• Title/Summary/Keyword: Water and heat degradation

Search Result 66, Processing Time 0.021 seconds

A Numerical Model for the Freeze-Thaw Damages in Concrete Structures

  • Cho Tae-Jun
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.5 s.89
    • /
    • pp.857-868
    • /
    • 2005
  • This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

Corrosion Resistance of Degraded STS310S and STS347H by Cr-free Modified Si Organic/Inorganic Hybrid Coating Solution (Cr-free Si 변성 유/무기하이브리드 코팅액에 의한 열화된 STS310S 및 STS347H의 내식성)

  • Lee, So-Young;Kim, Young-Soo;Jeong, Hee-Rok;Kim, Gui-Shik;Nam, Ki-Woo
    • Journal of Power System Engineering
    • /
    • v.19 no.6
    • /
    • pp.12-18
    • /
    • 2015
  • Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

Electrical Properties about Thermal and Water Degradation of Epoxy Powder for Bus Duct (부스닥트용 에폭시 분체도료의 열 및 수중열화에 대한 전기적 특성)

  • Kim, Hyun-Hee;Kim, Sang-Hyun
    • Fire Science and Engineering
    • /
    • v.23 no.3
    • /
    • pp.17-22
    • /
    • 2009
  • Epoxy powder is being in use for insulation materials widely. Especially, in cause of coating insulation can be caused electrical fire and explosion by Joul's heat. This study has been compared and examined around breakdown, arc discharge, and V-t about insulation of Epoxy powder. Also, it has been researched about insulation which is cause of electrical fire and its basic data. According to temperature change, sample KS was stable before the Tg to be about $8{\sim}10%$ decrease in the breakdown test. In case of V-t and arc discharge, it had been kept up suitable characteristic. Also, in case of electrical characteristic, sample KS has excellent capacity.

Crack growth rate evaluation of alloys 690/152 by numerical simulation of extracted CT specimens

  • Lee, S.H.;Kim, S.W.;Cho, C.H.;Chang, Y.S.
    • Nuclear Engineering and Technology
    • /
    • v.51 no.7
    • /
    • pp.1805-1815
    • /
    • 2019
  • While nickel-based alloys have been widely used for power plants due to corrosion resistance and good mechanical properties, during the last couple of decades, failures of nuclear components increased gradually. One of main degradation mechanisms was primary water stress corrosion cracking at dissimilar metal welds of piping and reactor head penetrations. In this context, precise estimation of welding effects became an important issue for ensuring reliability of them. The present study deals with a series of finite element analyses and crack growth rate evaluation of Alloys 690/152. Firstly, variation of residual stresses and equivalent plastic strains was simulated taking into account welding of a cylindrical block. Subsequently, extraction and pre-cracking of compact tension (CT) specimens were considered from different locations of the block. Finally, crack growth curves of the alloys and heat affected zone were developed based on analyses results combined with experimental data in references. Characteristics of crack growth behaviors were also discussed in relation to mechanical and fracture parameters.

Fatigue Life Analysis of SA508 Gr. 1A Low-Alloy Steel under the Operating Conditions of Nuclear Power Plant (원자력발전소 운전환경에서 SA508 Gr. 1A 저합금강의 피로 수명 분석)

  • Lee, Yong Sung;Kim, Tae Soon;Lee, Jae Gon
    • Transactions of the Korean Society of Pressure Vessels and Piping
    • /
    • v.6 no.1
    • /
    • pp.50-56
    • /
    • 2010
  • Fatigue has been known as a major degradation mechanism of ASME class 1 components in nuclear power plants. Fatigue damage could be accelerated by combined interaction of several loads and environmental factors. However, the environmental effect is not explicitly addressed in the ASME S-N curve which is based on air at room temperature. Therefore many studies have been performed to understand the environmental effects on fatigue behavior of materials used in nuclear power plants. As a part of efforts, we performed low cycle fatigue tests under various environmental conditions and analyzed the environmental effects on the fatigue life of SA508 Gr. 1a low alloy steel by comparing with higuchi's model. Test results show that the fatigue life depends on water temperature, dissolved oxygen and strain rate. But strain rate over 0.4%/s has little effect on the fatigue life. To find the cause of different fatigue life with ANL's and higuchi's model, another test performed with different heat numbered and heat treated materials of SA508 Gr. 1a. On a metallurgical point of view, the material with bainite microstructure shows much longer fatigue life than that with ferrite/pearlite microstructure. And the characteristics of crack propagation as different microstructure seem to be the main cause of different fatigue life.

