhance adhesion and crystallinnity of ZnO seed layer on substrate. Vertically well-aligned ZnO nanorods were grown by the "dipping-and-holding" process of the substrates into the mixture solution consisting of the mixture solution of DI water, Zinc nitrate and hexamethylenetetramine for 4 hours at $90^{\circ}C$.(two-step) It was found that density and morphology of ZnO nanorods were controlled by manipulation of ZnO seeds through rpm of spin coating. The morphology, crystallinity, optical properties of the grown ZnO nanostructures were carried out by field-emission scanning electron microscopy, high-resolution electron microscopy, photoluminescence, respectively. We are convinced that this method is complementing problems of main techniques of existing reports.

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Comparison of Growth and Survival Rates of Juvenile Grey Mullets (Mugil cephalus) in Different Salinities (어린 숭어(Mugil cephalus)의 염분농도별 성장과 생존을 비교)

  • Chang, Young-Jin;Lee, Young-Choon;Lee, Bok-Kyu
    • Journal of Aquaculture
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    • v.9 no.4
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    • pp.311-320
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    • 1996
  • In order to compare the growth and survival rates of grey mullet (Mugil cephalus) juveniles in different salinities, the fish reared in seawater (SW) abruptly were transferred to each experimental rearing water of $0\%SW\;(0\%_{\circ}),\;25\%SW\;(7.7\%_{\circ}),\;50\%SW\;(16.1\%_{\circ})$ and $100\%SW (32.8\%_{\circ})$. Growth rates in total length and body weight of fish in $25\%$ SW, $50\%$ SW and $75\%$ SW were greater than that in $0\%$ SW (P<0,05). Decreased salinity appeared to have an acute, but appetite depressive effect in short term in the experimental groups. Survival rate was low in $0\%$ SW (P<0.05), although those were more than $81\%$ in all salinities. There were no differences in thickness of epidermis and dermis layers in fish skin among the all experimental groups at the end of experiment. But the thickness of lipid layer in $0\%$ SW fish showed the significant differences to those in $50\%$ SW and $100\%$ SW (P<0.05). With decreased salinities, oxygen consumption was found to be decresed in the other experimental groups compared to the group in $100\%$ SW. The levels of lethal dissolved oxygen in $0\%$ SW to $100\%$ SW were 1.18, 0.30, 0,28 and 0.31 ppm, respectively.

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Spawning Behavior and Early Life History of Korean Aucha Perch, Coreoperca herzi Herzenstein (한국산 꺽지 (Coreoperca herzi)의 산란습성 및 초기생활사)

  • 한경호;박준택;정규화;이원교;이재용;방인철
    • Journal of Aquaculture
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    • v.11 no.1
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    • pp.49-58
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    • 1998
  • The spawning behavior and early life history of the Korean aucha perch, Coreoperca herzi were studied. The eggs were spawned in a one-layer mass, hanging from the underside of a largy stone and guarded by one male. According to the considerable size difference os eggs in the individual ovaries, it was concluded that they spawns several times within a spawning season of May~June. The ripe eggs were demersal and adhesive, and their diameter were 2.60~3.04mm with several oil globule of 0.10~0.64mm. Hatching in the tank with $19.0{\pm}1.0^{\circ}C.$ in men water temperature started from the 380 hours after fertilization. Newly-hatched larvae were measured 6.45~7.34mm in total length (TL, mean : 6.85mm), and mouth and anus were open. Melanophores were present on the head, around the yolk, and on the dorsal part of the abdominal region. 3 days old larvae were measured 7.00~7.40mm in TL (mean : 7.25mm), and they fed Daphnia sp. and Brachionus plicatilis actively. 6 days old larvae transformed to postlarval stage and they were 7.94~10.10mm in TL (mean : 9.00mm). As yolk sac were nearly absorbed, the caudal notochord flex at 45. Aggregate numbers of all fin rays were completed at over 16.90~19.80mm in TL (30 days after hatching), at which time the larvae reached the juvenile stage. In fifty days old larvae(24.60~27.10mm in TL) were similar in body form, lateral line and color to adult.

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Underground Migration of $^{54}Mn,\;^{60}Co,\;^{85}Sr\;and\;^{137}Cs$ Deposited during the Growth of Major Crop Plants (주요 작물의 생육중에 침적한 $^{54}Mn,\;^{60}Co,\;^{85}Sr,\;^{137}Cs$ 의 지하이동)

  • Choi, Yong-Ho;Jo, Jae-Seong;Lee, Chang-Woo;Lee, Myung-Ho;Kim, Sang-Bog;Hong, Kwang-Hee;Choi, Geun-Sik;Lee, Jeong-Ho
    • Journal of Radiation Protection and Research
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    • v.21 no.1
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    • pp.51-58
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    • 1996
  • Underground migration of $^{54}Mn,\;^{60}Co,\;^{85}Sr\;and\;^{137}Cs$ in paddy and upland conditions was studied through two years' greenhouse experiment. At early and late growth stages of rice, soybean, Chinese cabbage and radish, a mixed solution of the radionuclides was applied to the water or soil surfaces of the culture boxes filled with an acidic loamy-sandy soil for the upper 20cm. Soil was sampled in layers upto $15{\sim}20cm$ down after harvest. Soil concentrations of the radionuclides decreased exponentially with increasing soil depth and more than 80% of the radioactivities remained in top $3{\sim}4cm$. The mobility of the radionuclides decreased in the order of $^{85}Sr>^{54}Mn>^{60}Co{\geq}^{137}Cs$. Downward migrations of the radionuclides were the greatest in rice soil and the lowest in soybean soil which was fertilized with the least amount of N, P and K. Differences in depth profiles between two application times indicate that the amount of daily migration from $0{\sim}1cm$ layer to the lower area decreases with increasing time after deposition. By a simultaneous addition of KCl and lime following the earlier application, downward migration in soybean, Chinese cabbage and radish soils changed little or retarded more or less but that in rice soil accelerated a little.

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