• Toxicological Research
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• v.31 no.3
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• pp.255-264
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• 2015

Heterocyclic amines (HCAs) and acrylamide are unintended hazardous substances generated by heating or processing of foods and are known as carcinogenic and mutagenic agents by the animal experiments. A simple method was established for a rapid and accurate determination of 12 types of HCAs (IQ, MeIQ, Glu-P-1, Glu-P-2, MeIQx, Trp-P-1, Trp-P-2, PhIP, $A{\alpha}C$, $MeA{\alpha}C$, Harman and Norharman) and acrylamide in three food matrices (non-fat liquid, non-fat solid and fat solid) by isotope dilution liquid chromatography-tandem mass spectrometry (LC-MS/MS). In every sample, a mixture of internal standards including $IQ-d_3$, $MeIQx-d_3$, $PhIP-d_3$, $Trp-P-2-^{13}C_2-^{15}N$ and $MeA{\alpha}C-d_3$ was spiked for quantification of HCAs and $^{13}C_3$-acrylamide was also spiked for the analysis of acrylamide. HCAs and acrylamide in sample were extracted with acetonitrile and water, respectively, and then two solid-phase extraction cartridges, ChemElut: HLB for HCAs and Accucat: HLB for acrylamide, were used for efficiently removing interferences such as pigment, lipid, polar, nonpolar and ionic compounds. Established method was validated in terms of recovery, accuracy, precision, limit of detection, limit of quantitation, and linearity. This method showed good precision (RSD < 20%), accuracy (71.8~119.1%) and recovery (66.0~118.9%). The detection limits were < 3.1 ng/g for all analytes. The correlation coefficients for all the HCAs and acrylamide were > 0.995, showing excellent linearity. These methods for the detection of HCAs and acrylamide by LC-MS/MS were applied to real samples and were successfully used for quantitative monitoring in the total diet study and this can be applied to risk assessment in various food matrices.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.2
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• pp.153-159
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• 2016

Gwangyang traffic safety designated area is composed of 3 fairways (Deep water fairway, inbound fairway, and outbound fairway). However, inbound vessels can't use this passage because of Samyeo rock and artificial fishing banks in inbound route. The problem with the rocks and artificial fishing banks has been raised by ship navigators and authorities of the port. This research is about the safety evaluation and management plan of the passage, and we conducted maritime traffic simulation using a model based on a ship operator risks. As a result, assuming that future marine traffic volume is the same as the present, and if the ship operators use 3 fairways and not two, it showed risk reduction of 46.4 % (vessels over 50,000 DWT using DW route) and 57.1 % (vessels over 10,000 DWT using DW route). Also, in a traffic volume condition which is the same as the present, to induce vessels over 50,000 DWT to use DW route is effective in mitigating of risks. Meanwhile, in a condition which increased the traffic volume by 150 %, it is more effective to induce vessels to use DW route. This research is the result of analysis using the model based on ship operator risks, and not cost-effectiveness analysis on the removal of Samyeo rock and artifical fishing banks. This research is expected to be used on setting up the sea route and management plan (particularly, restriction on passing DW route).

• Journal of Microbiology and Biotechnology
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• v.26 no.4
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• pp.763-774
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• 2016

Equine gastric ulcer syndrome is one of the most frequently reported diseases in thoroughbred racehorses. Although several risk factors for the development of gastric ulcers have been widely studied, investigation of microbiological factors has been limited. In this study, the presence of Helicobacter spp. and the gastric microbial communities of thoroughbred racehorses having mild to severe gastric ulcers were investigated. Although Helicobacter spp. were not detected using culture and PCR techniques from 52 gastric biopsies and 52 fecal samples, the genomic sequences of H. pylori and H. ganmani were detected using nextgeneration sequencing techniques from 2 out of 10 representative gastric samples. The gastric microbiota of horses was mainly composed of Firmicutes (50.0%), Proteobacteria (18.7%), Bacteroidetes (14.4%), and Actinobacteria (9.7%), but the proportion of each phylum varied among samples. There was no major difference in microbial composition among samples having mild to severe gastric ulcers. Using phylogenetic analysis, three distinct clusters were observed, and one cluster differed from the other two clusters in the frequency of feeding, amount of water consumption, and type of bedding. To the best of our knowledge, this is the first study to investigate the gastric microbiota of thoroughbred racehorses having gastric ulcer and to evaluate the microbial diversity in relation to the severity of gastric ulcer and management factors. This study is important for further exploration of the gastric microbiota in racehorses and is ultimately applicable to improving animal and human health.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.9
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• pp.521-527
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• 2016

