• Analytical Science and Technology
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• v.24 no.4
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• pp.298-303
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• 2011

Selenium is one of the interesting elements in human body, because it's important micro-nutrient for human health as the essential biological tissue in protein. Selenite ($SeO_3^{2-}$) and selenate ($SeO_4^{2-}$) are the dominant dissolved selenium species in natural water, and their toxicity and chemical properties are very different each other. Thus it is necessary to separate the two selenium species for understanding selenium behaviors in natural waters. Some reported methods, using an alumina-filled column and an ion chromatography, to separate the selenite and selenite may be difficult to directly apply to the natural water. Therefore magnetite selectively adsorbs selenite and selenate according to pH of solution, the separation of selenite and selenate using a magnetite-filled column was successfully obtained at weak alkali solutions. Moreover, the influence of dissolved anions in natural water at the selenite sorption onto magnetite was also investigated because they could hinder the sorption of selenite onto magnetite. In other to directly apply to the natural water, reactive sites of magnetite should be considered because dissolved silicate in natural water can hinder the adsorption of selenite onto magnetite.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.720-726
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• 2009

We investigated the most effective pre-treatment processes and LC/MS/MS condition for microcystins analysis. With a step-by-step pre-treatment, efficiencies of several established methods were compared. At the level of cell burst, sonication method was found to be the most efficient. As a mycrocystins first extraction solvent, 5% acetic acid showed the highest efficiency. An isolation and recovery rate of mycrocystins of ODS Sep-Pak $C_{18}$ cartridge was higher than HLB SPE cartridge. As a final elution solvent from cartridge, 100% MeOH had a better efficiency than others. Using a LC/MS/MS, effective analytical methods were established. C18 reverse column was used and gradient elution was performed with using acetonitrile, 0.1% formic acid as a mobile phase. We analysed to 0.8 mL/min flow rate fit to the $5{\mu}m$ particle size column and $55^{\circ}C$ housing temperature. The validity of established analytical method was evaluated that MDL as average $0.050{\pm}0.014{\mu}g/L$ and LOQ as average $0.160{\pm}0.045{\mu}g/L$ had a good sensitivity over 40 magnification rather than $2{\mu}g/L$ detection limit of HPLC.

• Journal of the Korean Wood Science and Technology
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• v.37 no.1
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• pp.1-11
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• 2009

Although the exterior wood such as column may frequently contact with liquid water, little work has been found to measure liquid water absorption in wood. To investigate the moisture diffusivity of wood in the longitudinal direction including bound water and free water movement, liquid water absorption test was conducted at the room temperature. The order of magnitude for absorption coefficient and diffusivity was Japanese elm, horn beam, hemlock, spruce, radiata pine, and painted maple. The Boltzmann transformation method was used to determine the diffusivity from measured moisture content distributions in the absorption test. The shape of the curve representing the dependence of diffusivity with moisture content was similar in test samples. The diffusivity decreased with increasing moisture content until around the fiber saturation point and then increased at the nonhygroscopic region, which ranged from $10^{-10}$ to $10^{-7}m^2/s$.

• Journal of Environmental Science International
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• v.4 no.4
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• pp.379-386
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• 1995

Permethrin [3-phenox yben zyl(1RS)-cis,tans-3-(2,2-dichloroviny1)-2,2- dimethylcyclopropane carboxylate] insecticides were selected to study adsorption and leaching potentials related to pollution on Commerce silty clay loam soil near Baton Rouge, Louisiana, USA. GLC-ECD chromatogram of permethrin included 32.5 % of cis-pemehin and 67.4 % of trans-permethrin. Extraction efficiencies of is and trmu-pemetun were 92.5 % and 92.3 % in fortified water, respectively and 85.9 % and 88.8 % in fortified soil, respectively. At a 1:10 moi]/water ratio,the Koc values for sis and fan isomers of permethrin were 938 and 877, respectively. Leaching of permethrin was evaluated in soil columns$(5.4 cm i.d. \times 26 cm length)$. Total recoveries of the permethrin applied to the soil column were $84.5\pm3.1%$. When the soil columns were leached with three pore volumes of water, the distributions of cis-permethrin leached were 6.10 % and 0.07 % of amount applied in the untreated zone soil and leachate water, respectively Trans-pemethrin distributions were 5.20 % in the untreated zone soil and 0.05 % in leachate water. Cis and trans-pemethrin was strongly adsorbed to soil. The results of the study showed the strong relationship between adsorption and leaching. Cis and trans-permethrin to be leached into the groundwater in soils with shallow aquifers were suggested a low leaching potential.

