• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.588-588
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• 2012

Zn-doped $TiO_2$ mesoporous microspheres with high photocatalytic activity were synthesized via combined sol-gel and solvothermal methods for photocatalytic water splitting. It is found that the photocatalytic water splitting and photocatalytic degradation activity can be enhanced by doping an appropriate amount of Zn. Our results reveal that Zn doping inhibits the recombination of photo-generated charge carriers of $TiO_2$ and improves the probability of photo-generated charge carrier separation and hence the photocatalytic activity of $TiO_2$.

• 조명전기설비학회논문지
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• 제16권4호
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• pp.101-107
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• 2002

본 논문은 종래형 전해수 발생장치의 평판전극을 슬릿형 평행평판전극 구조로 함으로써 고효율의 강전해수 발생장치를 제안하였다. 염화나트륨이 용해된 수도수와 일반 수도수를 본 강전해수 발생장치에 인입하였을 때 전해수 생성공간내의 공간전하제한작용을 크게 감소시키면서 또한 이 전해수 생성공간내의 전계분포를 집중시킬 수 있는 슬릿형 평행평판전극을 설정하고, 이러한 슬릿의 형태와 개수증가가 수중 이온분리집속성능에 미치는 영향과 산화성물질 생성에 미치는 영향을 연구 검토하였다. 실험결과 수중 강전해수 발생장치내에 슬릿을 형성함으로써 전해수 발생공간내의 전계를 집중시키고 분리집속된 고농도의 이온들에 의한 공간전하 제한작용을 크게 감소시켜 저전력에서 기존의 전해수 발생장치보다 훨씬 고농도의 강전해수와 산화성물질 용존수를 얻을 수 있었다.

• 상하수도학회지
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• 제18권2호
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• pp.222-227
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• 2004

Flotation processes involve the use of very small bubbles (micro-bubbles) to separate particles from water. The process has become a good alternative to sedimentation, especially where the particles are small or of low density. Although the flotation process commences with a collision between particles and bubbles, most research has been focused only on the characteristics of the particles. In this paper, recent theoretical and experimental research on the characteristics of bubbles is summarized. The effect on the collision efficiency of the size and charge of bubbles is calculated through trajectory analysis. The size and charge of bubbles are measured under different conditions and the ramifications of the results are discussed. The results may lead to a better understanding and optimization of the existing process. In particular, we discuss an idea that a new advanced flotation process might be possible by the modification of the characteristics of the bubble alone or of both bubble and particle.

• 화약ㆍ발파
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• 제22권3호
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• pp.57-64
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• 2004

국내에서 적용되는 수중발파는 교량의 기초를 위한 수중 우물통 발파와 항만의 수로 증심 또는 준설을 위하여 적용되고 있다 그 중 교각의 기초를 위한 우물통 발파는 우물통내 물을 인위적으로 배수시켜 건조한 상태에서의 천공과 장약을 실시한 후 물을 다시 채운 후 수중에서의 발파를 수행하고 있어 전체적인 작업이 일반 노천발파와 동일하다 할 수 있다. 그러나 항만의 수로 증심과 준설을 위한 수중 발파는 수중 천공이 가능하도록 고안된 바지선을 이용하여 수중에서 천공과 장약 발파 작업이 이루어지는 특수성을 가지고 있다. 따라서 일반 터널이나 벤치발파와는 다르게 장약의 방법과 결선의 방법에 주의를 기울이지 않으면 수압에 의한 사압 등 어려운 조건하에서 불발이 야기될 수 있다. 본 사례연구는 국내 부산항 증심 준설공사에서 수중발파의 특수성을 고려하여 다이너마이트 (메가마이트 I)를 이용한 수중 발파의 장약량 선정과 파이프를 이용한 장약의 방법, 그리고 TLD를 이용한 기폭시스템이 수면위에서 기폭 될 수 있도록 부이를 이용한 결선방법을 적용하여 수중발파를 실시하고 사례별 결과를 비교하였다. 그 결과, 수중발파 장약량 설계에 따른 지발당장약량에 따른 진동의 예측과 실 계측을 통하여 예측 진동식의 타당성을 검증하였으며, 장약의 방법과 결선방법에 따라 발생될 수 있는 불발을 최소화시킬 수 있을 것이다. 따라서, 최적발파 효과와 안전한 발파를 수행하기 위하여, 천공경은 150mm이상, 화약은 고성능 수중 다이너마이트(메가마이트 II), 그리고 뇌관은 비전기뇌관을 적용하는 것이 가장 유리할 것으로 판단된다.

