• Title/Summary/Keyword: Water absorbance

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The Study on the Humic Acid Removal using Underwater Plasma Discharge (수중 방전을 이용한 휴믹산 제거)

  • Hong, Eunjung;Chung, Paulgene;Ryu, Seungmin;Park, Junseuk;Yoo, Seungryul;Lho, Taihyeop
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.367-374
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    • 2012
  • A flotation process has a shorter processing time and needs less space than a sedimentation process. Dissolved air flotation process (DAF) is an efficient flotation method and used in a conventional wastewater treatment process. However, DAF requires the circulation of water containing compressed air and requires expensive installation and operation cost. Plasma Air Flotation (PAF) process is able to float flocs by micro bubbles generated from underwater plasma without the circulation of bubbly water and additional saturators. Therefore, PAF can be an alternative solution overcoming economic barriers. In this study, Humic acid removal efficiency by PAF process was compared with that of sedimentation process. 44.67% and 87.3% reduction rate based on UV 254 absorbance has been measured in sedimentation and PAF respectively. In particular, PAF in the flocculation zone can dramatically remove humic acid from water. In flocculation zone, PAF can separate organic matters but sedimentation cannot.

Studies on Equilibria and Analytical Applications of Synergistic Solvent Extraction(II). Determination of Trace Lithium in Sea Water using TTA and TOPO

  • Kim, Yeong Sang;Choe, Jong Mun;Lee, Chi U
    • Bulletin of the Korean Chemical Society
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    • v.21 no.9
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    • pp.855-859
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    • 2000
  • An application of synergistic solvent extraction for the etermination of trace lithium in sea water has been studied by forming an adduct complex of thenoyltrifluoroacetone (TTA) and trioctylphosphine oxide (TOPO) in a solvent. The interference by major constituents in sea water was eliminated by phosphate precipitation. Ex-perimental conditions such as solution pH, concentrations of TTA and TOPO etc. were optimized in synthetic sea water with similar compositionto its natural counterpart. To eliminate the interference, 1.38g of ammoni-um dihydrogen phosphate and 2.5 mL of ammonia water were added into 100 mL of thediluted solution at $60^{\circ}C$ to form the phosphate precipitates of Ca2+ and Mg2+ ions. After the pH of this filtrate was adjusted to 8.0, 10.0 mL of m-xylene containing 0.1 M TTA and 0.05 M TOPO was added to the solution in a separatory funnel, and the solution was shaken vigorously for 20 minutes. The solvent was separated from the aqueous solution, and 20 uL of m-xylene solution was injected into a gaphite tube to measure the absorbance by GF-AAS. The detection limit was 0.42 ng/mL. Lithium was determined within the range of 146 to 221 ng/mLin Korean coast-al sea waters, and the recoveries in the spiked samples were 94 to 106%.

Molecular Weight Distribution Characterization of Organics for the Dongbok Lake Water by Coagulation and Adsorption of Activated Carbon (동복 호소수의 응집침전 및 활성탄 흡착에 의한 용존유기물 분자량 분포 특성)

  • 정경훈;최형일
    • Journal of Environmental Science International
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    • v.7 no.1
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    • pp.104-111
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    • 1998
  • The Dongbok lake water before and after alum coagulation and activated carbon adsorption were analyzed in terms of organic contents, molecular weight distributuin (MWD), and UV-absorbance. Dissolved organic compounds in the Dongbok lake were fractionated into three molecular size classes by gel permeation chromatography. The fractionation was reasonably successful in isolating compounds with The bulk of the dissolved carbon was present in compounds of molecular weight in the range of 3,000~10,000. Alum coagulation preferentially treated molecules of high molecular weight, which has molecules larger than 10,000. The dissolved organic carbon (DOC) removal after activated carbon adsorption was high in the Fraction B , IR . The $A_{260}$/DOC ratio after alum and activated carbon treatment the Fraction II, III. This results suggest that the organics remaining after each treatment has a trihalomethane formation potential

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Improvement of the Exisiting Nuclear Concrete Structures Durability Using Surface Penetration Sealer (표면침투제를 이용한 원전구조물의 내구성 향상)

  • Lho, Byeong-Cheol;Choi, Kyu-Hyung;Lee, Sang-Min
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.257-260
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    • 2004
  • The durability and water - resisting capability of nuclear concrete structures can be greatly improved as the density of concrete surface increases. Applying the surface penetration sealer to the concrete surface can increase the surface density. Therefore, the objective of this study is to identify the most suitable surface penetration sealer based on lab test. The considered parameters rate and water resistance and absorbance rate of the concrete specimen after the penetration sealer are applied. The experimental study resulted in the identification of the two most suitable surface penetration sealer based on their performance.