  • PDF

A Study on Optimization of The Concentration of Cutting Oil to be used for Cutting (절삭가공(切削加工)에 사용(使用)되는 절삭유(切削油)의 농도최적화(濃度最適化)에 관(關)한 연구(硏究))

  • Kim, Gue-Tae;Kim, Won-Il
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.16 no.3
    • /
    • pp.95-102
    • /
    • 2013
  • It is indispensable to modern society metal processing since the industrialized rapidly, but it is a metalworking cutting fluid immediately. In addition, this means selecting a emulsion on the basis of quality criteria processing method, the material of the material, cutting depth, cutting speed, Djourou fence Liang, and surface roughness, cutting oil, the shape of the device based on the emulsion, I will be the structure of the tank, filtration equipment also changes. In particular, acting bacteria is now breeding in response to the passage of time due to metal ion degradation due to heat generated hydraulic fluid leakage, humidity tung, during processing, seep from processing material at the time of processing the water-soluble cutting oil for generating the malodor by dropping significantly the performance of the cutting oil to corruption from, sometimes by introducing various additives to suppress spoilage in advance. In this study, we expect the effect of the cost reduction in the extension of fluid replacement cycle through the application of the management apparatus and deep understanding in the management of cutting fluid, the working environment through the understanding and interest of workers in the production site more than anything I try to become useful for the improvement.

Efficiency Investigation of Vanishing Composting Machine Using Exhaust gas Recirculation system (배기가스순환시스템을 적용한 소멸 퇴비화장치의 효율검토)

  • Phae, Chae-Gun;Kim, Jong-Chan
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.7 no.2
    • /
    • pp.93-104
    • /
    • 1999
  • Existing composting system was improved to have a high performance for organic degradation, deodorization and energy reduction. Compared with conventional devices, this developed system uses the heat recovered from platinum catalytic tower by three times heat exchange in which 65% of exhaust gas was recirculated. Evaporation of water was made easy by maintaining negative pressure in entire system. It was possible for reaction to be maintained steadily by microorganism agent. The optimum mixing volume ratio of garbage to sawdust was 15:1 contrary to 20:1 in conventional one. Moreover, aerobic condition was maintained efficiently. Effects obtained by using a inner circulation system were as follows. It was possible to reduce the ammonia causing offensive odor and verified that consumption of electricity cut down to 1/3 with reduction of exhaust gas inflowing. According to this inner circulation, the optimum air flow was $0.44m^3$ to 100kg treatment capacity. The electricity consumption was changed in proportion to inflowing air volume.

  • PDF

Solubility and Stability of Melatonin in Propylene glycol and 2-hydroxypropyl-${\beta}$-cyclodextrin vehicles

  • Lee, Beom-Jin;Choi, Han-Gon;Kim, Chong-Kook;Parrott, Keith-A.;Ayres, James-W.;Sack, Robert-L.
    • Archives of Pharmacal Research
    • /
    • v.20 no.6
    • /
    • pp.560-565
    • /
    • 1997
  • The physicochemical properties of melatonin (MT) in propylene glycol (PG) and 2-hydroxypropyl-.betha.-cyclodextrin $(2-HP{\beta}CD)$ vehicles were characterized. MT was endothermally decomposed as determined by differential scanning calorimetry (DSC). Melting point and heat of fusion obtained were $116.9{\pm}0.24^{\circ}C $.and $7249{\pm}217 cal/mol$., respectively. MT as received from a manufacture was very pure, at least 99.9%. The solubility of MT in PG solution increased slowly until reaching 40% PG and then steeply increased. Solubility of MT increased linearly as concentration of $2-HP{\beta}CD$ without PG INCREASED$(R^2=0.993)$. MT solubility in the mixtures of pg and $2-HP{\beta}CD$ also increased linearly but was less than the sum of its solubility in $2-HP{\beta}CD$ and PG individually. The MT solubility was low in water, simulated gastric or intestinal fluid but the highest in the mixture of PG(40v/v%) and $2-HP{\beta}CD$ (30w/v%) although efficiency of MT solubilization in $2-HP{\beta}CD$ decreased as the concentration of PG increased. MT was degraded in a fashion of the first order kinetics $(r^2>0.90)$. MT was unstable in strong acidic solution (HCl-NaCl buffer, pH 1.4) but relatively stable in other pH values of 4-10 at $70^{\circ}C$. In HCl-NaCl buffer, MT in 10% PG was more quickly degraded and then slowed dpwm at a higher concentration. However, the degradation rate constant of MT in 2-HP.betha.CD was not changed significantly when compared to the water. The current studies can be applied to the dosage formulations for the purpose of enhancing percutaneous absorption or bioavailability of MT.