• 한국태양에너지학회 논문집
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• 제33권1호
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• pp.15-23
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• 2013

In this study, thermodynamic performance of R435A is examined both numerically and experimentally in an effort to replace HFC134a used in the refrigeration system of domestic water purifiers. Even though HFC134a is used predominantly in such a system these days, it needs to be phased out in the near future in Europe and most of the developed countries due to its high global warming potential. To solve this problem, cycle simulation and experimental measurements are carried out with a new refrigerant mixture of 20%R152a/80%RE170 using actual domestic water purifiers. This mixture is numbered and listed as R435A by ASHRAE recently. Test results show that the system performance with R435A is greatly influenced by the amount of charge due to the small internal volume of the refrigeration system of the domestic water purifiers. With the optimum amount of charge of 21 to 22 grams, about 50% of HFC134a, the energy consumption of R435A is 11.8% lower than that of HFC134a. The compressor discharge temperature of R435A $8^{\circ}C$ lower than that of HFC134a at the optimum charge. Overall, R435A, a new long term environmentally safe refrigerant, is a good alternative for HFC134a requiring little change in the refrigeration system of the domestic water purifiers.

• 설비공학논문집
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• 제21권2호
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• pp.109-117
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• 2009

In this study, thermodynamic performance of R430A is examined both numerically and experimentally in an effort to replace HFC134a used in the refrigeration system of domestic water purifiers. Even though HFC134a is used predominantly in such a system these days, it needs to be phased out in the near future in Europe and most of the developed countries due to its high global warming potential. To solve this problem, cycle simulation and experimental measurements are carried out with a new refrigerant mixture of 76%R152a124% R600a using actual domestic water purifiers. This mixture is numbered and listed as R430A by ASHRAE recently. Test results show that the system performance with R430A is greatly influenced by the amount of charge due to the small internal volume of the refrigeration system of the domestic water purifiers. With the optimum amount of charge of 21 to 22 grams, about 50% of HFC134a, the energy consumption of R430A is 13.4% lower than that of HFC 134a. The compressor dome and discharge temperatures and condenser center temperature of R430A are very similar to those of HFC134a at the optimum charge. Overall, R430A, a new long term environmentally safe refrigerant, is a good alternative for HFC134a requiring little change in the refrigeration system of the domestic water purifiers.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권2호
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• pp.79-85
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• 2001

A conventional electrolyzing cell has been made by an ion exchange membrane inbetween parallel plate electrodes. A low dc voltage is applied to the electrodes for electrolyzing and the efficiency is remained in low. in this study, a novel electrolyzing cell with a pair of slit-type third electrodes installed inbetween parallel plate electrodes has been proposed and investigated experimentally. And pulse power wa supplied to between each electrodes. This slit type of third electrodes can concentrate the strong electric fields at the every its edges to accelerate the electrolyzing powers, and to generate oxygen bubble discharges for generating oxidants. And moreover the slits eliminate the space charge limiting action and the temperature of the water by leaking out through the slits from electrolyzing region to outside of the main electrode region. As a result, it was found that a strong electorzed water of pH 2.8 and pH 10.5 and oxidants dissolved water of 1 [ppm] in acidic water were obtained with a tap water fed at the electric current of 2 [A], which however were several times higher oxidant and ion concentration quantity compared with the conventional cell.

