• Title/Summary/Keyword: Water Region

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Dynamic Behavior Study in Systems Containing Nonpolar Hydrocarbon Oil and C12E5 Nonionic Surfactant (C12E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동 관찰)

  • Bae, Min Jung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.46-53
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed in systems containing $C_{12}E_5$ nonionic surfactant solution and nonpolar hydrocarbon oil. The phase behavior result showed an oil-in-water(O/W) microemulsion(${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water-in-oil(W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a 3 phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop with time were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous surfactant solution were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time were found to increase with an increase in the chain length of a hydrocarbon oil.

Dynamic Behavior Study Using Videomicroscopy in Systems Containing Nonpolar Hydrocarbon Oil and C10E5 Nonionic Surfactant Solution (Videomicroscopy를 이용한 C10E5 비이온 계면활성제 수용액과 비극성 탄화수소 오일 사이의 동적 거동에 관한 연구)

  • Bae, Min-Jung;Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.473-478
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    • 2009
  • Phase equilibrium and dynamic behavior studies were performed on systems containing $C_{10}E_5$ nonionic surfactant solutions and nonpolar hydrocarbon oils. The phase behavior showed an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water in oil (W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a three-phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time increased with an increase in the chain length of a hydrocarbon oil.

Socioeconomic vulnerability assessment of drought using principal component analysis and entropy method (주성분 분석 및 엔트로피 기법을 적용한 사회·경제적 가뭄 취약성 평가)

  • Kim, Ji Eun;Park, Ji Yeon;Lee, Joo-Heon;Kim, Tae-Woong
    • Journal of Korea Water Resources Association
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    • v.52 no.6
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    • pp.441-449
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    • 2019
  • Drought is a longer lasting and more extensive disaster than other natural disasters, resulting in significant socioeconomic damage. Even though drought events have same severity, their damage vary from region to region because of spatial, technical, economic, and social circumstances. In this study, drought vulnerability was assessed considering socioeconomic factors. Preliminary factors were identified from the case study for Chungcheong province, and evaluative factors were selected by applying the principal component analysis. The entropy method was applied to determine the weights of evaluative factors. As a result, in Chungcheong province, farm population, number of recipient of basic living, water fare gap indicator, area of industrial complex, amount of underground water usage, amount of water available per capita, water supply ratio, financial soundness for water resources, amount of domestic water usage, amount of agricultural water usage and agricultural land area were chosen as the evaluative factors. Among them, the factors associated with agriculture had larger weights. The overall assessment of vulnerability indicated that Cheongju, Dangjin and Seosan were the most vulnerable to drought.

Effect of Cosurfactant on Microemulsion Phase Behavior in NP7 Surfactant System (보조계면활성제가 NP7 계면활성제 시스템의 마이크로에멀젼 형성에 미치는 영향에 관한 연구)

  • Lim, HeungKyoon;Lee, Seul;Mo, DaHee;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.416-422
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    • 2011
  • In this study, the effect of cosurfactant on the phase equilibrium and dynamic behavior was studied in systems containing NP7 nonionic surfactant solutions and nonpolar hydrocarbon oils. All cosurfactants used during this study such as n-pentanol, n-octanol and n-decanol acted as a hydrophobic additive and thus promoted the transition from an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with an excess oil phase to a three-phase region containing excess water, excess oil, and a middle-phase microemulsion and further to a water in oil (W/O) ${\mu}E$ in equilibrium with the excess water phase. The transition temperature was found to decrease with both increases in the chain length and amount of addition of a cosurfactant. Dynamic behavior studies under O/W ${\mu}E$ conditions showed that an oil drop size decreased with time due to the solubilization into micelles. On the other hand, both the spontaneous emulsification of water into the oil phase and the expansion of oil drop were observed under W/O ${\mu}E$ conditions because of the diffusion of surfactant and water into the oil phase. Under conditions of a three-phase region including a middle-phase ${\mu}E$, both the rapid solubilization and emulsification of the oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Dynamic interfacial tension measurements have been found to be in a good agreement with dynamic behavior results.

