• 제목/요약/키워드: Water Vapor Pressure

검색결과 422건 처리시간 0.036초

양이온 교환 및 염 함침을 통한 메조다공성 실리카와 유기-금속 구조체의 수분 흡착 특성 조절 (Control of Water-Adsorption Properties of Mesoporous Silica and MOF by Ion Exchange and Salt Impregnation)

  • 이은경;조강희;김상겸;임종성;김종남
    • 청정기술
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    • 제24권1호
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    • pp.55-62
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    • 2018
  • $90^{\circ}C$ 이하의 저온열원 구동 수분 흡착식 냉방 시스템에 사용되는 흡착제는 효과적인 냉열 생산을 위해서 상대습도($P/P_0$) 0.1 ~ 0.3에서 높은 수분 흡-탈착량 차를 보이는 것이 좋다. 메조다공성 실리카(MCM-41)와 다공성 유기-금속 구조체(MIL-101) 의 경우 최대 수분 흡착량은 많지만 상대습도($P/P_0$) 0.1 ~ 0.3 구간에서 각각 $0.027{g_{water}\;g_{ads}}^{-1}$, $0.074{g_{water}\;g_{ads}}^{-1}$의 낮은 수분 흡-탈착량 차를 갖는다. 이 연구에서는 메조다공성 실리카와 다공성 유기-금속 구조체의 표면 성질을 조절하여 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차를 증가시켰다. 주로 수분 흡착이 상대습도($P/P_0$) 0.5 ~ 0.7에서 일어나는 메조 다공성 실리카의 경우 알루미늄을 관능화 시킨 후에 염기도가 다른 여러 양이온($Na^+$, ${NH_4}^+$, $(C_2H_5)_4N^+$)들로 교환하거나 염($CaCl_2$)을 20 wt% 함침하여 각각의 흡착제들에 대해 $35^{\circ}C$에서 수분 흡착 등온선을 측정하였다. 양이온 교환 후 수분 흡착이 주로 일어나는 구간이 상대습도($P/P_0$) 0.5 부근으로 이동하였으나 여전히 상대습도($P/P_0$) 0.1 ~ 0.3에서 낮은 수분 흡-탈착량 차를 보였다. 하지만 흡습성을 갖는 염($CaCl_2$)을 20 wt% 함침한 메조다공성 실리카는 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차가 $0.027{g_{water}\;g_{ads}}^{-1}$에서 $0.152{g_{water}\;g_{ads}}^{-1}$으로 증가하였다. 수분 흡착이 상대습도($P/P_0$) 0.3 ~ 0.5에서 주로 일어나는 다공성 유기-금속 구조체에도 염($CaCl_2$)을 20 wt% 함침하였더니 상대습도($P/P_0$) 0.1 ~ 0.3에서 수분 흡-탈착량 차가 $0.330{g_{water}\;g_{ads}}^{-1}$까지 증가하였다.

농용(農用) 디이젤 엔진 연료(燃料)로서의 에타놀 이용(利用)에 관(關)한 연구(硏究) (Technical Feasibility of Ethanol as a Fuel for Farm Diesel Engines)

