• Macromolecular Research
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• v.12 no.1
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• pp.127-133
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• 2004

We have studied the surface micelle formation of polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) at the air-water interface. A series of four PS-b-P2VPs were synthesized by anionic polymerization, keeping the PS block length constant (28 kg/㏖) and varying the P2VP block length (1, 11, 28, or 59 kg/㏖). The surface pressure-area ($\pi$-A) isotherms were measured and the surface morphology was studied by atomic force microscopy (AFM) after Langmuir-Blodgett film deposition onto silicon wafers. At low surface pressure, the hydrophobic PS blocks aggregate to form pancake-like micelle cores and the hydrophilic P2VP block chains spread on the water surface to form a corona-like monolayer. The surface area occupied by a block copolymer is proportional to the molecular weight of the P2VP block and identical to the surface area occupied by a homo-P2VP. It indicates that the entire surface is covered by the P2VP monolayer and the PS micelle cores lie on the P2VP monolayer. As the surface pressure is increased, the $\pi$-A isotherm shows a transition region where the surface pressure does not change much with the film compression. In this transition region, which displays high compressibility, the P2VP blocks restructure from the monolayer and spread at the air-water interface. After the transition, the Langmuir film becomes much less compressible. In this high-surface-pressure regime, the PS cores cover practically the entire surface area, as observed by AFM and the limiting area of the film. All the diblock copolymers formed circular micelles, except for the block copolymer having a very short P2VP block (1 kg/㏖), which formed large, non-uniform PS aggregates. By mixing with the block copolymer having a longer P2VP block (11 kg/㏖), we observed rod-shaped micelles, which indicates that the morphology of the surfaces micelles can be controlled by adjusting the average composition of block copolymers.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.19-32
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• 2002

This study is objected to identify the relations between surface- and shallow ground-water and the seasonal variation of their qualities in watersheds near Muju area. The water type shows mainly Ca-$HCO_3$type. Heavy-metal contamination of surface water is locally detected, due to the mixing with mine drainage. In October nitrate concentration is especially high in densely populated area. Cluster Analysis and Principal Component Analysis are implemented to interpret the complexity of the chemical variation of surface- and ground-water with large amount of chemical data. Based on the cluster analysis, surface-water was divided into five groups and ground-water into three groups. Principal Component Analysis efficiently supports the result of cluster analysis, allowing the identification of three main factors controlling the water quality. There are (1) hydrogeochemical factor, (2) anthropogenic factor and (3) heavy metal contaminated by mine drainage.

• Solar Energy
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• v.8 no.1
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• pp.49-56
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• 1988

Thermally treated Korean ilmenite was characterized and used for water splitting to obtain hydrogen by photo-catalytic reaction. Experiments on specific surface area, X-ray diffraction and EDS showed that the formation of FeO, $Fe_2O_3$ and $TiO_2$ ilmenite crystal surface increased the specific surface area with maximum value, phase change of $TiO_2$ at $600^{\circ}C$ and hetrogeneity. The hydrogen evolved in caustic soda solution on these ilmenites indicated that there was a maximum yield point at about $600^{\circ}C$. This point was explained with the change of the surface area due to sintering of newly formed FeO, $Fe_2O_3$ and $TiO_2$, as well as crystal phase change of anatase to rutile at $600^{\circ}C$. Produced hydrogen increased also as the concentration of caustic soda, but become constant at the near 1N solution.

• Journal of Korea Water Resources Association
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• v.55 no.11
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• pp.913-922
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• 2022

The purpose of this research is to propose the measurement of improving DEM by using the water surface range of SAR image analysis for river corridors and to suggest the construction of satellite-based 3D river spatial information of inaccessible regions such as North Korea. For this research, it has been progressed from the accessible area, watershed of Namgang river, the branch of Nakdonggang river. The satellite image was collected from SAR satellite image data for a year in 2021 which was provided by ESA from Sentinel-1A/B data and extracted from the seasonal water surface area. Ground gauge water level was collected from hourly intervals data by WAMIS. The DEM was improved by analysis of the river altitude of water surface area change by the combination of the ground water level of minimum to maximum water surface area data extracted from SAR image analysis. After the improvement of DEM, the altitude of the river varied that it is defined to comprise more natural form of river DEM than the existing DEM. The correction validation of improvement DEM was necessary in field survey elevation data; however, the correction validation was not progressed due to the absence of the data. Although, the purpose of this research is to provide the improvement of DEM by using the analyzed water surface by existing DEM data and SAR image analysis. After the progression of additional correction validation research, we would plan to examine the application in other places and to progress the additional methodological research to apply in inaccessible and unmeasured area including the North Korea.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.369-372
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• 2004

This study presents the hydrogeochmical investigation to know the effect of geology and sources for water quality in small potable water supply system at rural area. The results of water quality in Geumsan area showed the 3.2% of water samples exceeded the limit of drinking water standard by bacteria. The hydrochemical investigation results indicated the high EC, Ca and HCO$_3$ in surface water and metasedimentary rocks and this is caused by the dissolution of calc-slicate minerals of metasedimentary rocks.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.4
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• pp.591-596
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• 2011

