• Advances in nano research
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• 제5권3호
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• pp.193-201
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• 2017

ZnO, ZnO: Cu, Ga, and ZnO: Cu, Ga, Ag thin films were obtained by oxidization of ZnS and ZnS: Cu, Ga films deposited onto glass substrates by electron-beam evaporation from ZnS and ZnS: Cu, Ga targets and from ZnS: Cu, Ga film additionally doped with Ag by the closed space sublimation technique at atmospheric pressure. The film thickness was about $1{\mu}m$. The oxidation was carried out at $600-650^{\circ}C$ in air or in an atmosphere containing water vapor. Structural characteristics were investigated by X-ray diffraction (XRD) and atomic force microscopy (AFM). Photoluminescence (PL) spectra of the films were measured at 30-300 K using the excitation wavelengths of 337, 405 and 457.9 nm. As-deposited ZnS and ZnS: Cu, Ga films had cubic structure. The oxidation of the doped films in air or in water vapors led to complete ZnO phase transition. XRD and AFM studies showed that the grain sizes of oxidized films at wet annealing were larger than of the films after dry annealing. As-deposited doped and undoped ZnS thin films did not emit PL. Shape and intensity of the PL emission depended on doping and oxidation conditions. Emission intensity of the films annealed in water vapors was higher than of the films annealed in the air. PL of ZnO: Cu, Ga films excited by 337 nm wavelength exhibits UV (380 nm) and green emission (500 nm). PL spectra at 300 and 30 K excited by 457.9 and 405 nm wavelengths consisted of two bands - the green band at 500 nm and the red band at 650 nm. Location and intensities ratio depended on the preparation conditions.

• Journal of Ecology and Environment
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• 제35권3호
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• pp.213-225
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• 2012

Sap flux density (SFD) measurements were used, in combination with morphological characteristics of trees and forest structure, to calculate whole-tree transpiration, stand transpiration (St) and mean canopy stomatal conductance (Gs). Analysis based on the relationships between the morphological characteristics of trees and whole tree water use, and on the responses of SFD and Gs to short wave radiation (RR), vapor pressure deficit (VPD) and soil water content (SWC) during drought and non-drought periods were conducted. The results showed a strong positive correlation between whole tree transpiration and both tree diameter at breast height (DBH) ($r^2$ = 0.95, P < 0.05) and sapwood area (SA) ($r^2$ = 0.98, P < 0.05). Relationships between SFD and DBH ($r^2$ = 0.25), as well as SA ($r^2$ = 0.17) were weak. Daily SFD of Quercus serrata Thunb was closely related to VPD and RR. Although operating at different time scales, RR and VPD were important interacting environmental controls of tree water use. SFD increased with increasing VPD (<1 kPa) and RR. SWC had a considerable effect on stand transpiration during the drought period. The relationships between SFD, VPD and RR were distorted when SWC dropped below 35%.

• 한국초전도ㆍ저온공학회논문지
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• 제6권3호
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• pp.27-32
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• 2004

High temperature superconducting coated conductor has a structure of /< superconducting layer>//. The buffer layer consists of multi layer, and the architecture most widely used in RABiTS approach is CeO$_2$(cap layer)/YSZ(diffusion barrier layer)/CeO$_2$(seed layer). Evaporation technique is used for the CeO$_2$ layer and DC reactive sputtering technique is used for the YSZ layer, A chamber was set up specially for DC reactive sputtering, Detailed features are as following. A separator divided the chamber into two halves a sputtering chamber and a reaction chamber. The argon gas for sputtering target elements flows out of the cap of sputtering gun, and water vapor for reaction with depositing species spouts near the substrate. Turbo pump is connected with reaction chamber. High speed deposition of YSZ film could be achieved in the chamber. Detailed deposition conditions (temperature and partial pressure of reaction gas) were investigated for the rapid growth of high quality YSZ film.

• 한국재료학회지
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• 제21권3호
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• pp.149-155
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• 2011

We investigated tribological characteristics of diamond-like carbon (DLC) in a condition with carbon nanotube (CNT) content of 1wt% in aqueous solution. Si-DLC films were deposited by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) process on Al6061 aluminum alloy. In this study, the deposition of DLC films was carried out in vacuum with a chamber pressure of 10-5 to 10-3 Torr achieved by mechanical pump followed by turbo molecular pump. The surface adsorbed oxygen on the Aluminum substrates was removed by passing Ar gas for 10 minutes. The RF power was maintained at 500W throughout the experiment. A buffer layer of HMDSO was deposited on the substrate to improve the adhesion of DLC coating. At this point CH4 gas was introduced in the chamber using gas flow controller and DLC coating was deposited on the buffer layer along with HMDSO for 50 min. The thickness of 1 ${\mu}m$ was obtained for DLC films on aluminum substrates The tribological properties of as synthesized DLC films were analyzed by wear test in the presence of dry air, water and lubricant such as CNT ink.

• 콘크리트학회논문집
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• 제11권5호
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• pp.69-77
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• 1999

A spalling is defined as the damages of concrete exposed to high temperature during the fire by causing cracks and localized bursting of small pieces of concrete. It is reported that spalling is caused by the vapor pressure and polypropylene(PP) fiber has an important role in protecting from spalling. This paper is a study on the properties and spalling resistance of high-performance concrete with the kinds of aggregate and the contents of PP fiber. According to the experimental results, concrete contained no PP fiber take place in the form of the surface spalling and the failure of specimenns after fire test regardless of the kinds of aggregate. Concrete contained more than 0.05% of PP fiber with the aggregate of basalt does not take place the spalling, while the concrete using granite and limestone does the surface spalling. It is found that residual compressive strength after exposed at high temperature has 50~60% of its original strength. Although specimens after exposed at high temperature is cured at water for 28days, they do not recover their original strength.