  • 유관희;배영환;유수남
    • Journal of Biosystems Engineering
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    • 제6권2호
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    • pp.1-8
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    • 1982
  • The objective of this study was to find out the technical feasibility of ethanol-diesel fuel blends as a diesel engine fuel. Fuel properties essential to the proper operation of a diesel engine were determined for blends containing several concentrations of ethanol in No. 2 diesel fuel. A single-cylinder diesel engine for a power tiller was used for the engine tests, in which load, speed and fuel consumption rate were measured. The fuels used in tests were No. 2 diesel fuel and a blend containing 10-percent ethanol and 90-percent No. 2 diesel fuel. The results of the study are summarized as follows. 1. It was not possible to blend ethanol and No. 2 diesel fuel as a homogeneous solution even though anhydrous ethanol was used. The problem of blending ethanol in No. 2 diesel fuel could be solved by adding butanol about 5% of the amount of ethanol in the blends. 2. Because ethanol had a much lower boiling point ($78.3^{\circ}C$ under atmospheric pressure) than a diesel fuel, it was necessary to store ethanol-diesel fuel blends airtight in order to prevent them from evaporation losses of ethanol. 3. The addition of ethanol to No. 2 diesel fuel lowered the fuel viscosity and the cetane rating, but a blend of 10% ethanol and 90% diesel fuel had a viscosity and a cetane rating well above the KS minimum values for No. 2 diesel fuel. 4. At the rated speed, the specific fuel consumption of No.2 diesel fuel was lower than that of the 10% ethanol blend for the almost entire range of load. However, under the overload condition the specific fuel consumption was lower for the 10% ethanol blend. 5. Under the variable-speed full-load tests, both fuels produced approximately the same torque and power. At the speeds of 1600rpm or below, the specific fuel consumption of No. 2 diesel fuel was lower than that of the 10% ethanol blend. At the speeds of 1600rpm or above, however, the specific fuel consumption was lower for the 10% ethanol blend. 6. At the ambient temperature above $15^{\circ}C$, the use of the 10% ethanol blend in the engine created a vapor lock in the fuel injection pump and stalled the engine. The vapor locking problem was overcome by chilling the surroundings of the fuel injection pump and the cylinder head with water.

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오염토양 복원을 위한 연직배수시스템의 지반공학적 특성 (Geotechnical Characteristics of Prefabricated Vertical Drain System for Contaminated Soil Remediation)

  • 신은철;박정준
    • 한국지반환경공학회 논문집
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    • 제8권5호
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    • pp.5-14
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    • 2007
  • 개발사업과 산업발달로 인하여 발생되는 유해화학물질과 유류사용량이 늘면서 화학물질과 유류를 저장하는 지하저장탱크에서의 오염물질 유출로 토양 및 지하수 오염이 심각해지고 있다. 또한, 산업지역, 공장지대가 밀집된 매립 지반에서는 투수계수가 낮아 오염물질 추출에 한계가 있다. 이러한 문제해결 방안의 하나로 연약지반 개량공법에서 사용되고 있는 연직배수재를 이용하여 기존의 복원기술인 진공추출공법, 토양세정공법의 효율을 증진시킨 연직배수시스템에 대한 연구를 수행하였다. 오염된 토양의 복원을 목적으로 사용한 연직배수시스템의 적용성 평가를 위하여 오염토양 복원시 오염지반에 영향을 주는 인자에 대한 지반공학적 특성 등을 분석하였다. 연직배수재의 수두손실 및 통수능 측정 결과, 진공압력과 연직배수재의 폭이 증가할수록 통수능은 배수재의 통수 단면적에 비례하여 증가하는 경향을 나타내었다. 축척효과에 의해 단면을 축소시킨 폭이 2.5 cm인 배수재의 경우에는 영향반경이 대략 14cm에서 16cm를 넘어가면서부터 간극수압이 더 이상 감소하지 않고 일정해지는 유효 영향범위로 판단하였다. 또한, 투기계수는 등가직경이 증가 할수록 감소하였으며, 흐름률이 높을수록 압력수두는 더 정밀한 값을 나타내어 평균 투기계수 값인 3.152 Darcy에 가까운 공기흐름률은 1,500~2,000 $cm^3/s$일 때 가장 정확한 값을 나타내었다.

