• Title/Summary/Keyword: Water exchange rate

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Study on the Ethanol Recovery Process using Dircet Contact Heat Exchange (고온의 기포접촉에 의한 에탄올 회수공정에 관한 연구)

  • Lee, Won-Young;Yeo, Sang-Do;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.176-180
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    • 1995
  • Direct contact heat exchange (DCHE) method has been employed to investigate the separation of ethanol from dilute aqueous solutions. Bubbles at high temperature were dispersed into a continuous liquid phase, generating temperature gradient in air-liquid interface, which causes heat and mass transfer accordingly. The experiments were performed in the ranges of jet regime air flow. The air-water stripping coefficient increased $5{\sim}10,\;and\;1{\sim}1.5$ times as temperature and air flow rate increased, respectively. The recovery ratio based on the initial ethanol concentration reached into 80% at the air flow rate of 84.88 m/min. The initial ethanol concentration showed little effect on the stripping coefficient and the recovery ratio.

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Solid-state NMR Studies of Phenethyl Sulfonic Acid-functionalized MCM-41

  • Chul Kim
    • Journal of the Korean Chemical Society
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    • v.68 no.2
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    • pp.74-81
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    • 2024
  • A sulfonic acid-water-silanol system in SO3H-functionalized MCM-41 was investigated using solid-state nuclear magnetic resonance techniques. The proton exchange rate between a water molecule and a silanol group in the S-PE-MCM-41 was determined by analyzing the 1D proton spectra, the proton EXSY spectrum, and 2H spin-lattice relaxation data under various hydration levels. Two kinds of water-bounding sites were found in the S-PE-MCM-41: weakly and strongly bound sites. Over several hours, water molecules bound to the weakly bound sites at the low hydration level migrated to the strongly bound sites. At high temperature, the S-PE-MCM-41 easily lost water molecules weakly bound to the silanol, while the strongly bound water molecules survived. Water molecules that participated in the hydration of the phenethyl sulfonate were involved in the hydrogenbonded silanol mechanism of proton conductivity. This phenomenon contributes higher proton conductivity to the S-PE-MCM-41 by the cooperation of sulfonyl and silanol groups in the proton transfer process, even at higher temperature.

Modeling the Effects of Periodic Intrusions of Outer Water on the Variation in the Phytoplankton Biomass and Productivity in a Small Embayment (작은 만에서 식물플랑크톤 생체량과 생산력 변화에 대한 외부 물의 정기적인 침입 효과의 모델링)

  • Ougiyama, Shu;Koizumi, Tsuneyoshi;Takeoka, Hidetaka;Yuichi, Hayami
    • Korean Journal of Ecology and Environment
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    • v.37 no.4 s.109
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    • pp.455-461
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    • 2004
  • Effects of the different strengths and intervals of the periodic outer water intrusions (kyuchos and bottom intrusions) on the dynamics of phytoplankton biomass in a small embayment were examined with a simple numerical model. Environmental conditions of Kitanada Bay in the Bungo Channel were applied to the model. As the interval of the intrusion became longer and the amplitude became smaller, phytoplankton biomass In the bay became higher. On the other hand, as the interval became shorter and the amplitude became larger, the growth rate of the phytoplankton became higher. It suggested that when the intrusion was weaker, water exchange of the bay decreased and the phytoplankton in the bay accumulated at a high density, When water exchange was improved by active intrusions, availability of light would become more efficient and the growth rate of the phytoplankton was enhanced.

Mass Production of Resting Eggs by the Freshwater Rotifer, Brachionus calyciflorus Pallas with Exchange of Culture Water and Supplemental Aeration (환수 및 공기공급에 따른 담수산 rotifer, Brachionus calyciflorus의 내구란 대량생산)

