• Title/Summary/Keyword: Water Repellency

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A Study of the usage of Corrugated Fiberboard Cartons for Domestic Fresh Produce and Their Physical Properties: Focused on a Gyeongsan City, North Gyeongsan Province (국내 신선 농산물 포장용 골판지 상자의 이용 실태 및 물리적 특성 연구: 경북 경산 소재 지역 중심으로)

  • Kim, Minhwi;Lee, Myungho;Boonsiriwit, Athip;Lee, Youn Suk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.1
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    • pp.55-66
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    • 2022
  • In this study, forty corrugated fiberboard (CF) boxes for fresh produce were collected from farms located in Gyeongsan city and evaluated its characterizations and physical properties according to Korean Standard (KS). The basis weight, flute, and paperboard combination were determined for the characterizations of CF boxes. The measured basis weights of all samples were within the tolerance limit referred to KS and the flutes were B/F, EB/F, and AB/F flute, respectively. The bursting strength (BS), edgewise crush resistance (ECR), and compression strength (CS) were tested to evaluate the physical properties. There are four single-walled (SW) CF boxes showed BS and ECR higher than 638 kPa and 3.30 kN/m, respectively. One SW CF boxes showed BS and ECR higher than 785 kPa and 3.43 kN/m, respectively. In case of double-walled (DW) CF boxes, sixteen CF boxes showed BS and ECR higher than 785 kPa, 4.96 kN/m (AB flute), or 4.90 (EB flute), respectively. The other nineteen CF boxes showed BS and ECR higher than 981 kPa, 5.29 kN/m (AB flute), or 5.20 (EB flute), respectively. All the CF boxes except two samples showed the acceptable compression strength in reference to the guideline of KS.

Morphological Characteristics of Tricholoma matsutake Ectomycorrhiza (송이 외생균근(外生菌根)의 형태적(形態的) 특징(特徵))

  • Koo, Chang-Duck
    • Journal of Korean Society of Forest Science
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    • v.94 no.1 s.158
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    • pp.16-20
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    • 2005
  • Tricholoma matsutake ectomycorrhizas are unique in their morphology: not bifurcated broom shaped roots with not easily wettable brilliant and profuse white hyphae. To understand these characteristics the ectomycorrhizas were investigated with electron microscopy. T. matsutake ectomycorrhiza have thin mantle and typical Hartig net development in the epidermis and cortex, but no fungal mantle on the root apex. There were no penetrating hyphae inside of the cells of either epidermis, cortex or stele. Inside of the walls of epidermis and cortex cells are lined with ca. $2{\mu}m$ hemispherical amyloplasts. The brilliant hyphal surface was covered with various fine amorphous granules. The hyphal cell wall was thin membrane less than $0.3{\mu}m$ thick. There is no clamp connection on the hyphae. This thin membraneous cell wall with high elasticity can be related to survival strategy of the species without plasmolysis under frequent soil water stress environment. And the coarse hyphal surface with some water repellency can control sudden inrush of water of the hyphae with an extremely low osmotic potential. It is concluded that no mantle on the tip can induce mycorrhizas not bifurcated and that finely coarse surface of T. matsutake hyphae can make the hyphae brilliantly white but less wetted.

Applying Evaluation of Soil Erosion Models for Burnt Hillslopes - RUSLE, WEPP and SEMMA (산불사면에 대한 토양침식모형의 적용 평가 - RUSLE, WEPP, SEMMA)

  • Park, Sang Deog;Shin, Seung Sook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.3B
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    • pp.221-232
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    • 2011
  • Applicability of three soil erosion models for burnt hillslopes was evaluated. The models were estimated with the data from plots established after tremendous wildfire occurred in the east coastal region. Soil erosion and surface runoff were simulated by the Water Erosion Prediction Project (WEPP) and the Revised Universal Soil Loss Equation (RUSLE) of application mode for disturbed forest areas and the Soil Erosion Model for Mountain Areas (SEMMA) developed for burnt hillslopes. Simulated sediment yield and surface runoff were compared with the measured those. In maximum value of sediment yield, three models was under-predicted and RUSLE and WEPP had difference of over two times. SEMMA showed the best model response coefficient, determination coefficient and the model efficiency. In application of models to the soil erosion according to the elapsed year after wildfire, all models were underestimated in initial stage disturbed by wildfire. Evaluation of models in this burnt hillslopes was shown the tends to under-predict soil erosion for larger measured values. Although a lot of sediment can be generated in small rainfall event as fine-grained soil of the high water repellency was exposed excessively right after wildfire, this under-prediction was shown that those models have a limit to estimate the weighted factors by wildfire.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part 1) (저분자 유기실리콘 계면활성제의 개발 동향 (제1보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.66-82
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    • 2017
  • Organosilicone-based surfactants consist of hydrophobic organosilicone groups coupled to hydrophilic polar groups. Organosilicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, trisiloxane surfactants, having low molecular weight organosilicone as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of trisiloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review covers the synthetic schemes of reactive trisiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive trisiloxanes to hydrophilic groups, and the synthetic schemes of the main trisiloxane surfactants including polyether-, carbohydrate-, gemini-, bolaform-, double trisiloxane-type surfactants.