A Study on the Optimal Operation and Policy of the Boryeong Dam Diverion Pipe Line Using the SWAT Model (SWAT 모형을 이용한 보령댐 도수로 운영 방안 및 정책 연구)

  • Park, Bumsoo;Yoon, Hyo Jik;Hong, Yong Seok;Kim, Sung Pyo
    • Journal of Korean Society on Water Environment
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    • v.36 no.6
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    • pp.546-558
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    • 2020
  • While industrialization has provided in abundance, the pollution it creates has caused untold damage to the environment, increasing the frequency and severity of natural disasters through changes in global climate patterns. The World Risk Forum's (WEF) World Risk Report presented the results of a survey of experts from around the world detailing the most influential risk factors over the next decade. Notably, the failure to respond to climate change ranked first and the global water crisis third. The extreme drought in the western Chungnam province was unexpected in 2016. At the time, the water level of Boryeong Dam was drastically decreased due to receiving less than half the average recorded rainfall in the region that year. The Boryeong Dam diversion pipeline has the capacity to solve the water shortage problem between these two regions by providing water from Geumgang to the western part of Chungnam, including Boryeong City. Current weather trends suggest drought is likely to continue in western Chungnam, which uses the Boryeong Dam as an intake source. This makes it necessary to operate Boryeong Dam diversion pipeline in an efficient and effective manner. SWAT is a watershed scale model developed to predict the impact of land management practices on water. The SWAT model was used in this study to evaluate the adequacy of the Boryeong Dam diversion pipeline operational plan by comparing it to present Boryeong Dam diversion pipeline operation. By investigating the number of days required to reach each reservoir stage, we determined that the number of days required to reach the boundary stage was less than that of the current operation. This determination accounts for the caveats that the Boryeong Dam waterway was not operated and only one pump will be operated from October to May of next year. As our results suggest, the most stable operation scenario is to operate two pumps at all times. This can be accomplished by operating two pumps from the caution stage to increase the number of pumps whenever the stage is raised. In addition to the stable operation of the Boryeong Dam pipeline, policy considerations are required with regard to imposing a water use charge on users of the Boryeong Dam region.

Origin of the Cold Water below $10^{\circ}C$ Occurring in the Southern Coastal Region of the Korean East Sea in Summer by Ra Isotope Distribution (Ra동위체로 본 하계 동해 남부 연안해역에 출현하는 $10^{\circ}C$ 이하 냉수괴의 기원)

  • YANG Han-Soeb;KIM Pyoung-Joong;LEE Jae-Chul;MOON Chang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.4
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    • pp.404-412
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    • 1994
  • Radium isotopes were measured together with oceanographical parameters in the southern coastal region of the Korean East Sea during the period of September $2{\sim}8$, 1991. In September, there were various water masses vertically distributed in this region due to formation of strongly seasonal thermoclines. These water masses were characterized by activity of radium isotopes as well as water temperature and dissolved oxygen. Among the water masses, Japan Sea Proper Water(JSPW) below $1^{\circ}C$ had the highest Ra-226 activities but the lowest Ra-228 concentrations. However, Tsushima Surface Water (TSW) above $20^{\circ}C$ in water temperature had the highest Ra-228 which decreased sharply with depth. In TSW, Ra-228 activities were in the range of $194{\sim}270$ dpm/kl, which were approximately 10 times higher than JSPW. Activity ratios(A.R's) of Ra-228/Ra-226 were $1.9{\sim}2.6$ for TSW, $0.7{\sim}1.1$ for Tsushima Middle Water(TMW) of $12{\sim}17^{\circ}C\;to\;0.4{\sim}0.7$ for North Korea Cold Water(NKCW) with $1{\sim}7^{\circ}C$ and below 0.2 for JSPW. The Ra-228/Ra-226 ranged from 0.6 to 0.9 in the cold waters of $2{\sim}6^{\circ}C$, which were observed at depth of $65{\sim}120\;m$ in this study area. Radium isotopes provided a useful means of identifying origins of the cold water which occurred annually at intermediate or bottom layers in the southern coastal zone of the Korean East Sea. By plotting radium isotopes against water temperature, it could be observed clearly that the cold waters between $2{\sim}6^{\circ}C$ did not originate from the mixed water of JSPW and TMW but from NKCW.

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A Study on the Relationship between the Physical Properties of Soil and the Compression Index of Soft Clay in Gyungnam Coastal Region (경남해안지역 연약점토의 토질특성과 압축지수와의 상관성에 관한 연구)

  • 장정욱;최성민;박춘식
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.13 no.4
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    • pp.282-289
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    • 2001
  • This study analyzed the relationship between the physical properties of soil and the compression index of the soft clay in Gyungnam coastal region. Tests of physical and mechanical properties of soil have been carried out under the undisturbed condition at 82 Gimhae, 18 Jinhae and 27 Geojespecimens. The result showed that Terzaghi & Peck's empirical equation of the compression index were not applicable. The compression index of soft clay in Gyungnam coastal region was correlated with the water contents, the liquid limit and the initial void ratio. Among these, the initial void ratio showed the highest correlation with the compression index of soft clay in Gyungnam coastal region and the relationship is shown in the following. (1) The compression index of soft clay in Gyungnam coastal region is represented as follows: $C_c=0.74(e_o-0.7$ (2) The relationship between compression index and the swelling index in Gyungnam coastal region is represented as follows: $C_s=(1/8-1/15)C_c$.