• Bulletin of the Korean Chemical Society
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• 제6권1호
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• pp.23-29
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• 1985

The charge-transfer complexing properties of 1-methyl nicotinamide (MNA), an acceptor, and adenine, a donor, were investigated in water and SDS micellar solutions in relation to the intramolecular interaction in nicotinamide adenine dinucleotide ($NAD^+$). The spectral and thermodynamic parameters of MNA-indole and methyl viologen-adenine complex formations were determined, and the data were utilized to evaluate the charge-transfer abilities of MNA and adenine. The electron affinity of nicotinamide was estimated to be 0.28 eV from charge-transfer energy $of{\sim}300$ nm for MNA-indole. The large enhancement of MNA-indole complexation in SDS solutions by entropy effect was attributed to hydrophobic nature of indole. The complex between adenine and methyl viologen showed an absorption band peaked near 360 nm. The ionization potential of adenine was evaluated to be 8.28 eV from this. The much smaller enhancement of charge-transfer interaction involving adenine than that of indole in SDS solutions was attributed to weaker hydrophobic nature of the donor. The charge-transfer energy of 4.41 eV (280 nm) was estimated for nicotinamide-adenine complex. The spectral behaviors of $NAD^+$ were accounted to the presence of intramolecular interaction in $NAD^+$, which is only slightly enhanced in SDS solutions. The replacement of nicotinamide-adenine interaction in $NAD^+$ by intermolecular nicotinamide-indole interaction in enzyme bound $NAD^+$, and guiding role of adenine moiety in $NAD^+$ were discussed.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.70-70
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• 2013

As the costs of carbon-footprinetd fuels grow continuously and simultaneously atmospheric carbon dioxide concentration increases, solar fuels are receiving growing attention as alternative clean energy carriers. These fuels include molecular hydrogen and hydrogen peroxide produced from water, and hydrocarbons converted from carbon dioxide. For high efficiency solar fuel production, not only light absorbers (oxide semiconductors, Si, inorganic complexes, etc) should absorb most sunlight, but also charge separation and interfacial charge transfers need to occur efficiently. With this in mind, this talk will introduce the fundamentals of solar fuel production and artificial photosynthesis, and then discuss in detail on photoelectrochemical (PEC) water splitting and CO2 conversion. This talk largely divides into two section: PEC water oxidation and PEC CO2 reduction. The former is very important for proton-coupled electron transfer to CO2. For this oxidation, a variety of oxide semiconductors have been tested including TiO2, ZnO, WO3, BiVO4, and Fe2O3. Although they are essentially capable of oxidizing water into molecular oxygen, the efficiency is very low primarily because of high overpotentials and slow kinetics. This challenge has been overcome by coupling with oxygen evolving catalysts (OECs) and/or doping donor elements. In the latter, surface-modified p-Si electrodes are fabricated to absorb visible light and catalyze the CO2 reduction. For modification, metal nanoparticles are electrodeposited on the p-Si and their PEC performance is compared.

• 한국건설순환자원학회논문집
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• 제10권3호
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• pp.307-313
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• 2022

본 연구에서는 3가지 수준의 물-시멘트 비, 상부 염수 농도, 피복 두께를 고려하여 반 전위와 영향인자들 간의 상관성을 분석하였다. 장기 부식 모니터링 결과 염수 농도 3.5, 7 %에서 초기에 모든 물-시멘트 비에서 임계부식전위(-350mV)에 근접하는 거동을 보였다. 통과 전하량 시험 결과 548일에서 모든 배합에서 'Moderate' 등급으로 개선된 통과 전하량이 평가되었다. 부식 영향인자와 반 전위 값 간의 상관성을 평가 하고자 다중 회귀분석을 수행하였는데, 염수 농도, 물-시멘트 비, 피복 두께 순으로 영향을 준 것으로 평가되었다. 반 전위와 통과 전하량간의 상관성 분석 결과는 0.9로 높은 수준의 결정계수를 보였으며, 통과 전하량과 반 전위 값 간에는 밀접한 상관성이 존재하는 것으로 판단된다.