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중대사고시 수소폭발이 격납건물에 미치는 영향 (Hydrogen explosion effects at a containment building following a severe accident)

  • 류명록;박권하
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권3호
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    • pp.165-173
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    • 2016
  • 2011년 3월 11일 리히터 스케일 9.0의 강진과 10-14m파도로 인해 Fukushima Daiichi(FD) 원자력 단지의 주전력과 보조전력이 끊어져 냉각장치가 작동하지 않았고 노심의 열이 제거되지 못해 폭발이 일어나는 사고가 발생했다. 노심의 열이 제거되지 못하면 핵연료 피복재인 지르칼로이(zircaloy)와 같은 금속이 고온 상태에서 수증기와 산화 반응하여 수소를 발생시킨다. 발생된 수소는 격납건물로 방출되는데 방출된 수소가 연소하는 경우 격납건물의 안정성에 영향을 줄 정도의 큰 충격을 유발할 수 있는 수소폭발로 이어질 수 있다. 본 연구에서는 격납건물 내부의 수소 분포를 분석한 연구 [1]에서 제시한 폭발의 위해도가 높은 영역에 대하여 폭발해석을 수행하였으며 수소 폭발이 격납건물의 건전성에 미치는 영향에 대하여 분석하였다. 격납건물 중앙부를 제외하고 수소폭발이 발생하였고 상부에 전체 수소의 40%이상이 모였을 때와 하부 좌측, 우측의 격벽사이에 수소가 모였을 때 큰 폭발이 발생했으며 격납건물 벽면에 큰 응력을 동반하였다.

THE STUDY OF SCINTILLATION ON C-BAND LOW ELEVATION ANGLE AT SRI-RACHA SATELLITE EARTH STATION

  • Theerapatpaiboon, P.;Sukkaewthanom, S.;Leelaruji, N.;Hemmakorn, N.
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2004년도 ICCAS
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    • pp.20-23
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    • 2004
  • Tropospheric and ionospheric scintillation may impact on C-band satellite communication systems, particularly at lowmargin systems and low elevation angles. This paper presents the characteristics of C-Band scintillation at low elevation angle received and recorded the satellite signal from INTELSAT above the Pacific Ocean Region (POR) from January 2002 to December 2002 in the period of solar maximum. We received 3.9525 GHz beacon signal at Sri-Racha satellite earth station by the 32 meters in diameter antenna with 8 degrees of elevation. The analysis was found that the values of amplitude fluctuation is mostly about 0.5-0.6 dB peak to peak and $S_4$ = 0.03-0.04. The maximum amplitude fluctuation is about 9 dB peak to peak occurring in April. The occurrence numbers of scintillation is most frequently in April and minimum in November. The occurrence numbers of tropospheric scintillation are most frequently in April and October, and minimum in November. It relates to temperature and water vapor pressure variation in $N_{wet} $. The occurrence numbers of ionospheric scintillation are most frequently in April and September, and minimum in November. It varies corresponding to both equinoctial periods (vernal and autumnal equinox in March and September) and solstice periods (June and December) respectively.

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Brachydanio rerio와 Xiphophorus hellieri를 이용한 Dichlorvos, Methidathion 및 Phosalone의 단기간 생물농축계수의 측정 (Detemination of Short-term Bioconcentration Factor on Dichlorvos, Methidathion and Phosalone in Brachydanio rerio and Xiphophorus hellieri)