Nanoscale zero valent iron (nZVI) has been intensively studied for the treatment of a plethora of pollutants through reductive reaction, however, the nano size should be of concern when nZVI is considered for water treatment, due to difficulties in recovery. The loss of nZVI causes not only economical loss, but also potential risk to human health and environment. Thus, the immobilization onto coarse or structured support is essential. In this study, two representative processes for nZVI immobilization on granular activated carbon (GAC) were evaluated, and optimized conditions for synthesizing Fe/GAC composite were suggested. Both total iron content and $Fe_0$ content can be significantly affected by preparation processes, therefore, it was important to avoid oxidation during preparation to achieve higher reduction capacity. Synthesis conditions such as reduction time and existence of intermediate drying step were investigated to improve $Fe_0$ content of Fe/GAC composites. The optimal condition was two hours of $NaBH_4$ reduction without intermediate drying process. The prepared Fe/GAC composite showed synergistic effect of the adsorption capability of the GAC and the degradation capability of the nZVI, which make this composite a very effective material for environmental remediation.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.9
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• pp.528-533
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• 2016

One of ways for effectively maintaining asbestos buildings is to select asbestos buildings to be removed firstly by manufacturing and analyzing asbestos map of various topics. Thus, in this study we manufactured asbestos map of various topics for the effective management of asbestos buildings owned by Seoul using QGIS (Quantum Geographic Information System). To select asbestos buildings likely to cause asbestos scattering problem and exposure into the air, we comprehensively took into consideration various topics such as asbestos buildings density, asbestos-area ratio, asbestos buildings distribution considering the population, first removal object, risk assessment, elapsed year. As described in this study, using the GIS may be utilized as a method for selecting asbestos buildings to be removed firstly as well as distribution of asbestos buildings. In the future, it is necessary to make assessment criteria considering diversification of property value in GIS such as the characteristics of the living environment around the asbestos buildings. This is expected to be utilized to manage the vulnerable region to asbestos exposure.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.293-301
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• 2005

We conducted several different leaching experiments for assessing the potential environmental risk when utilizing recycled concrete for stabilizing bridge pier. The methods include continuous batch leaching test (DIN 38414-S4), availability test (NEN 7341), pH-stat test (CEN/TC 292/WG6) and tank diffusion test (NEN 7345). The concentration ranges vary depending on the testing method. Nearly all the trace elements were low, some elements recording under detection limit. The maximum concentrations for trace elements leached throughout the whole tests are (as mg/L); Cd (0.029), Cu (0.437), Pb (0.14), Ni, Zn (0.95), Hg (0.005). Although the testing methods we used in this study are much more rigorous than other commonly adapted method including TCLP and domestic testing method for solid waste, the trace elemental concentrations are under the criteria for hazardous material set by the TCLP and domestic method. The result seems to suggest that applying the recycled concrete on stream water will be accepatable practice as for as trace elements are concerned. However, the influence of inorganics such as Ca, Mg, Ni and $SO_4^{2-}$ on aquatic ecology should be further examined.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.3
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• pp.173-183
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• 2006

