• Title/Summary/Keyword: Water Vapor Pressure

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Scalants removal from synthetic RO brine using natural zeolite (막증류 공정의 전처리 공정으로서 천연 제올라이트 컬럼 적용)

  • Jeong, Seongpil;Chung, Hayoon;Yoon, Teakgeun;Lee, Seockheon
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.279-284
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    • 2016
  • Membrane distillation (MD) is the thermally driven water separation process based on the vapor pressure difference across the membrane. In order to increase the water recovery of the conventional RO process, the additional MD-PRO pocess was suggested. In this study, the syntheric RO brine was used as a feed solution of the MD process. Due to the high salinity of the RO brine, the MD membrane could be fouled by the scalants. In order to mitigate the scaling on the MD membrane surface, the pre-treatment process using the column filled by natural zeolite was applied. The roughing filter was installed between the pre-treatment process and MD system in order to prevent possible particulate fouling by the debries of the natural zeolite. Moreover, in order to enhance the CEC of the natural zeolite, the NaCl soaking was conducted. The flux and electronic conductivity were monitored under given experimental conditions. And the membrane morphology and the chemical compositions were analyzed by using the SEM-EDX.

The Effect of Water Stress on Carbon Dioxide Treatment during Protected of Tomato (Solanum lycopersicum) Cultivation at Summer (여름철 시설 토마토 재배 시 Carbon Dioxide 처리가 Water Stress에 미치는 영향)

  • Woo, Young-Hoe;Lee, Kwan-Ho;Kang, In-Chul;Kim, Dong-Eok
    • Journal of Practical Agriculture & Fisheries Research
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    • v.17 no.1
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    • pp.93-100
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    • 2015
  • This study was performed to examine the high temperature adaptability with CO2 treatment for tomato under the condition of greenhouse cultivation during summer season. The indoor condition of CO2 concentrations were controlled as control, 500 ppm, and 1,000 ppm for the greenhouse with the maximum air temperature of 44℃. With the observation of VPD (vapor pressure deficit) and CWSI (crop water stress index) by leaf-air temperature difference according to CO2 treatment concentration, the plants with the CO2 concentration of 1,000 ppm performed less water stress than those with the CO2 concentrations of control and 500 ppm. The plants without CO2 treatment performed the severest degree of water stress.

Study on the Chemical Management - 1. Chemical Characteristics and Occupational Exposure Limits under Occupational Safety and Health Act of Korea (화학물질 관리 연구-1. 산업안전보건법상 관리 화학물질의 특성과 노출기준 비교)

  • Park, Jihoon;Ham, Seunghon;Kim, Sunju;Lee, Kwonseob;Ha, Kwonchul;Park, Donguk;Yoon, Chungsik
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.45-57
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    • 2015
  • Objectives: This study aims to compare the physicochemical characteristics, toxicological data with Occupational Exposure Limits (OELs) of chemicals under the Occupational Safety and Health Act(OSHA) regulated by the Ministry of Employment and Labor of Korea. Methods: Information on chemicals which have OELs on physicochemical characteristics and toxicological data was collected using Material Safety Data Sheet(MSDS) from Korea Occupational Safety and Health Agency(KOSHA) and the Korea Information System for Chemical Safety Management(KISChem) in 2014. Statistical analyses including correlation and simple regression were performed to compare the OELs with chemical characteristics including molecular weight, boiling point, odor threshold, vapor pressure, vapor density, solubility and octanol-water partition coefficient(OWPC) and toxicological data such as median lethal dose($LD_{50}$) and median lethal concentration($LC_{50}$). Results: A total of 656 chemicals have OELs under OSHA in Korea. The numbers of chemicals which have eight-hour time weighted average(TWA) and short term exposure limits(STEL) are 618 and 190, respectively. TWA was significantly correlated with boiling point and STEL was only correlated with vapor pressure among physicochemical characteristics. Solubility and OWPC between "skin" and "no skin" substances which indicate skin penetration were not significantly different. Both $LD_{50}$ and $LC_{50}$ were correlated with TWA, while the $LC_{50}$ was not with STEL. As health indicators, health rating and Emergency Response Planning Guidelines(ERPG) rating as recommended by the National Fire Protection Association(NFPA) and American Industrial Hygiene Association(AIHA) were associated with OELs and reflect the chemical hazards. Conclusions: We found relationships between OEL and chemical information including physicochemical characteristics and toxicological data. The study has an important meaning for understanding present regulatory OELs.

