• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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• pp.216-220
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• 1998

Experimental studies were carried out to investigate water diffusion in unsaturated compacted bentonite for a landfill of hazardous wastes. Water content distributions were measured and water diffusion coefficients were determined when the dry densities of compacted bentonite were in the range of 1.4 - 1.8 g/㎤. Resaturation times were also calculated to analyze the ability of the compacted bentonite to retard water movement. The results obtained were as follows: Diffusion model described properly the water migration in unsaturated compacted bentonite. Water diffusion coefficients ranged from 4.30$\times$10$^{-6}$ $\textrm{cm}^2$/sec to 1.93$\times$10$^{-6}$ $\textrm{cm}^2$/sec, and decreased with increasing the dry density. The dry density of compacted bentonite was found to be an important factor to control the resaturation time by water. This study suggests that the domestic compacted bentonite should be a good barrier material against water movement in a landfill of hazardous wastes.

• 펄프종이기술
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• 제30권3호
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• pp.46-56
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• 1998

The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 추계 학술논문 발표대회
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• pp.127-131
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• 2009

The purpose of this study is to provide fundamental data on chloride diffusion from lightweight aggregate concrete by utilizing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated after experiment based on NT BUILD 492. Diffusion coefficient of SLG and CLG were little bit higher than CG Concrete, but the difference is meaningless. Also, chloride diffusion coefficient indicates that it is highly affected by water-binder ratio, and it decreases with the decrease in water-binder ratio. The admixture substitution indicates decrease only with water-binder ratio of 0.4 for FA15% case, but admixture substitution indicates decrease with all levels of ratio for FA10 + BFS20% which means more appropriate. According to the analysis result of chloride diffusion from lightweight aggregate concrete, crushed stone-powder utilized lightweight aggregate concrete indicates higher chloride diffusion coefficient than CG concrete, which is not a significant difference, and can improve resistance through water-binder ratio and admixture substitution.

• 상하수도학회지
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• 제13권1호
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• pp.72-80
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• 1999

Separation of VOCs(Volatile Organic Compounds) in Water Using Activated Carbon is known to be effective. Activated Carbon has been and will be employed in many water treatment plants. Simplified plug flow homogeneous surface diffusion model(PFHSDM) has been used to predict adsorption of organic matter. Finite Element Method(FEM) was used to analyze the model. Out of water quality control substances, benzene, toluene and tetrachloroethylene were used in the small column test. Film diffusion coefficients and surface diffusion coefficients were obtained from the column test, and were compared with the modeling results. Mc Cune, Williamson, William and Kataoka model, were compared with film diffusion coefficients obtained in the test. McCune model was fitted best for those VOCs used in this experiment. Film diffusion coefficients of VOCs obtained were benzene 0.265 cm/min, toluene 0.348 cm/min and tetrachloroethylene 0.298 cm/min. Surface diffusion coefficients of VOCs obtained were benzene $6.36{\times}10^{-8}cm^2/min$, toluene $3.20{\times}10-8cm2/min$, and tetrachloruethylene $4.94{\times}10^{-8}cm^2/min$.

• 콘크리트학회지
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• 제8권5호
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• pp.135-143
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• 1996

콘크리트 및 모르터중의 수분의 확산 거동은 탄성계수, 크리프, 건축수축 등의 역학적 성질에 큰 영향을 미친다. 일반적으로 건조과정에서 폴리머 시멘트 콘크리트와 모르터의 수분의 증발에 의한 중량감소는 내부의 폴리머 필름형성에 의한 보수효과로 보통 시멘트 콘크리트 및 모르터에 비해 월등히 적다. 본 연구는 폴리머 시멘트 모르터 내부의 수분의 확산 과정을 확인하기 위하여 3종류의 폴리머디스퍼션과 에폭시 수지를 사용한 폴리머 시멘트 모르터를 제조하여 건조조건에 따른 수분의 확산 정도를 확산계수로 평가하였다. 실험결과, 폴리머 시멘트 모르터의 수분확산은 보통 시멘트 모르터에 비하여 아주 적었으며 폴리머 시멘트비에 따라 감소하였다.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 연료전지심포지움 2001논문집
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• pp.179-184
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• 2001

The diffusion layer within MEA(membrane electrode assembly) has been evaluated important factor for improvement of cell performance in DMFC. The diffusion layer in MEA structure leads to the reduction of catalyst loss in active catalysts layer as well as prevention of water-flooding in cathode. Cell performance is directly affected by interior properties of diffusion layer materials. Acetylene Black and $RuO_2$ with large pore size and low porosity compared to Vulcan XC-72R gave better performance caused by vigorous methanol diffusion and water removal. And $RuO_2$ as diffusion layer materials showed different behavior in anode and cathode compartment, that is, diffusion layers in anode and cathode side make methanol diffusion and water removal facilitate, respectively.