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Optimization of membrane fouling process for mustard tuber wastewater treatment in an anoxic-oxic biofilm-membrane bioreactor

  • Chai, Hongxiang;Li, Liang;Wei, Yinghua;Zhou, Jian;Kang, Wei;Shao, Zhiyu;He, Qiang
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.196-202
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    • 2016
  • Membrane bioreactor (MBR) technology has previously been used by water industry to treat high salinity wastewater. In this study, an anoxic-oxic biofilm-membrane bioreactor (AOB-MBR) system has been developed to treat mustard tuber wastewater of 10% salinity (calculated as NaCl). To figure out the effects of operating conditions of the AOB-MBR on membrane fouling rate ($K_V$), response surface methodology was used to evaluate the interaction effect of the three key operational parameters, namely time interval for pump (t), aeration intensity ($U_{Gr}$) and transmembrane pressure (TMP). The optimal condition for lowest membrane fouling rate ($K_V$) was obtained: time interval was 4.0 min, aeration intensity was $14.6 m^3/(m^2{\cdot}h)$ and transmembrane pressure was 19.0 kPa. And under this condition, the treatment efficiency with different influent loads, i.e. 1.0, 1.9 and $3.3kgCODm^{-3}d^{-1}$ was researched. When the reactor influent load was less than $1.9kgCODm^{-3}d^{-1}$, the effluent could meet the third discharge standard of "Integrated Wastewater Discharge Standard". This study suggests that the model fitted by response surface methodology can predict accurately membrane fouling rate within the specified design space. And it is feasible to apply the AOB-MBR in the pickled mustard tuber factory, achieving satisfying effluent quality.

Decision of Road Direction by Polygonal Approximation. (다각근사법을 이용한 도로방향 결정)

  • Lim, Young-Cheol;Park, Jong-Gun;Kim, Eui-Sun;Park, Jin-Su;Park, Chang-Seok
    • Proceedings of the KIEE Conference
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    • 1996.07b
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    • pp.1398-1400
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    • 1996
  • In this paper, a method of the decision of the road direction for ALV(Autonomous Land Vehicle) road following by region-based segmentation is presented. The decision of the road direction requires extracting road regions from images in real-time to guide the navigation of ALV on the roadway. Two thresholds to discriminate between road and non-road region in the image are easily decided, using knowledge of problem region and polygonal approximation that searches multiple peaks and valleys in histogram of a road image. The most likely road region of the binary image is selected from original image by these steps. The location of a vanishing point to indicate the direction of the road can be obtained applying it to X-Y profile of the binary road region again. It can successfully steer a ALV along a road reliably, even in the presence of fluctuation of illumination condition, bad road surface condition such as hidden boundaries, shadows, road patches, dirt and water stains, and unusual road condition. Pyramid structure also saves time in processing road images and a real-time image processing for achieving navigation of ALV is implemented. The efficacy of this approach is demonstrated using several real-world road images.

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Study on Environmental Changes of River in the Suburban Area and Transition of Relations between Residents and River

  • Hiroyuki Kaga;Kumi Kawano;Yasuhiko Shimomura;Noboru Masuda
    • Journal of the Korean Institute of Landscape Architecture International Edition
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    • no.2
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    • pp.185-191
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    • 2004
  • This study dealt with the Kogi River, located in Kaizuka City, Osaka, which has experienced different improvements from the upper through the lower regions, aimed at revealing temporal relations between residents and the river, as well as probing future problems and directions regarding the river in the suburban area, by conducting a survey of local residents. The result showed that, in the upper region where nature remains in its natural state and the good water quality has been maintained, the relations between the residents and the river continued until around 1965; meanwhile in the middle region the relations have been disappearing since about 1955, and in the lower region where the stream has been repeatedly rehabilitated since 1955, there are fewer involvements of the people with the river. It also revealed that the weaker the relations between people and the river became, the larger the number of residents, even in the upper region, who became concerned over the deteriorating river environment after about 1975, and that in the middle and lower areas, about a decade earlier than in the upper area, the number of those who were aware of the environmental deterioration began to increase. Consequently, with an eye to resuming the relations between people and the river in an suburban area, their future challenges would be the space improvements depending on the environmental characteristics of the area; for example, the recovery of grassy banks for the purpose of protection in the lower region; the preservation and maintenance of many waterside woods as well as the creation of open spaces utilizing the river banks in the middle area; and throughout the whole region, the establishment of a system in which the relations between man and the river can be passed down to future generations, by utilizing the local human resources including those who know the former river landscapes or about the playing in and around the river.

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