Purpose of this study was to estimate of soil erosion, which is related with crop productivity and water quality in watershed, in Seonakdong river watershed using USLE. The data set for USLE estimation were derived from detailed digital map(K factor), satellite imagery(C and P factors) and DEM(LS factor). The R factor was calculated by AWS data from Kimhae agricultural technology center. The soil loss from arable land was equivalent of 31.5% of total soil loss in Seonakdong river watershed. The soil loss amount of paddy field and upland were 2.8% and 97.2% of arable land, respectively, even in the area where paddy field was occupied much largely as 76.3%. The reason of large amount of soil loss from upland was that 30.4% of upland was distributed at "severe" and "very severe" soil erosion grade in watershed. The distribution of soil erosion grade during cropping season(May-Sept.) was similar to the annual soil loss. Soil erosion of non-cropping season(Oct.-Apr.) was small due to a low R factor. But, soil erosion grade of near mountain footslope areas showed severe and very severe even in non-cropping season.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.6
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• pp.155-163
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• 2010

The past researches on flood inundation simulation mainly focused on development of numerical models based on unstructured mesh networks to improve model performances. However, despite the accurate simulation results, such models are not suitable for real-time flood inundation forecasting due to a huge computational burden in terms of geographic data processing. In addition, even though various types of vector and raster data are available to be compatible with flood inundation models for post-processes such as flood hazard mapping and flood inundation risk analysis, the unstructured mesh-based models are not effective to fully use such information due to data incommensurability. Therefore, this study aims to develop a raster-based two-dimensional inundation model; it guarantees computational efficiency because of direct application of DEM for flood inundation modeling and also has a good compatibility with various types of raster data, compared to a commercial model such as FLUMEN. We applied the model to simulate the BaekSan levee break in the Nam river during a flood period from August 10 to 13, 2002. The simulation results showed a good agreement with the field-surveyed inundation area and were also very similar with results from the FLUMEN. Moreover, the model provided physically-acceptable velocity vectors with respect to inundating and returning flows due to the difference of water level between channel and lowland.

• Journal of the Korean Association of Geographic Information Studies
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• v.22 no.4
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• pp.181-196
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• 2019

Floods can be caused by a variety of factors, and the main cause of floods is the exceeding of urban drainage system or river capacity. In addition, rainfall frequently occurs that causes large watershed runoff. Since the existing methodology of preparing for flood risk map is based on hydraulic and hydrological modeling, it is difficult to analyse for a large area because it takes a long time due to the extensive data collection and complex analysis process. In order to overcome this problem, this study proposes a methodology of mapping for flood vulnerable area that considered the surface runoff mechanism. This makes it possible to reduce the time and effort required to estimate flood vulnerabilities and enable detailed analysis of large areas. The target area is Seoul, and it was confirmed that flood damage is likely to occur near selected vulnerable areas by verifying using 2×2 confusion matrix and ROC curve. By selecting and prioritizing flood vulnerable areas through the surface runoff mechanism proposed in this study, the establishment of systematic disaster prevention measures and efficient budget allocation will be possible.

• Journal of Environmental Policy
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• v.14 no.4
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• pp.45-61
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• 2015

The river environment in Korea has changed significantly after the completion of the Four Major Rivers Project due to the outdated river management methods and thus, it is necessary to modify the current river management process. A typical example of this management is dredging but it is a method that usually results in socio-environmental side effects. Therefore, in order to minimize the socio-environmental impacts of dredging, Korea is currently applying the Environmental Windows, a management practice currently being used in the United States that eliminates the risk of potentially harmful impacts of dredging. The use of statistical methods was suggested to address the issue of data insufficiency and this methodology was applied in the downstream part of the Gangjeong-Goryeong weir located within the Nakdong river basin. The results show that when performing a month of dredging, the optimal period is March whereas the optimal month to start dredging is August in case of an eight-month dredging project. If Korea's flood season is also considered for an eight-month dredging process, then October is the optimal month to start dredging. Non-structural methods such as the Environmental Windows reduce maintenance costs and also bring only short-term side effects to the environment, as opposed to structural methods such as the development of environmentally-friendly dredging machine. Given that few studies have explored this topic in Korea, the findings and suggestions could serve as basic data in studying river dredging in the future.