• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.813-816
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• 2009

A commercial-scale RDF boiler that its burning capacity is 400 kg-RDF/hr and steam production capacity is 2 ton/hr. It has a chain type stoker and waste heat recovery system. Heat exchanger is vertical water-pipe so that soot blowing and removal is convenient during operation. Dry scrubber, bag filter and activated carbon tower have been installed for the reduction of air pollutant gases and dust. Analysing data of pollutants from stack such as $SO_x$. $NO_x$ and dioxin shows so good results that the boiler system could comply the regulated emission limits.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.6
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• pp.482-493
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• 2005

Biomass is originally photosynthesized from inorgainic compounds such as $CO_2$, minerals, water and solar energy. Recent studies have shown that anaerobic bacteria have the ability to convert recalcitrant biomass such as cellullosic or chitinoic materials to useful compounds. The biomass containing agricultural waste, unutilized wood and other garbage is expected to utilize as feed, food and fuel by microbial degradation and other metabolic functions. In this study we isolated several anaerobic, cellulolytic and chitinolytic bacteria from rumen fluid, compost and soil to study their related enzymes and genes. The anaerobic and cellulolytic bacteria, Clostridium thermocellum, Clostridium stercorarium, and Clostridium josui, were isolated from compost and the chitinolytic Clostridium paraputrificum from beach soil and Ruminococcus albus was isolated from cow rumen. After isolation, novel cellulase and xylanase genes from these anaerobes were cloned and expressed in Escherichia coli. The properties of the cloned enzymes showed that some of them were the components of the enzyme (cellulase) complex, i.e., cellulosome, which is known to form complexes by binding cohesin domains on the cellulase integrating protein (Cip: or core protein) and dockerin domains on the enzymes. Several dockerin and cohesin polypeptides were independently produced by E. coli and their binding properties were specified with BIAcore by measuring surface plasmon resonance. Three pairs of cohesin-dockerin with differing binding specificities were selected. Two of their genes encoding their respective cohesin polypeptides were combined to one gene and expressed in E. coli as a chimeric core protein, on which two dockerin-dehydrogenase chimeras, the dockerin-formaldehyde dehydrogenase and the dockerin-NADH dehydrogenase are planning to bind for catalyzing $CO_2$ reduction to formic acid by feeding NADH. This reaction may represent a novel strategy for the reduction of the green house gases. Enzymes from the anaerobes were also expressed in tobacco and rice plants. The activity of a xylanase from C. stercorarium was detected in leaves, stems, and rice grain under the control of CaMV35S promoter. The digestibility of transgenic rice leaves in goat rumen was slightly accelerated. C. paraputrificum was found to solubilize shrimp shells and chitin to generate hydrogen gas. Hydrogen productivity (1.7 mol $H_2/mol$ glucos) of the organism was improved up to 1.8 times by additional expression of the own hydrogenase gene in C. paraputrficum using a modified vector of Clostridiu, perfringens. The hydrygen producing microflora from soil, garbage and dried pelletted garbage, known as refuse derived fuel(RDF), were also found to be effective in converting biomass waste to hydrogen gas.

• Journal of Climate Change Research
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• v.3 no.3
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• pp.211-224
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• 2012

Technology for energy recovery from waste can reduce the greenhouse gas emissions. So recently, there are several companies using RDF, RPF, WCF instead of using only coal fuel and it's part of the fuel on the increase. In this study, we developed Wood chip fuel $CO_2$ emission factor through fuel analysis. It's moisture content is 23%, received net calorific value is 2,845 kcal/kg, and received basis carbon is 34%. The result of emission factor is $105ton\;CO_2/TJ$, it's 5.9% lower than 2006 IPCC guideline default factor $112ton\;CO_2/TJ$. The gross GHG(Greenhouse gases) emissions of plant A is $178,767ton\;CO_2 eq./yr$, and Net GHG emissions is $40,359ton\;CO_2 eq./yr$. Therefore, the reduction of GHG emissions is $138,408ton\;CO_2/yr$ through using WCF, and I accounts for 77% of all GHG emissions.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.5
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• pp.39-45
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• 2009

An experimental research with 2.0 liter 4-cylinder turbocharged diesel engine was carried out to investigate the combustion and emission characteristics for various alternative fuels. The conventional diesel fuel, neat GTL, blends of 80% of GTL and 20% of biodiesel derived from waste cooking oil are utilized without any modification of engine hardware and ECU data. For GTL and blends of GTL/biodiesel fuel, the ignition delay decreased at the same operating conditions, and overall combustion duration increased slightly. Also, the peak cylinder pressure increased for blends of GTL/biodiesel compared to diesel and GTL fuel. THC and CO emissions with blends of GTL/biodiesel compared to other fuels decreased for the low and middle load conditions. But NOx emission increased due to oxygen content in biodiesel. The number concentrations of PM are higher for blends of GTL/biodiesel than other test fuels in the nucleation mode, while it had an opposite tendency in the accumulation mode, which implies more reduction of PM for blends of GTL/biodiesel on the base of mass concentration.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.429-432
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• 2011