Studies on the Aging Characteristics in Different Parts of Beeswax-treated Duplicates during Humidified Artificial Aging (습식 인공열화 시 밀랍본 복제품의 제책 부위별 열화특성)

  • Choi, Kyoung-Hwa;Cho, Jung Hye;Kang, Yeong Seok;Yang, Eun Jung;Jeong, Hye Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.72-79
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    • 2012
  • In this study, to understand the aging factor and mechanism in different partitions of the beeswax-treated volumes, the duplicated beeswax-treated volume was artificially aged at $80^{\circ}C$ of temperature and 65% of relative humidity and then a physical and optical properties of an aged volumes was analyzed. Also, the degraded components of the beeswax samples isolated from different partitions of aged volumes was measured using a gas chromatography/mass spectroscopy (GC/MS). In results, the surface of beeswax-treated volume which is primarily affected by a main aging factors such as light, oxygen, moisture was more deteriorated than the inside of that volume. However, unlike inside of the book volume which was made from paper, the inside of beeswax-treated volume wax was also considerably deteriorated. The inside of the beeswax-treated volume is largely unaffected by the oxygen and humidity during aging due to the water repellency and the air permeation resistance of beeswax. Therefore, it is confirmed that aging factors and mechanisms in the inside of the volume are different from thats of the outside of the volume. This fact was also verified by the results of GC/MS analysis of an beeswax samples which was sampled from different partitions of aged volumes. As result as GC/MS analysis of the beeswax extracted from the outside of the aged volume, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) were increased and the compounds with a carbon length of above $C_{34}$ (ester, etc) were also increased. But the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were decreased. In case of the aged beeswax of inside, the low molecular compounds with a carbon length of $C_9-C_{20}$ (fatty acid, etc) and the compounds with a chain length of $C_{21}-C_{36}$ (hydrocarbon, alcohol, etc) were increased. While, the compounds with a carbon length of above $C_{34}$ (ester, etc) were decreased.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part II) (저분자 유기실리콘 계면활성제의 개발 동향 (제2보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.461-477
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    • 2017
  • Organosilicone-based surfactants, consisting of hydrophobic organosilicone groups coupled to hydrophilic polar groups, have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, organosiloxane surfactants, having low molecular weight siloxane as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of low molecular weight siloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review includes the synthetic schemes of reactive tetrasiloxanes and disiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive tetrasiloxanes or disiloxanes to hydrophilic groups, and the main synthetic schemes of the tetra- and di-siloxane surfactants having polyether-, carbohydrate-, gemini-, bola-type surfactant structures.

Preparation of Cellulose Nanofibrils and Their Applications: High Strength Nanopapers and Polymer Composite Films (셀룰로오스 나노섬유의 제조 및 응용: 고강도 나노종이와 고분자복합필름)

  • Lee, Sun-Young;Chun, Sang-Jin;Doh, Geum-Hyun;Lee, Soo;Kim, Byung-Hoon;Min, Kyung-Seon;Kim, Seung-Chan;Huh, Yoon-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.3
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    • pp.197-205
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    • 2011
  • Cellulose nanofibrils (CNF) with 50~100 nm diameter were manufactured from micro-size cellulose by an application of a high-pressure homogenizer at 1,400 bar. High strength nanopapers were prepared over a filter paper by a vacuum filtration from CNF suspension. After reinforcing and dispersing CNF suspension, hydroxypropyl cellulose (HPC) and polyvinyl alcohol (PVA)-based composites were tailored by solvent- and film-casting methods, respectively. After 2, 4, 6 and 8 passes through high-pressure homogenizer, the tensile strength of the nanopapers were extremely high and increased linearly depending upon the pass number. Chemical modification of 1H, 1H, 2H, 2H-perfluorodecyl-triethoxysilane (PFDTES) on the nanopapers significantly increased the mechanical strength and water repellency. The reinforcement of 1, 3, and 5 wt% CNF to HPC and PVA resins also improved the mechanical properties of the both composites.

A Study on the Tannin Weighting of Silk (견의 탄닌가공에 관한 연구)

  • Jeong, In-Mo;Lee, Yong-U;Lee, Gi-Won
    • Journal of Sericultural and Entomological Science
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    • v.28 no.1
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    • pp.72-78
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    • 1986
  • The studies were performed to investigate the optimum conditions for tannic processing of silk by use Chinese Gallotannin and synthesized tannic acid, which are aimed at weighting, dyeing and physical properties of tannin treated silk. 1. It was reasonable that the concentration of tannin solution is 30 grams per liter of Chinese Gallotannin, 15 grams per liter of tannic acid for the efficient weighting of processed silk. The temperature and time for tannin treatment was optimum at 80$^{\circ}C$, 60 minutes and the acidity of tannin solution at pH 2 to 3. 2. In dyeing the tannintreated silk by Acid dye Orange II, the temperature and time was reasonable at 60$^{\circ}C$, 90 minutes to control the desorption of tannin components weighted onto silk. 3. The colour differences ($\Delta$E) of dyed silk fabric by soaping could be remarkably narrowed by tannin treatment, resulting in improving the washing fastness of tannin treated silk by two grades more than that of untreated one. 4. The light fastness of tannin treated silk could be drastically improved by reducing the dye-loss of dyed silk fabric which was coused from the Ultra-violet ray irrdiation. 5. The rubbing fastness and water repellency of tannin treated silk was at the same level with that of untreated one. However, the Drape coefficient of tannin treated silk was decreased more than that of untreated one, which is closely related with fabric softness and dressing appearence.