• 한국세라믹학회지
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• 제39권2호
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• pp.190-193
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• 2002

3Y-TZP에 희토류 산화물($CeO_2,\;Tb_2O_3$)을 0.5% 이하로 첨가시킨 지르코니아 단결정을 skull melting법으로 제조하여 오토클레이브 하에서 열수 상 안정성을 조사하였다. 극점도 측정결과, skull melting 법으로 제조한 $CeO_2$와 $Tb_2O_3$가 첨가된 시편들은 단결정이었으며 150∼250$^{\circ}C$에서 5시간 수증기 분위기 하에서 열처리한 후에도 정방정 상이 유지되는 우수한 열수 상 안정성이 관찰되었다.

• 한국환경과학회지
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• 제20권12호
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• pp.1599-1605
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• 2011

To evaluate heat environment surrounding plants diurnal change of leaf temperature in the broad-leaved deciduous and evergreen trees was measured with microclimatic environmental factors including global solar radiation, and upward and downward long wave radiation. Maximum daily solar radiation was 961.2 and 976.3 w/$m^2$ in August 9 and 23, respectively. Upward long wave radiation was slightly higher than downward long wave radiation, showing 404.2 w/$m^2$ in August 9 and 394.5 w/$m^2$ in August 23. In addition, daily maximum vapor pressure deficit was 5.42 and 6.84 kPa in August 9 and 23, respectively, indicating high evaporative demand. Quercus glauca and Acer mono was differently responded to changing light regimes. On August 9, leaf temperature at the top-positioned leaves of Acer plants was higher than air temperature as well as those of Quercus plants in the morning. This indicates that stomata in Acer plants were closed by heat stress or water stress in the morning, while Quercus plant maintained active transpiration by opening stomata. These results indicated that improved light regimes such as gap opening in the closed forest may not always affect positively in the physiology of understory plants.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2010년 춘계학술대회논문집
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• pp.320-325
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• 2010

A multiphase CFD analysis is performed to investigate the effect of near-wall grid for simulating a subcooled boiling flow in vertical tube. The multiphase flow model used in this CFD analysis is the two-fluid model in which liquid(water) and vapor(steam) are considered as continuous and dispersed fluids, respectively. A wall boiling model is also used to simulate the subcooled boiling heat transfer at the heated wall boundary. The diameter and heated length of tube are 0.0154 m and 2 m, respectively. The system pressure in tube is 4.5 MPa and the inlet subcooling is 60 K. The near-wall grid size in the non-dimensional wall unit ($y_{w}^{+}$) was examined from 64 to 172 at the outlet boundary. The CFD calculations predicted the void distributions as well as the liquid and wall temperatures in tube. The predicted axial variations of the void fraction and the wall temperature are compared with the measured ones. The CFD prediction of the wall temperature is shown to slightly depend on the near-wall grid size but the axial void prediction has somewhat large dependency. The CFD prediction was found to show a better agreement with the measured one for the large near-wall grid, e.g., $y_{w}^{+}$ > 100.

• 대한기계학회논문집A
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• 제37권9호
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• pp.1151-1158
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• 2013

습기 수착 물성은 전자 패키징 장치의 신뢰성에 있어서 층간의 수증기 압력에 의해 공정과정 동안 발생되는 박리 불량의 고장 분석 및 최적의 재료 개발에 있어서 필수적이다. 본 논문에서는 온습도 모델에 따른 전자 패키징 재료의 온도 의존적인 흡습 및 탈습 물성을 변수화 하였고 이에 대한 온도 및 습도의 영향에 대해 고찰하였다. 변수화된 확산성에서 얻어진 확산 활성화 에너지는 등가의 습기 수착 수준을 위한 가속 수명 비율을 결정하고 신뢰 수명 평가에 요구되는 등가의 소요 시험 시간에 미치는 습기 확산성의 영향을 예측할 수 있게 한다. 신뢰성 시험 표준에서 평가된 유연 전자 모듈의 가속 수명비율을 예시하였다.

• 한국대기환경학회지
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• 제24권5호
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• pp.604-612
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• 2008

The ozone concentration is one of the important environmental issue for measurement of the atmospheric condition of the country. This study focuses on applying the Autoregressive Error (ARE) model for analyzing the ozone data at middle part of the Gyeonggi-Do, Anyang monitoring site in Korea. In the ARE model, eight meteorological variables and four pollution variables are used as the explanatory variables. The eight meteorological variables are daily maximum temperature, wind speed, amount of cloud, global radiation, relative humidity, rainfall, dew point temperature, and water vapor pressure. The four air pollution variables are sulfur dioxide $(SO_2)$, nitrogen dioxide $(NO_2)$, carbon monoxide (CO), and particulate matter 10 (PM10). The result shows that ARE models both overall and monthly data are suited for describing the oBone concentration. In the ARE model for overall ozone data, ozone concentration can be explained about 71% to by the PM10, global radiation and wind speed. Also the four types of ARE models for high level of ozone data (over 80 ppb) have been analyzed. In the best ARE model for high level of ozone data, ozone can be explained about 96% by the PM10, daliy maximum temperature, and cloud amount.