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Measurement of turbidity using Infrared Ray (적외선 광원을 이용한 탁도 측정)

  • Youm, Sungkwan;Shin, Kwang-Seong
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2021.05a
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    • pp.263-264
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    • 2021
  • The importance of evaluation and management of drinking water quality is emerging among the impacts of industrial changes and environmental destruction. Currently, the turbidity-related laws in Korea are regulated, and the low-concentration turbidity of 1.0 NTU or less must be maintained for process management, and control technology remains a necessary task. In this study, absorbance experiments according to turbidity were conducted using 470nm, 670nm, and 850nm, and water quality was measured using a light source of 850nm and a light receiving device of 820nm.

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The Study on Manufacture of PACl(Polyaluminum Chloride) from Water Treatment Plant Sludges (정수장 슬러지(Alum Sludge)로부터 PACl(Polyaluminum Chloride) 응집제 제조에 관한 연구)

  • Kim, In-Bae;Lee, Sang-Bong;Kim, Dong-Youn;Kim, Boo-Gil
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.3
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    • pp.441-451
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    • 2000
  • Sludge produced from water treatment plants contains plenty of aluminum due to addition of coagulants, polyaluminum chloride(PACI) which has been widely used in most of water treatment plants. however. the whole of PACI is imported from other countries. In this research. the effective methods for recycling PACI from sludge of water treatment plants were developed and evaluated. Aluminum chloride hexahydrate($AlCl_3{\cdot}6H_2O$) was obtained by sparging HCl gas aluminum extracted from sludge using hydrochloric acid (HCI). This aluminum chloride hexahydrate was solidified by decomposition at $180^{\circ}C$. and dissolved in water to produce PACI. The optimum extraction rate was obtained at the condition of 10 minutes of reaction time. $105^{\circ}C$ of reaction temperature. 27.65%(W/W) of HCI concentration. The KS experiment proved that manufactured aluminum chloride hexahydrate was 98.7% degree and the recycled PACI coagulants agreed with the KS standard. The optimum temperature of decomposition was $180^{\circ}C$ and the basicity of the PACI was decided upon the extent of decomposition The compared experiments between purchased coagulant and manufactured coagulant presented that both coagulants had same performance for turbidity, DOC, $UV_{254}$ absorbance. and chlorophyll-a.

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Effect of the Extruded Ginseng on Antioxidant Activity (압출 성형 인삼의 항산화 활성 증강 효과)

  • Kim, Sung-Hwan
    • Journal of the East Asian Society of Dietary Life
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    • v.17 no.3
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    • pp.402-408
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    • 2007
  • This study was conducted in order to evaluate the antioxidant activity of extruded ginseng in different extracted fractions. Each of the fractions obtained from extruded ginseng and ginseng (control) were extracted with 80% ethanol, and then the lipophilic components were removed with ether while the hydrophilic components were separated with water-saturated butanol. Each of the 80% ethanol/butanol/water layers were collected and evaporated to acquire samples for tests of saponin content and antioxidant activity. The antioxidant activity of extruded ginseng fractions and ginseng fractions were determined via the oxygen radical absorbance capacity (ORAC) assay. Overall, the extruded ginseng samples harbored saponin contents of 2.2 (Rg1), 2.3 (Re), 1.2 (Rc), 1.3 (Rb2), and 2.2 (Rd) times that measured in the ginseng prior to extrusion. Antioxidant capacity was also higher, not only in the 80% ethanol/butanol which harbor a significant quantity of saponin, but also in the water fractions, which harbor relatively low quantities of saponin as compared to the control samples. All three of the fractions extracted from extruded ginseng evidence significantly higher antioxidant capacity than the controls (0.05