  • Kwon, O-Nam;Park, Heum-Gi
    • Journal of Aquaculture
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    • v.18 no.2
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    • pp.115-121
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    • 2005
  • This study was performed to investigate the formation and mass production of resting eggs by freshwater rotifer, Brachionus calyciflorus as influenced by different aeration supplements and exchange intervals of culture water in 15-L culture vessels and 500 L culture tanks. The maximum densities and mixis rates of the rotifers were not different between experimental group exposed to air or oxygen supplements. However, the fertilization rate and formation of resting eggs of the rotifers in the air-supplemented group were significantly higher than those in the oxygen supplemented group. In the experiment concerning exchange interval of culture water, the maximum density of the rotifers and formation of resting eggs in the batch culture were significantly higher than those in the semi-continuous culture with exchange of water every day. The formation of resting eggs per Chlorella dry weight was highest in the semi-continuous culture with exchange of water every day. The resting eggs of rotifers were produced at a density of $51.8{\sim}57.9{\times}10^6$ eggs in 500-L culture tanks. In this study, the batch culture with air is an effective method for mass production of resting eggs by the freshwater rotifer, B. calyciflorus, and the efficiency of mass production of resting eggs by this rotifer was similar to that of the seawater rotifers, B. plicatilis and B. rotundiformis.

Evaluation of Surface Temperature Variation and Heat Exchange Rate of Concrete Road Pavement with Buried Circulating Water Piping (열매체 순환수 배관이 매설된 콘크리트 도로 포장체의 표면 온도 변화와 방열량 평가)

  • Byonghu Sohn;Yongki Kim
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.19 no.3
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    • pp.1-13
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    • 2023
  • Hydronic heated road pavement (HHP) systems have been well established and documented to provide road safety in winter season over the past two decades. However, most of the systems run on asphalt, only a few are tested with concrete, and there rarely is a comparison between those two common road materials in their performance. The aim of this study is to investigate the thermal performance of the concrete HHP systems, including surface temperature variations of experimental pavements in winter season. For preliminary study a small-scale experimental system was installed to evaluate the heat transfer characteristics of the concrete HHP in the test field. The system consists of 3 concrete slabs made of 1 m in width, 1 m in length, and 0.25 m in height. In these slabs, circulating water piping was embedded with different pipe depths of 0.08 m (Case A), 0.12 m (Case B), and 0.20 m (Case C) and same horizontal space of 0.16 m. Heating performance in winter season was tested with different inlet temperatures of 25℃, 30℃, 35℃ and 40℃ during the entire measurement period. Overall, the surface temperature of the concrete HHPs remained above 3℃ in all experimental conditions applied in this study. The results of the surface temperature measurement with respect to the pipe depth showed that Case B was the highest among the three cases. However, the closer the circulating water pipe was to the pavement surface, the greater the heat exchange rate. This results is considered that the heat is continuously accumulated inside the pavements and then the temperature inside the pavements increases, while the amount of heat dissipation decreases as the temperature difference between the inlet and outlet of circulating water decreases. In this preliminary test the applicability of the concrete HHP on road deicing was confirmed. Finally, the results can be used as a basis for studying the effects of various variables on road pavements through numerical analysis and for conducting large-scale empirical experiments.

EXHAUST GAS HEAT RECOVERY SYSTEM FOR PLANT BED HEATING IN GREENHOUSE PRODUCTION

  • Kim, Y.J.;Ryou, Y.S.;Rhee, K.J.;Kang, G.C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.639-646
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    • 2000
  • Hot air heater with light oil combustion is the most common heater for greenhouse heating in the winter season in Korea. However, since the heat efficiency of the heater is about 80%, considerable unused heat in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust gas heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The system consists of a heat exchanger made of copper pipes, ${\phi}\;12.7{\times}0.7t$ located inside the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tame The total heat exchanger area is $1.5m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to performance test it can recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690{\ell}$/hr from the waste heat discharged. The exhaust gas temperature left from the heat exchanger dropped to $100^{circ}C$ from $270^{circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{circ}C$ from $21^{circ}C$ at the water flow rate of $690{\ell}$/hr. And, the condensed water amount varies from 16 to $43m{\ell}$ at the same water circulation rates. This condensing heat recovery system can reduce boiler fuel consumption amount in a day by 34% according to the feasibility study of the actual mimitomato greenhouse. No combustion load was observed in the hot air heater.