  • 민경진;전봉식;차춘근;김근배;조영주
    • 한국환경보건학회지
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    • 제24권3호
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    • pp.99-106
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    • 1998
  • This study was performed to investigate the bioconcentration of dichlorvos, methidathion and phosalone in zebrafish (brachydanio rerio), red sword tail(Xiphophorus hellieri). The fishes were exposed to 0.05 ppm, 0.01 ppm, 0.50 ppm, one-hundredth concentration of 96-hrs LC$_{50}$ and one-thousandth concentration of 96-hrs LC$_{50}$ and test periods were 3, 5 and 8 days. The deputation rate of each pesticide from the whole body of fish was determined over the 24-hr period after treatment. Obtained results are summerized as follows: In the case of dichlorvos, dichlorvos concentration in zebrafish extract and BCF$_{s}$ of dichlorvos were increased as increasing test concentration. In the case of same experimental concentrations, dichlorvos concentration in zebrafish extract and BCF$_{s}$ of dichlorvos were decreased as proloning test periods, especially dropped after 5days. Dichlorvos concentration in red sword tail extract were increased as increasing test concentration, lyat BCF$_{s}$ in concentration of 0.05 ppm, 0.01 ppm and one-hundredth of 96-hrs LC$_{50}$ were decreased. Methidathion and phosalone concentration in zebrafish extract in zebrafish extract were increased as increasing test concentration, but there was little difference in BCF$_{s}$. In the case of same experimental concentrations, there were little differences in BCF$_{s}$ and concentration in zebrafish extract. In the case of red sword tail, it was impossible to calculate on BCF$_{s}$ data because test concentration was under the detecting limit on GC or test fish were die. Determined deputation rate conatant were highest on dichlorvos, and followed by methidathion, and phosalone. The results of determining depuration rate of these pesticides showed that the high BCF in fish might be due to the slow depuration rate in fish, it is thought to be responsible for vapor pressure, water solubility and partition coefficient. It is suggested that one-hundredth concentration of 96-hrs LC$_{50}$ will be proper test concentration because one-thousundth of LC$_{50}$ was under the detecting limit on GC. Dichlorvos, methidathion and phosalone, organophosphorous pesticides, were examined to their BCF$_{s}$ and depuration rates by means of fish test.

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LNG 냉열을 이용한 냉장·냉동 창고 모사에 관한 연구 (A Study of Simulation on the Refrigerated Warehouse System Based on the Cold Energy of Lng Using the Pro-Ii Simulator)

  • 한단비;김윤지;염규인;신재린;백영순
    • 한국수소및신에너지학회논문집
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    • 제28권4호
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    • pp.401-406
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    • 2017
  • When Liquified Natural Gas (LNG) is vaporized into NG for industrial and household usage, tremendous cold energy was transferred from LNG to seawater during phase-changing process. This heat exchanger loop is not only a waste of huge cold energy, but will cause thermal pollution to the coastal fishery area also when cold water was re-injected into the sea. In this study, an innovation design has been performed to reclaim the cold energy for -35 to $62^{\circ}C$ refrigerated warehouse. Conventionally, this was done by installing mechanical refrigeration systems, necessitating tremendous electrical power to drive temperature. A closed loop LNG heat exchangers in series was designed to replace the mechanical or vapor-compression refrigeration cycle by process simulator. The process simulation software of PRO II with provision has been used to simulate this process for various conditions, what to effect on cold energy and used energy for re-liquefaction and evaporation process. In addition, through analysis the effect of the change of LNG supply pressure on sensible and latent heat, optimum operational conditions was suggested for LNG cold energy warehouse.

30kW급 LFG 가스터빈 발전용 연료화 정제시스템 개발 (Development of Fuel Conditioning System for 30 kW-class LFG Gasturbine Power Generation)

  • 허광범;박정극;임상규;이정빈
    • 신재생에너지
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    • 제6권1호
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    • pp.29-37
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    • 2010
  • Biogas is a carbon neutral energy and consists of mostly methane and carbon dioxide, with smaller amounts of water vapor, and trace amounts of $H_2S$, Siloxane and other impurities. Hydrogen sulfide and Siloxane usually must be removed before the gas can be used for generation of electricity or heat. The goals of this project are to develope the Fuel conditioning system of Land Fill Gas for 30kW-Micro Gas Turbine co-generation system. The fuel conditioning system mainly consists of $H_2S$ removal system, Land Fill Gas compressor, Siloxane removal system and many filtering systems. The fuel requirement of 30kW MGT is at least 32% of $CH_4$, $H_2S$ (<30 ppm), Siloxane (<5ppb) and supply pressure (> 0.6 MPa) from LFG compressor. Main mechnical charateristics of Micro Gas Turbine system by using LFG have the specific performance; 1) high speed turbine speed (96,000 rpm) 2) very clean emmission NOx (<9 ppm) 3) high efficiency of energy conversion rate. This paper focuses on the development of design technology for LFG fuel conditioning system. The study also has the plan to replace the fuel of gas turbine and other distributed power systems. As the increase of Land Fill Gas (LFG), this system help to contribute to spread more New & Renewable Energy and the establishment of Renewable Portfolio Standards (RPS) for Korea.