• Structural Engineering and Mechanics
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• v.62 no.2
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• pp.209-224
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• 2017

Elevated water tanks are considered as important structures due to its post-earthquake requirements. Elevated water tank on reinforced concrete frame staging is widely used in India. Different response reduction factors depending on ductility of frame members are used in seismic design of frame staging. The study on appropriateness of response reduction factor for reinforced concrete tank staging is sparse in literature. In the present paper a systematic study on estimation of key components of response reduction factors is presented. By considering the various combinations of tank capacity, height of staging, seismic design level and design response reduction factors, forty-eight analytical models are developed and designed using relevant Indian codes. The minimum specified design cross section of column as per Indian code is found to be sufficient to accommodate the design steel. The strength factor and ductility factor are estimated using results of nonlinear static pushover analysis. It was observed that for seismic design category 'high' the strength factor has lesser contribution than ductility factor, whereas, opposite trend is observed for seismic design category 'low'. Further, the effects of staging height and tank capacity on strength and ductility factors for two different seismic design categories are studied. For both seismic design categories, the response reduction factors obtained from the nonlinear static analysis is higher than the code specified response reduction factors. The minimum dimension restriction of column is observed as key parameter in achieving the desired performance of the elevated water tank on frame staging.

• Magazine of the Korean Society of Agricultural Engineers
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• v.45 no.1
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• pp.63-73
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• 2003

The settling of the dredged soil may vary with mineral composition, grain size distribution, initial water content and salt concentration of suspension of the site. A series of settling column test was performed to investigate the behaviour of solid suspension material from dredging and reclamation. Settling mode was divided into four types from the observation of interface and settling curves of clay minerals and marine clay samples, and the relationship charts of salt concentration and the initial water content were established to use in the dredging operation with any salt concentration. The critical initial water content which was defined as a threshold of zone settling and the consolidation settling was varied with salt concentration of water and was proportional to the plasticity of soil in sea water.

• Korean Journal of Pharmacognosy
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• v.15 no.2
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• pp.104-107
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• 1984

The essential oil fraction of Leonurus sibiricus was analyzed by TLC and gas chromatography. By utilizing silica gel column, a ketone compound, m.w. 167, was isolated from the essential oil. The essential oil showed considerably the diuretic action, but the water extract exhibited weak action. This diuretic action of the water extract was potentiated by combined administration of essential oil. On the isolated rabbit's uterus the essential oil decreased spontanous movement and showed relaxation.

• 한국생물공학회:학술대회논문집
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• 2000.04a
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• pp.418-421
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• 2000

A model was developed to describe the microbial decontamination of diesel contaminated soil in a soil column. The biodegradation rate of diesel in nature depends on temperature and the pH of soil, availability of nutrients, oxygen and water. The soil moisture content is one of the essential factors because it characterizes the availability not only of water to microorganisms but also of oxygen and nutrient dissolved in soil. In this work, the rate of biodegradation was modeled by coupling Michaelis-Menten kinetics for the aqueous-phase solute with adsoption-desoption equation for diesel sorption and desorption from soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.86-88
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• 2002

The mathematical model was proposed to simulate ozone transport and remediation in unsaturated soils contaminated with phenanthrene. Soil column experiments were also carried out to calibrate the mathematical model. The experimental results successfully matched with the modeling results in various soil conditions. The model proposed nondimensional fraction factor to reveal reactivity between phenanthrene and gas phase ozone and liquid phase ozone. From sensitivity analysis, the fraction factor and stoichiometric coefficient decreased as water content increased. Simulation results showed increased SOM content retarded the ozone transport and the phenanthrene removal due to increased ozone consumption.

• YAKHAK HOEJI
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• v.37 no.1
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• pp.54-65
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• 1993

A method for the determination of 16 residual pesticides in crude deugs was examined. Crude drug was extracted with acetonitrile/water solution and the extract was partitioned between hexane/CH$_{2}$Cl$_{2}$ and NaCl saturated water. The organic layer was passed through cleanup column and subjected to the GC/ECD or GC/NPD analysis. Essential oil components in crude drug interfere with the analysis, and sulfuric acid treatment was adapted to overcome this interference.