Effect of Polyethylene Glycol Molecular Weight and NCO Index on Properties of the Hydrophilic Reactive Hotmelt Polyurethane Adhesives (Polyethylene Glycol의 분자량 및 NCO index의 변화에 따른 Hydrophilic Reactive Hotmelt Polyurethane의 물성 변화)

  • Han, Young Chul;Kim, Dack Han;Oh, Kyung Seok;Shin, Hyeon Jeong;Yang, Jeong Han;Jeong, Han Mo
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.90-97
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    • 2018
  • Hydrophilic reactive hot-melt polyurethane adhesive(HRHA) using a hydrophilic polyol having different molecular weight and NCO index was synthesized. This HRHA was synthesized using Polyethylene glycol(PEG) as a hydrophilic polyol, Polypropylene glycol(PPG) and Polycaprolactone diol(PCL) as hydrophobic polyols, and Methylene diphenyl diisocyanate(MDI) as an isocyanate. The changes in IR spectrum, viscosity and thermal properties of HRHA with different PEG molecular weights and NCO index were investigated, and the tensile strength and elongation of the HRHA casting film and the peel strength, moisture permeability and water pressure of the HRHA coated fabric were confirmed. In this experiment, as the molecular weight of PEG and NCO index increased, the adhesive strength, tensile strength, elongation and moisture permeability was increased but viscosity and Tg was decreased.

Prediction of Environmental Fate of Certain Chemicals Using Computer Simulation Programs (Computer Program을 이용한 화학물질의 환경동태 예측)

  • Kim, Kyun;Kim, Yong-Hwa
    • Korean Journal of Environmental Agriculture
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    • v.12 no.1
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    • pp.69-80
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    • 1993
  • Environmental hazards of a chemical could be assessed by two different approaches : toxicity test and assessment of exposure potentials to human and environmental organisms. For the prediction of environmental fate of chemicals three available computer programs were compared each other and were verified. The results obtained by using these computer programs, PCHEM, EXAMS, and E4CHEM were summarized as follows. The estimated octanol/water partition coefficients by PCHEM were similar to the experimental values in the literature. But the other factors, water solubility and vapor pressure were different from the data in the literature. The simulation results of selected compounds by EXAMS showed similar tendency to the literature results of model field environment. Therefore, this computer program could be utilized to predict the environmental fate of chemicals. E4CHEM program is very simple and this program could predict the ultimate environmental fate of stable chemicals by input of two or three parameters. However, the validity should further be verified in the future field study using more compounds. It is suggested that these approaches could be fully utilized by understanding their limitations to predict the environmental fate of new chemicals under development, to screen the potential environmental pollutants among chemicals already-in use, and to devise measures to minimize the hazards to the environment.

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Heat Dissipation of Sealed LED Light Fixtures Using Pulsating Heat Pipe Technology

  • Kim, Hyung-Tak;Park, Hae-Kyun;Bang, Kwang-Hyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.1
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    • pp.64-71
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    • 2012
  • An efficient cooling system is an essential part of the electronic packaging such as a high-luminance LED lighting. A special technology, Pulsating Heat Pipe (PHP), can be applied to improve cooling of a sealed, explosion-proof LED light fixture. In this paper, the characteristics of the pulsating heat pipes in the imposed thermal boundary conditions of LED lightings were experimentally investigated and a PHP device that works free of alignment angle was investigated for cooling of explosion-proof LED lights. Five working fluids of ethanol, FC-72, R-123, water, and acetone were chosen for comparison. The experimental pulsating heat pipe was made of copper tubes of internal diameter of 2.1 mm, 26 turns. A variable heat source of electric heater and an array of cooling fins were attached to the pulsating heat pipe. For the alignment of the heating part at bottom, an optimum charging ratio (liquid fluid volume to total volume) was about 50% for most of the fluids and water showed the highest heat transfer performance. For the alignment of the heating part on top, however, only R-123 worked in an un-looped construction. This unique advantage of R-123 is attributed to its high vapor pressure gradient. Applying these findings, a cooling device for an explosion-proof type of LED light rated 30 W was constructed and tested successfully.

