• Korean Journal of Environmental Agriculture
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• v.18 no.1
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• pp.48-53
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• 1999

In this study, various batch tests were performed to examine the utilization of waste oyster shells for removal of $PO_4^{3-}-P$ in livestock wastewater, because waste oyster shells have been known to be very porous and to have alkaline minerals such as calcium and mangnesium. $PO_4^{3-}-P$ removal rate were increased by waste oyster shells, as specific surface area and contact efficiency per unit area of their were increased. Generally, it could be showed that $PO_4^{3-}-P$ removal rate were very influenced by particle size, dosage and temperature. At low pH of initial reactions, it would be showed that $PO_4^{3-}-P$ removals were directly influenced by adsorption but crystallization process were dominated with passed time and pH increasing. The SEM observed that the variations were hardly seen, but particle sizes of waste oyster shell were relatively big after reactions and showed forms of smaller plate than before reactions.

• Clean Technology
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• v.24 no.4
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• pp.315-322
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• 2018

Industrial use of waste oyster shells is limited because of requiring excessive energy for converting natural oyster shells in the form of calcium carbonate ($CaCO_3$) into calcium oxide (CaO) for this purpose. This study aimed to develop energy-saving process for producing solidifying agent using waste oyster shells for backfill materials. It was suggested that oyster shells were converted to calcium sulfates which were mixed with sodium hydroxide solution and red clay, forming solid specimen. The optimal concentrations of sulfuric acid for sulfation of oyster shell and sodium hydroxide to generate calcium hydroxide ($Ca(OH)_2$), were determined. Unconfined compressive strength of solid specimen increased with increasing the content of solidifying agent while it increased also with increasing ratio of natural oyster shells to coal ash. The result clearly demonstrates that solidifying agent consisting of sulfuric acid-treated oyster shell, coal ash, and sodium hydroxide solution, can be effectively utilized for preparing backfill materials using natural oyster shell and coal ash. Sulfuric acid-treated oyster shell-based solidifying agent has not been previously developed and will contribute to broaden industrial application of waste oyster shells.

• Journal of the Korea Institute of Building Construction
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• v.14 no.6
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• pp.523-529
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• 2014

Large amounts of waste shells have been produced each year from shellfish raising industries located in Korean costal areas. Due to the limited space for the waste shell disposal, the related environmental problem has been a serious issue. It is believed that using the waste shells as a source of aggregate for mortar, concrete or bricks can be a good solution. In this research, possibility of utilizing waste shells as an aggregate of mortar is investigated. Waste shells of manila clam, cockle, clam, sea mussel, and oyster were properly crushed, sieved, and sorted to meet the requirements of the grading of standard fine aggregate. After that, the waste shells were used as partial and total replacement of the fine aggregate, and their absorption and 28-day compressive strengths of mortar were measured. In general, replacement of waste shells increased the absorption and decreased the strength. However, one specimen with cockle increased compressive strength as replacement ratio increased. Mortar with cockle of 50% and 100% replacement showed higher compressive strength than that of control mortar. This increase of compressive strength was found to be affected by the strong interfacial bonding properties of the cockle and a cement matrix.

• Journal of Energy Engineering
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• v.27 no.1
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• pp.51-58
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• 2018

In this paper, we reported that the influence of advanced functional mineral filler calcium carbonate ($CaCO_3$) extracted from oyster shell waste, which are rich mineral sources of $CaCO_3$. Oyster Shells, available in abundance, have no eminent use and are commonly regarded as waste. Their improper disposal causes a significant level of environmental concern and also results in a waste of natural resources. Recycling shell waste could potentially eliminate the disposal problem, and also turn an otherwise useless waste into high value added products. Oyster shell waste calcination process to produce pure lime (CaO) which have good anti-microbial property for waste water treatment and then focuses on its current applications to treat the coffee waste and its effluents for biological treatment and utilization as a fertilizers.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.62-63
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• 2018

Oyster shell is produce by shucking process in oyster farming in southern coast of Korea. In average, about 6.7kg of oyster shell is produced as an industrial waste for 1kg of oyster flesh, and even only in last year, it is estimated that about 150,000 ton of oyster shell is produced. Oyster shell is light weighted and the strength characteristic of it is similar to send. So we produced mortar test piece using grounded oyster shell according to aggregate and reviewed strength characteristic. Therefore, in this study, the strength characteristics of the test specimen are evaluated by artificially altering fineness modulus and curing method by processing oyster shells.

• Magazine of RCR
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• v.11 no.1
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• pp.11-16
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• 2016

• Cement Symposium
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• no.27
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• pp.6-13
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• 2000

• Journal of Energy Engineering
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• v.27 no.1
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• pp.76-80
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• 2018

The objective of this research paper is to discuss the waste coffee residue disposal and its environmental effects on the environment. As we know, coffee is one of the most demand and swallowed beverages in the world, which leads to large quantities of solid waste. Which can be toxic and a lot of environmental problems occur. In developing countries, there is a lack of proper coffee waste residue management. The coffee beans and residues contain several organic compounds. The wastewater from coffee industry emitted several pollutants (highly concentrated) and it contaminates the soil, ground waters, aquatic life, and also human health. Hence it is essential to treat the coffee waste residues. Mean while, oyster shell waste and its disposal also a big environmental challenge in the coastal regions of southeast Korea. In this paper, we focused the treatment of coffee waste residue with oyster shell waste powder. Primarily, oyster shells are calcinated at higher temperatures and investigated the calcined CaO powder as an anti microbic agent to the bacteria presented in coffee waste residues. We successfully applied calcium oxide from oyster shell waste, as an antimicrobic agent.

• Journal of Energy Engineering
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• v.27 no.3
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• pp.48-56
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• 2018

The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.2
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• pp.185-192
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• 2010

The objective of this study was to investigate the effectiveness of stabilization for army firing range soil highly contaminated with Pb (total Pb: 29,000 mg/kg) using calcined waste oyster shells. The calcination was conducted to activate quicklime from calcite. In order to evaluate the effectiveness of calcination, both natural oyster shells (NOS) and calcined oyster shells (COS) were applied to the Pb contaminated soil. Stabilization was conducted by mixing the contaminated soil with oyster shell media at 5-20 wt% and cured for 28 days. Following 28 days of curing, Pb leachability was measured based on the Korean Standard Test method (0.1 N HCl extraction). The treatment results showed that the COS treatment outperformed the NOS treatment. All of the NOS treatments failed to meet the Korean warning standard of 100 mg/kg. However, the Pb concentrations were significantly reduced to 47 mg/kg and 3 mg/kg upon 15 wt% and 20 wt% COS treatments, respectively which passed the Korean warning standard. Moreover, -#20 mesh materials were more effective than the -#10 mesh materials in effectively reducing Pb leachability. The scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX) results indicated that Pb immobilization was strongly linked to Al and Si.