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Development of Continuous Real-time COD Measurement Sensor with Double Beam and Multiple Wavelength Analysis (더블 빔 구조, 다파장 분석을 적용한 연속식 실시간 COD 측정 센서 개발)

  • Lee, Joon-Seok;Shin, Daejung;Hyoung, Gi-Woo;Ryu, In-Jae
    • Journal of Sensor Science and Technology
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    • v.23 no.4
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    • pp.272-277
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    • 2014
  • At present, the index of chemical oxygen demand (COD) is widely used as an indicator of organic water pollution with biochemical oxygen demand (BOD). But, traditional COD measurement method are not only with various chemical reagents exhausted, but also long time consumed, the operation procedure and the modification are much professional. This paper reported a novel COD measurement system using double-beam and multiple wavelength analysis UV-VIS spectrometries. It consists of pulsed xenon lamp, two-way optical fiber, optical switch, spectrometer and main processor. Proposed COD measurement system obtains any spectral information of water sample (KHP standard sample and two river water and wastewater) and reference sample (distilled water) in the range of 200~520 nm, corresponding to the COD concentration from 0 to 300 mg/L through calculating the UV absorbance. The system show improved precision and can work continuously fast at time interval about 25 seconds.

Inactivation of Sewage Microorganisms using Multi-Plasma Process (멀티 플라즈마 공정을 이용한 하수 미생물의 불활성화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.985-993
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    • 2014
  • For the field application of dielectric barrier discharge plasma reactor, a multi-plasma reactor was investigated for the inactivation of microorganisms in sewage. We also considered the possibility of degradation of non-biodegradable matter ($UV_{254}$) and total organic carbon (TOC) in sewage. The multi-plasma reactor in this study was divided into high voltage neon transformers, gas supply unit and three plasma modules (consist of discharge, ground electrode and quartz dielectric tube). The experimental results showed that the inactivation of microorganisms with treated water type ranked in the following order: distilled water > synthetic sewage effluent >> real sewage effluent. The dissolved various components in the real sewage effluent highly influenced the performance of the inactivation of microorganisms. After continuous plasma treatment for 10 min at 180 V, residual microorganisms appeared below 2 log and $UV_{254}$ absorbance (showing a non-biodegradable substance in water) and TOC removal rate were 27.5% and 8.5%, respectively. Therefore, when the sewage effluent is treated with plasma, it can be expected the inactivation of microorganisms and additional improvement of water quality. It was observed that the $NH_4{^+}$-N and $PO{_4}^{3-}$-P concentrations of sewage was kept at the constant plasma discharging for 30 min. On the other hand, $NO_3{^-}$-N concentration was increased with proceeding of the plasma discharge.

The Effects of PAC (Powdered Activated Carbon) on Water Treatment Performance of an Immersed Membrane System Using Flat-sheet Membrane Module (평막을 이용한 침지형 막여과시스템에서 고농도 분말활성탄 주입에 의한 수처리성능 개선 효과)

  • Gai, Xiang-Juan;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.2
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    • pp.195-201
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    • 2007
  • A submerged flat-sheet membrane separation system integrated with PAC (powdered activated carbon) was used in this research in order to investigate the effects of PAC on the efficiencies of operation and treatment and to evaluate the performance of the system. The experiments were carried out under operating conditions of a filtration rate of 0.38 m/d, water temperature of $20-28^{\circ}C$, and PAC dose of 0 g/L (Run-A) and 20 g/L (Run-B). The influent concentrations of TOC (total organic carbon), $NH_4{^+}-N$ (ammonia nitrogen) and $UV_{254}$ (UV absorbance at 254 nm) were 2.48 mg/L, 1.4 mg/L and 2.53 1/m, respectively. TOC removal of 43.2 and 73.6%, ammonia nitrogen removal of 4.9 and 15.9%, and $UV_{254}$ removal of 20.6 and 31.6% were obtained for Run-A and Run-B, respectively. During an experimental period of 33 days, no change was found in TMP (Run-B), but the TMP in Run-A increased by 5 kPa after 29 days. This research showed that the filtrate quality and the performance efficiency were enhanced when PAC was introduced into the filtration system.