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Performance Ratings According to Characteristics of Thermosyphon Solar Hot Water System (자연대류형 태양열온수기의 특성별 성능평가에 관한 연구)

  • Kang, Y.H.;Kwak, H.Y.;Yoo, C.G.;Yoon, H.G.;Kang, M.C.;Lee, D.G.
    • Solar Energy
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    • v.20 no.2
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    • pp.9-17
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    • 2000
  • To obtain thermal performance data, an experiment was performed with the two selected thermosyphon systems. The system parameters obtained by experimental data were used to perform TRNSYS simulation and verified TRNSYS model of thermosyphon solar hot water system. The thermosyphon solar hot water system was TYPE 145 which is modified from non-linear model. This model can describe heat exchange type and non-linear efficiency equation. It is possible to analyze the annual energy rate with efficiency equation and system specification. In this paper, we could compare the annual performance of the coil heat exchanger with that of the tank-in-tank heat exchanger. Under the same efficiency and parameter, heat exchange, drain, initial tank temperature, ratio of tank volume over collector area(V/Ac), regional annual performance rating were performed.

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Environmental Geochemistry of Atmospheric Mercury: Its Backgriound Concentrations and Exchange Across the Air-Surface Interface (대기수은의 환경지화학: 배경농도측정 및 대기-지표면간의 교환작용)

  • 김기현
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.2
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    • pp.189-198
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    • 1996
  • Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

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Arsenic Removal from Water Using Various Adsorbents: Magnetic Ion Exchange Resins, Hydrous Ion Oxide Particles, Granular Ferric Hydroxide, Activated Alumina, Sulfur Modified Iron, and Iron Oxide-Coated Microsand

  • Sinha, Shahnawaz;Amy, Gary;Yoon, Yeo-Min;Her, Nam-Guk
    • Environmental Engineering Research
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    • v.16 no.3
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    • pp.165-173
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    • 2011
  • The equilibrium and kinetic adsorption of arsenic on six different adsorbents were investigated with one synthetic and four natural types (two surface and two ground) of water. The adsorbents tested included magnetic ion exchange resins (MIEX), hydrous ion oxide particles (HIOPs), granular ferric hydroxide (GFH), activated alumina (AA), sulfur modified iron (SMI), and iron oxide-coated microsand (IOC-M), which have different physicochemical properties (shape, charge, surface area, size, and metal content). The results showed that adsorption equilibriums were achieved within a contact period of 20 min. The optimal doses of adsorbents determined for a given equilibrium concentration of $C_{eq}=10\;{\mu}g/L$ were 500 mg/L for AA and GFH, 520-1,300 mg/L for MIEX, 1,200 mg/L for HIOPs, 2,500 mg/L for SMI, and 7,500 mg/L for IOC-M at a contact time of 60 min. At these optimal doses, the rate constants of the adsorbents were 3.9, 2.6, 2.5, 1.9, 1.8, and 1.6 1/hr for HIOPs, AA, GFH, MIEX, SMI, and IOC-M, respectively. The presence of silicate significantly reduced the arsenic removal efficiency of HIOPs, AA, and GFH, presumably due to the decrease in chemical binding affinity of arsenic in the presence of silicate. Additional experiments with natural types of water showed that, with the exception of IOC-M, the adsorbents had lower adsorption capacities in ground water than with surface and deionized water, in which the adsorption capacities decreased by approximately 60-95%.

Analysis of Falling-film Generator in Ammonia-water Absorption System (암모니아-물 흡수식 시스템에서 유하액막식 발생기의 해석)

  • 김병주;손병후;구기갑
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.5
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    • pp.422-430
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    • 2001
  • In the present study, an evaporative generation process of ammonia-water solution film on the vertical plate was analysed. For the utilization of waste heat, hot water of low temperature was used as the heat source. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. Counter-current solution-vapor flow resulted in the refrigerant vapor of the higher ammonia concentration than that of co-current flow. Eve the rectification of refrigerant vapor was observed near the inlet of solution film in counter-current flow. For the optimum operation of generator using hot water, numerical experiments, based on the heat exchange and generation efficiencies. revealed the inter-relationships among the Reynolds number of the solution film and hot water, and the length of generator. Enhancement of heat and mass transport in the solution film was found to be very effective for the improvement of generation performance, especially at high solution flow rate.

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