Surface floating air cathode microbial fuel cell (MFC) having horizontal flow was developed for the application of MFC technology. RVC (Reticulated vitreous carbon) coated with anyline was used as anode electrode and carbon cloth coated with Pt (5.0 g Pt/$m^2$, GDE LT250EW, E-TEK) was used as cathode electrode. As results of continuous operation with changing the flow rate from 4.3 mL/min to 9.5 mL/min, maximum power density of 4.5 W/$m^3$ was acquired at 5.4 mL/min, which was at 0.35 m/hr of flow velocity under anode electrode. When the ratio of cathode surface area to anode surface area($A_c/A_a$) was changed to 1.0, 0.5, and 0.25, the maximum power density of 2.7 W/$m^3$ was shown at the ratio of 1.0. As the ratio decreased from 1.0 to 0.25, the power density also decreased, which is caused by increasing the internal resistance resulted from reducing the surface area to contact with oxygen. Actually, internal resistances of the ratio of 1.0, 0.5, and 0.25 were 63.75${\Omega}$, 142.18${\Omega}$, and 206.12${\Omega}$, respectively.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.451-454
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• 2003

Nonpoint source pollution of groundwater and subsurface water from irrigated agriculture is a major concern in many areas. In this study we aimed to investigate the effect of the water applied by irrigation in agricultural area on the transport of nitrogen and phosphorus originated from fertilizers applied to the surface of soil in agricultural activities. We first conducted investigation on the resdual concentrations of soil N and P in a selected agricultural area. And simulating the target area by column studies in the laboratory leaching extent of various components from the composite and urea fertilizers applied on the soil surface during irrigation was studied. Infiltration of water enhanced the leaching of nitrogen and phosphorus in both the rice paddy field soil and the patch soil. The downward N and P transport with infiltrating water was more pronounced in the patch soil column and the increased residual concentrations of N and P in the lower sections in the patch soil column was found with time.

• KIEAE Journal
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• v.15 no.1
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• pp.117-127
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• 2015

The cool surface ratio could be used as a proxy of the overall thermal environment contributing to heat islands in urban area. This research proposes a comparative evaluation framework in an objective and quantitative way for measuring cool surface ratios. Two university campuses (Kyungpook National University: KNU, South Korea and UC Davis: University of California, Davis, USA) were selected as case study sites in order to monitor cool surface condition. Google Earth combined with digital maps realistically identified the major type of cool surfaces such as cool roofs and water bodies in the study area. Cool surfaces were sparsely identified over the KNU campus while the UC Davis campus was heavily covered by cool surfaces such as cool roofs and water bodies, resulting in almost four times more first-grade cool surfaces, as compared to KNU. It is confirmed that standard remote sensing technology can offer the viable method of measuring and comparing the campus-wide cool surface condition. It is anticipated that this research output could be used as a valuable reference to initiate a nation-wide cool surface strategy since objective evidence has been provided based on area-wide measurement for the cool surface in the two university context.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.349-357
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• 2006

Nowadays, the discharges of urban streams during dry season are depleted because the hydrologic cycle in the watershed has been destroyed due to the expansion of the impermeable area, the excessive groundwater pumping, climate change, and so forth. The streamflow depletion may bring out severe water quality problems. This research are to investigate the hydrologic characteristics and to develop a technology to restore sound hydrologic cycle of Anyangcheon watershed. For the hydrological cycle analysis of the Anyangcheon watershed, continuous simulations of urban runoff were performed for the upstream basin of Gocheok bridge whose basin area covered 4/5 of the whole catchment area. The increase of impervious area by urbanization was analysed and its effect on urban runoff was evaluated. The SWMM 5 (Storm Water Management Model 5) was used for the continuous simulation of urban runoff. The analysis results of urbanization effect on runoff are as follows: the surface runoff in 2000 increases to 65% of the whole precipitation whereas the surface runoff in 1975 amounts to 50% of the precipitation; the groundwater runoff in 2000 amounts to 7% and shows 6% decrease during the period from 1975 to 2000.

• Journal of The Korean Society of Agricultural Engineers
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• v.62 no.6
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• pp.1-9
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• 2020

Reservoir storage and water level information is essential for accurate drought monitoring and prediction. In particular, the agricultural drought has increased the risk of agricultural water shortages due to regional bias in reservoirs and water supply facilities, which are major water supply facilities for agricultural water. Therefore, it is important to evaluate the available water capacity of the reservoir, and it is necessary to determine the water surface area and water capacity. Remote sensing provides images of temporal water storage and level variations, and a combination of both measurement techniques can indicate a change in water volume. In areas of ungauged water volume, satellite remote sensing image acts as a powerful tool to measure changes in surface water level. The purpose of this study is to estimate of reservoir storage and level variations using satellite remote sensing image combined with hydrological statistical data and the Normalized Difference Water Index (NDWI). Water surface areas were estimated using the Sentinel-2 satellite images in Seosan, Chungcheongnam-do from 2016 to 2018. The remote sensing-based reservoir storage estimation algorithm from this study is general and transferable to applications for lakes and reservoirs. The data set can be used for improving the representation of water resources management for incorporating lakes into weather forecasting models and climate models, and hydrologic processes.