Countermeasure and Spalling Property of High Performance Concrete (고성능 콘크리트의 폭렬특성 및 대책)

  • Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1105-1108
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    • 2008
  • This paper investigated measures of spalling prevention and mechanism to secure stability of subjected to a fire circumstance. The results were summarized as following. 1) There were 4 kinds of methods for spalling prevention, such as declining percentage of water content and cement water ratio, isolating from high temperature with fire proof covering, giving lateral resistance stress, and discharging vapor pressure using fibers. 2) It was confirmed that methods using fibers to a new construction and fire proof covering to a existing construction on the basis of investigation for the spalling mechanism through the existing theory of spalling and a new theory of WPB.

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Operational Characteristics of Pulsating Heat Pipes for the Application to the Heat Dissipation of LED Lighting (LED 조명 방열 환경에서 진동형 히트파이프의 작동 특성)

  • Bang, Kwang-Hyun;Kim, Hyoung-Tak;Park, Hae-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.10
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    • pp.830-836
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    • 2012
  • An efficient cooling system is essential for the electronic packaging such as a high-luminance LED lighting. A special heat transport technology, Pulsating Heat Pipe (PHP), can be applied to the cooling of LED lighting. In this paper, the operational characteristics of the PHP in the imposed thermal boundary conditions of LED lighting were experimentally investigated. The experimental PHP was made of copper tubes of internal diameter of 2.1 mm. The working fluids of ethanol, FC-72, water, acetone and R-123 were chosen for comparison. The results showed that an optimum range of charging ratio exists for high cooling performance; 50% for most of the fluids. Among the five working fluids, water showed the highest heat transfer rate of 260 W. Two distinguished characteristics of pulsating direction were identified. It is also identified that high vapor pressure gradient is one of key parameters for better heat transfer performance.

The Effect of Compliance Structures Near the Mechanical Heart Valve on Valve Surface Erosion (기계식 인공 판막 주위의 유연성 구조가 표면 괴식에 미치는 영향)

  • Lee, Hwan-Sung;Hwang, Sung-Won;Sun, Kyung
    • Journal of Biomedical Engineering Research
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    • v.23 no.4
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    • pp.309-315
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    • 2002
  • Since the discovery, in the 1980s, of erosion-pit-induced fractures in implanted mechanical heart valves. cavitation on the surface of mechanical heart valves has been widely studied as a possible cause of pitting. Several factors, including peak dp/dt of the ventricular pressure. maximum closing velocity of the leaflet, and squeeze flow. have been studied as indices of the cavitation threshold. In the present study. cavitation erosion on the surface of a mechanical valve was examined by focusing on squeeze flow and the water hammer phenomenon during the closing period of the valve. In this study, we measures pressure wave forms near a valve and closing velocities of a disk, which were placed in a holder with and without compliance. In case of all holders, pressure drop of below vapor pressure expect at near the surface disk. It was also found that the closing velocity of the disk increased and that cavitation erosion was enhanced too. These results suggest that disk closing velocity during the closing phase has signifiant effects on pitting erosion.

Review of Spatting Effect on Concrete Element in Fire (화재시 콘크리트 요소 폭렬영향성 고찰)

  • Kim, Hyung-Jun;Han, Sang-Hoon;Choi, Seng-Kwan
    • Fire Science and Engineering
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    • v.21 no.2 s.66
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    • pp.54-63
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    • 2007
  • Concrete is generally accepted to have good inherent fire resistance. It mainly relies on the assumption that concrete has low heat-transfer characteristic and spatting does not occur during the course of a fire. However, the significant numbers of fire accidents have shown in recent years that incidence of spatting has caused sever damages to many structures. This review has systematically investigated the behaviour of concrete in fire, including phenomenon of spatting, with respect to the theorical consideration and experimental results. Explosive spatting is caused by the build-up of water vapor pressure in concrete subjected to increasing temperatures. When this pressure exceeds the tensile strength of the concrete over a fire-exposed area, explosive spatting can result in a typical temperature range between $200^{\circ}C\;and\;400^{\circ}C$. The major functions are known to be moisture content, pore pressure, load ratio, and heating regime.