  • PDF

Research on a Stability of Feedwater Control System after Stretched Power Uprate and Replacement Steam Generator for Ulchin Units 1&2 (울진1,2호기 출력최적화 및 증기발생기 교체가 주급수 제어계통 안정도에 미치는 영향연구)

  • Yoon, Duk-Joo;Kim, In-Hwan;Kim, Sang-Yeol
    • Transactions of the Korean Society of Pressure Vessels and Piping
    • /
    • v.8 no.2
    • /
    • pp.14-20
    • /
    • 2012
  • Full load rejection capability of nuclear power plant depends primarily on steam dump capacity (SDCAP) and steam generator level control capability. Recently, Ulchin Units 1&2 have performed stretched power uprate (SPU) and replacement steam generator (RSG) projects, which increase the power by 4.5 percent. They change major design or operating parameters and especially reduces steam dump capacity at full power due to increase of the steam flow. The reduction of SDC after SPU results in degradation of heat removal capability in full load rejection transients. Therefore, we should perform evaluation to determine whether reactor trips occur in large load rejection transients. Uchin Units 1&2 have experienced full load rejection (FLR) three times from 2004 to 2010. Operating data from the plant occurrence of FLR at Ulchin Units 1&2 showed that steam generator (SG) level transients were limiting in point of reactor trip. However the plant had never reached reactor trip in the FLR and successfully continued in house load operation. The parameters and setpoints for the SG will be changed if the SG is replaced. Therefore, we evaluated the appropriateness of steam dump, main feedwater and steam generator water level control system preventing the plant from reactor trip in case of FLR by the parameter sensitivity study whether SG water level operated smoothly after SPU and RSG projects.

UNCERTAINTY AND SENSITIVITY ANALYSIS OF TMI-2 ACCIDENT SCENARIO USING SIMULATION BASED TECHNIQUES

  • Rao, R. Srinivasa;Kumar, Abhay;Gupta, S.K.;Lele, H.G.
    • Nuclear Engineering and Technology
    • /
    • v.44 no.7
    • /
    • pp.807-816
    • /
    • 2012
  • The Three Mile Island Unit 2 (TMI-2) accident has been studied extensively, as part of both post-accident technical assessment and follow-up computer code calculations. The models used in computer codes for severe accidents have improved significantly over the years due to better understanding. It was decided to reanalyze the severe accident scenario using current state of the art codes and methodologies. This reanalysis was adopted as a part of the joint standard problem exercise for the Atomic Energy Regulatory Board (AERB) - United States Regulatory Commission (USNRC) bilateral safety meet. The accident scenario was divided into four phases for analysis viz., Phase 1 covers from the accident initiation to the shutdown of the last Reactor Coolant Pumps (RCPs) (0 to 100 min), Phase 2 covers initial fuel heat up and core degradation (100 to 174 min), Phase 3 is the period of recovery of the core water level by operating the reactor coolant pump, and the core reheat that followed (174 to 200 min) and Phase 4 covers refilling of the core by high pressure injection (200 to 300 min). The base case analysis was carried out for all four phases. The majority of the predicted parameters are in good agreement with the observed data. However, some parameters have significant deviations compared to the observed data. These discrepancies have arisen from uncertainties in boundary conditions, such as makeup flow, flow during the RCP 2B transient (Phase 3), models used in the code, the adopted nodalisation schemes, etc. In view of this, uncertainty and sensitivity analyses are carried out using simulation based techniques. The paper deals with uncertainty and sensitivity analyses carried out for the first three phases of the accident scenario.