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Analysis of the Effect of Forest Fires on the Mineralogical Characteristics of Soil (산불 영향에 따른 토층의 광물학적 특성 변화에 관한 연구)

  • Man-Il Kim;Chang-Oh Choo
    • The Journal of Engineering Geology
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    • v.33 no.1
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    • pp.69-83
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    • 2023
  • Forest fires increase the risk of subsequent soil erosion and mass movement in burned areas, even under rainfall conditions below landslide alert thresholds, by destroying plants and vegetation and causing changes to soil properties. These effects of forest fires can alter runoff in burned areas by altering soil composition, component minerals, soil water repellency, soil mass stability, and soil fabric. Heat from forest fires not only burns shallow organic matter and plants but also spreads below the surface, affecting soil constituents including minerals. This study analyzed X-ray diffraction and physical properties of topsoil and subsoil obtained from both burned and non-burned areas to identify the composition and distribution of clay minerals in the soil. Small amounts of mullite, analcite, and hematite were identified in burned soils. Vermiculite and mixed-layer illite/vermiculite (I/V) were found in topsoil samples from burned areas but not in those from non-burned areas. These findings show changes in soil mineral composition caused by forest fires. Expansive clay minerals increase the volume of soil during rainfall, degrading the structural stability of slopes. Clay minerals generated in soil in burned areas are therefore likely to affect the long-term stability of slopes in mountainous areas.

Mobility of Nitrate and Phosphate through Small Lysimeter with Three Physico-chemically Different Soils (소형 라이시메터시험을 통한 토양특성에 따른 질산과 인산의 이동성 비교)

  • Han, Kyung-Hwa;Ro, Hee-Myong;Cho, Hyun-Jun;Kim, Lee-Yul;Hwang, Seon-Woong;Cho, Hee-Rae;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.4
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    • pp.260-266
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    • 2008
  • Small lysimeter experiment under rain shelter plastic film house was conducted to investigate the effect of soil characteristics on the leaching and soil solution concentration of nitrate and phosphate. Three soils were obtained from different agricultural sites of Korea: Soil A (mesic family of Typic Dystrudepts), Soil B (mixed, mesic family of Typic Udifluvents), and Soil C (artificially disturbed soils under greenhouse). Organic-C contents were in the order of Soil C ($32.4g\;kg^{-1}$) > Soil B ($15.0g\;kg^{-1}$) > Soil A ($8.1g\;kg^{-1}$). Inorganic-N concentration also differed significantly among soils, decreasing in the order of Soil B > Soil C > Soil A. Degree of P saturation (DPS) of Soil C was 178%, about three and fifteen times of Soil B (38%) and Soil A (6%). Prior to treatment, soils in lysimeters (dia. 300 mm, soil length 450 mm) were tabilized by repeated drying and wetting procedures for two weeks. After urea at $150kg\;N\;ha^{-1}$ and $KH_2PO_4$ at $100kg\;P_2O_5\;ha^{-1}$ were applied on the surface of each soil, total volume of irrigation was 213 mm at seven occasions for 65 days. At 13, 25, 35, 37, and 65 days after treatment, soil solution was sampled using rhizosampler at 10, 20, and 30 cm depth and leachate was sampled by free drain out of lysimeter. The volume of leachate was the highest in Soil C, and followed by the order of Soils A and B, whereas the amount of leached nitrate had a reverse trend, i.e. Soil B > Soil A > Soil C. Soil A and B had a significant increase of the nitrate concentration of soil solution at depth of 10 cm after urea-N treatment, but Soil C did not. High nitrate mobility of Soil B, compared to other soils, is presumably due to relatively high clay content, which could induce high extraction of nitrate of soil matrix by anion exclusion effect and slow rate of water flow. Contrary to Soil B, high organic matter content of Soil C could be responsible for its low mobility of nitrate, inducing preferential flow by water-repellency and rapid immobilization of nitrate by a microbial community. Leached phosphate was detected in Soil C only, and continuously increased with increasing amount of leachate. The phosphate concentration of soil solution in Soil B was much lower than in Soil C, and Soil A was below detection limit ($0.01mg\;L^{-1}$), overall similar to the order of degree of P saturation of soils. Phosphate mobility, therefore, could be largely influenced by degree of P saturation of soils but connect with apparent leaching loss only more than any threshold of P accumulation.