The feasibility of applications of the char obtained from a gasification process of municipal-waste refuse derived fuel (RDF) as an auxiliary fuel was evaluated by combustion experiments. The higher heating value of the RDF char was 3000~4000 kcal/kg and its chlorine content was below the standard requirement demonstrating its potential as an auxiliary fuel. In the combustion exhaust gas, the maximum $NO_x$ and $SO_2$ concentrations were 240 ppm and 223 ppm, respectively. If an aftertreatment is applied, it is possible to control their concentrations low enough to meet the air pollutant emission standard. The HCl concentration was relatively high indicating that a care should be taken for HCl emission from the combustion of RDF. Based on the temperature distribution within the reactor, the concentration change of $O_2$ and $CO_2$, and the amount and the loss on ignition of solid residue, it was inferred that the combustion reaction was the most reliable when the excess air ratio of 1.3 was used.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.3
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• pp.27-33
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• 2012

According to the statistics of the Ministry of Environment, the emission of sewage sludge is increased by 7~9% yearly. In the future, it will be increased continuously because of extension of sewage disposal plants, high class treatment for removing nitrogen and phosphorus. Until now, we have depended on reclamation for lots of quantity and some part has been treated by ocean emission. But, direct reclamation of organic waste will be prohibited and even ocean emission will be prohibited now, so the treatment of sludge is put on emergency alert. Bio-gas can be produced by applying anaerobic digestion method for the recycling or refuse derived fuel can be conducted by applying carbonization method. However, the process is difficult, causes bad smell and makes it the second waste, so it cannot be practical method in fact. This study applied a fluidized bed combustor for sewage sludge treatment technologies that can actually take advantage of key technologies in order to verify its purpose is to demonstrate selected. If applying the fluidized bed combustor, it can be easily utilized as the replaced resource of energy(fuel) in the countries whose energy resources are insufficient, like our country. Especially, if applying only original strengths of the fluidized bed combustor sufficiently, the sewage sludge can be treated simply, eco-friendly, sanitarily and economically. Particularly, it is verified as the energy technology suitable for government's green growth policy.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.101-101
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• 2010

Anaerobic digestion(AD) is the most promising method for treating and recycling of different organic wastes, such as organic fraction of municipal solid waste, household wastes, animal manure, agro-industrial wastes, industrial organic wastes and sewage sludge. During AD, i.e. organic materials are decomposed by anaerobic forming bacteria and fina1ly converted to excellent fertilizer and biogas which is a mixture of carbon dioxide and methane. AD has been one of the leading technologies that can make a large contribution to produce renewable energy and to reduce $CO_2$ and other green-house gas(GHG) emission, it is becoming a key method for both waste treatment and recovery of a renewable fuel and other valuable co-products. Currently some 80% of the world's overall energy supply of about 400 EJ per year in derived from fossil fuels. Nevertheless roughly 10~15% of this demand is covered by biomass resources, making biomass by far the most important renewable energy source used to date. The representative biofuels produced from the biomass are bioethanol, biodiesel and biogas, and currently biogas plays a smaller than other biofuels but steadily growing role. Traditionally anaerobic digestion applied for different biowaste e.g. sewage sludge, manure, other organic wastes treatment and stabilization, biogas has become a well established energy resource. However, the biowaste are fairly limited in respect to the production and utilization as renewable source, but the plant biomass, the so called "energy crops" are used for more biogas production in EU countries and the investigation on the biomethane potential of different crops and plant materials have been carried out. In Korea, with steadily increasing oil prices and improved environmental regulations, since 2005 anaerobic digestion was again stimulated, especially on the biogasification of different biowastes and agro-industrial biomass including "energy crops". This study have been carried out to investigate anaerobic biodegradability by the biochemical methane potential(BMP) test of animal manures, different forage crops i.e. "energy crops", plant and industrial organic wastes in the condition of thermophilic temperature, The biodegradability of animal manure were 63.2% and 58.2% with $315m^3CH_4/tonVS$ of cattle slurry and $370m^3CH_4/tonVS$ of pig slurry in ultimate methane yields. Those of winter forage crops were the range 75% to 87% with ultimate methane yield of $378m^3CH_4/tonVS$ to $450m^3CH_4/tonVS$ and those of summer forage crops were the range 81% to 85% with ultimate methane yield of $392m^3CH_4/tonVS$ to $415m^3CH_4/tonVS$. The forge crops as "energy crops" could be used as good renewable energy source to increase methane production and to improve biodegradability in co-digestion with animal manure or only energy crop digestion.

• Journal of Marine Bioscience and Biotechnology
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• v.7 no.1
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• pp.1-10
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• 2015

Bio diesel has advantages to reduce GHG(Greenhouse Gas) compare with the fossil fuel by using oil comes from plant/animal sources and even waste such as used cook oil. The diversity of energy feeds brings the positive effects to secure the national energy mix. In this circumstance, micro-algae is one of the prospective source, though some technical barriers. We analyzed the bio diesel which was derived from Dunaliella tertiolecta LB999 through the BD100 quality specifications designated by the law. From that result, it is revealed that the oxidation stability is one of the properties to be improved. In order to find the reason for low oxidation stability, we analyzed the oxidation tendency of each FAME components through some methods(EN 14111, EN14112, EN16091). In this study, we could find the higher double bond FAME portion, the more oxidative property(C18:1${\ll}C18:3$) in bio diesel and main unsaturated FAME group is acted as the key component deciding the bio diesel's oxidation stability. It is proved experimentally that C18:3 FAME are oxidized easily under the modified accelerated oxidation test. We also figure out low molecular weight hydrocarbon and FAME were founded as a result of thermal degradation. Some alcohol and aldehydes were also made by FAME oxidation. In conclusion, it is necessary to find the way to improve the micro-algal bio diesel's oxidation stability.