수도권에서 유출류 경계(Outflow Boundary)를 따라 발생한 집중호우 분석 (Analysis of An Outflow Boundary Induced Heavy Rainfall That Occurred in the Seoul Metropolitan Area)

  • 이지원;민기홍
    • 대기
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    • 제27권4호
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    • pp.455-466
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    • 2017
  • In Korea, property and human damages occur annually due to heavy precipitation during the summer. On August 8, 2015, heavy rainfall occurred in the Seoul metropolitan area due to an outflow boundary, and $77mmhr^{-1}$ rainfall was recorded in Gwangju, Gyeonggi Province. In this study, the simulation of the WRF numerical model is performed to understand the cause and characteristics of heavy rainfall using the Conditional Instability of the Second Kind (CISK), potential vorticity (PV), frontogenesis function, and convective available potential energy (CAPE) analyses, etc. Convective cells initiated over the Shandong Peninsula and located on the downwind side of an upper level trough. Large amounts of water vapor were supplied to the Shandong Peninsula along the southwestern edge of a high pressure system, and from the remnants of typhoon Soudelor. The mesoscale convective system (MCS) developed through CISK process and moved over to the Yellow Sea. The outflow boundary from the MCS progressed east and pushed cold pool eastward. The warm and humid air over the Korean Peninsula further enhanced convective development. As a result, a new MCS developed rapidly over land. Because of the latent heat release due to convection and precipitation, strong potential vorticity was generated in the lower atmosphere. The rapid development of MCS and the heavy rainfall occurred in an area where the CAPE value was greater than $1300Jkg^{-1}$ and the fronto-genesis function value of 1.5 or greater coincided. The analysis result shows that the MCS driven by an outflow boundary can be identified using CISK process.

기상자료의 결측과 산정에 따른 기준작물 증발산량 공식의 비교 평가 (Assessment of Reference Evapotranspiration Equations for Missing and Estimated Weather Data)

  • 윤푸른;최진용
    • 한국농공학회논문집
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    • 제60권3호
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    • pp.15-25
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    • 2018
  • Estimating the reference evapotranspiration is an important factor to consider in irrigation system design and agricultural water use. However, there is a limitation in using the FAO Penman-Monteith (FAO P-M) equation, which requires various meteorological data. The purpose of this study is to compare three reference evapotranspiration (ETo) equations in the case of meteorological data missing for 11 study weather stations. Firstly, the FAO P-M equation is used for reference potential evapotranspiration estimation with the actual solar radiation data $R_n$ and the actual vapor pressure $e_a$. Then, in the case of $R_n$, and $e_a$ are missed, the reference evapotranspirations applying FAO P-M, Priestley-Taylor (P-T), Hargreaves (HG) equation were calculated using other meteorological factors. Secondly, MAE, RMSE, $R^2$ were calculated to compare ETo relationship from the ETo equations. From the results, ETo with Hargreaves equation in coastal areas and the Priestley-Taylor equation in the inland areas showed relatively high correlation with FAO P-M when $e_a$ data is missed. In the case of $R_n$ data is missed or two weather data, $e_a$, and $R_n$ data are all missed, $R^2$ value in Priestley-Taylor equation was highest in coastal areas, and $R^2$ values in Hargreaves equation were the high values for 7 inland areas. The results of sensitivity analysis showed that net radiation was the most sensitive for P-T and HG equation, and for FAO P-M, the most sensitive factor was net radiation and relative humidity, air temperature and wind speed were follows. Therefore, in considering of the accessibility to the coast, the types of the missing wether data, and the correlation and the magnitude of error, the reference evapotranspiration equations would be selected in sense of different conditions.