• 한국항만학회지
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• 제13권2호
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• pp.419-426
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• 1999

It is essential for port planning, coastal zone management and environmental impact study to analyze the variation of current and water quality due to the development of water area and discharged water from estuary barrage and basin etc. Mokpo sea area downstreams from a long river and two large basins, the Yongsan river and Yongam-Kumho basins discharging much of water through water gates for the purpose of flood control and prohibition of salt intrusion to the inland fresh water area. In this study, the numerical calculations were carried out for the analysis of diffusion characteristics due to discharging operation, adapting the results of tidal current simulation ADI methord is applied to the governing equation for the movement of sea water and diffusion and 6-point method to the advection terms of diffusion equation. As the results of this study, it is known that the discharging operation causes increasing and/or decreasing of current velocity and enlarging and/or depressing of pollutant diffusion limits depending on the distance from the discharging gates and the mode of discharging operation. To utilize these result, the linked gate operation and the method increasing exchange of sea water must be considered.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 1999년도 추계학술대회논문집
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• pp.253-261
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• 1999

It is essential for port planning, coastal zone management and environmental impact study to analyze the variation of current and water quality due to the development of water area and discharged water from the estuary barrage and basin, etc. Mokpo sea area has downstream from a long river and two large basins, the Yongsan river and Yongam-Kumho basins, discharging much of water through water gates for the purpose of flood and prohibition of salt intrusion to the inland fresh water area. In this study, the numerical calculation were carried out for the analysis of diffusion characteristics due to discharging operation, adopting the results of tidal current simulation. ADI method is applied to the governing equation for the movement of sea water and diffusion and 6-point method to the advection terms of diffusion equation. As the results of this study, it is known that the discharging operation causes increasing and/or decreasing of current velocity and enlarging and/or depressing of pollutant diffusion limits depending on the distance from the discharging gates and the modes of discharging operation. To utilize these result, the linked gate operation and the method increasing exchange of sea water must be considered.

• Advances in concrete construction
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• 제4권4호
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• pp.305-317
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• 2016

Porous materials such as concrete could be subjected to aggressive ions transport. Durability of cement paste is extremely depended on water and ions penetration into its interior sections. These ions transport could lead different damages depending on reactivity of ions, their concentrations and diffusion coefficients. In this paper, chloride diffusion process in cement hydrates is simulated at atomistic scale using molecular dynamics. Most important phase of cement hydrates is calcium silicate hydrate (C-S-H). Tobermorite, one of the most famous crystal analogues of C-S-H, is used as substrate in the simulation model. To conduct simulation, a nanopore is considered in the middle of simulation cell to place water molecules and aggressive ions. Different chloride salts are considered in models to find out which one is better for calculation of the transport properties. Diffusion coefficients of water molecules and chloride ions are calculated and validated with existing analytical and experimental works. There are relatively good agreements among simulation outputs and experimental results.

• 한국의류학회지
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• 제3권2호
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• pp.37-41
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• 1979

In order to obtain tasic information for solvent dyeing, polyethylene terephthalate (PET) films was pretreated with water, tetrachloroethylene (TCE) and water/TCE emulsion for three hours at $140^{\circ}C$ for stabilizing the substrate. By film roll cyliderical method, Disperse Red 60, Disperse Yellow 42, and Disperse Blue 27 were diffused in the films and examined dyeing properties. The results are summarized as follows; 1) Diffusion coefficient increases in the order, waterTCE>water/TCE 2) A linear relationship between diffusion coefficient and shrinkage was Observed 3) The temperature dependence of the diffusion coefficient can't be expressed by WLF equation.