• Title/Summary/Keyword: Waste solution

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Effect of Reaction Factors on the Fabrication of Nano-Sized Ni-ferrite Powder by Spray Pyrolysis Process (분무열분해공정에 의한 니켈 페라이트 나노 분말 제조에 미치는 반응인자들의 영향)

  • 유재근;서상기;박시현;한정수
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.202-209
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    • 2004
  • In this study, nano-sized powder of Ni-ferrite was fabricated by spray pyrolysis process using the Fe-Ni complex waste acid solution generated during the shadow mask processing. The average particle size of the produced powder was below 100 nm. The effects of the reaction temperature, the inlet speed of solution and the air pressure on the properties of powder were studied. As the reaction temperature increased from 80$0^{\circ}C$ to 110$0^{\circ}C$, the average particle size of the powder increased from 40 nm to 100 nm, the fraction of the Ni-ferrite phase was also on the rise, and the surface area of the powder was greatly reduced. As the inlet speed of solution increased from 2 cc/min. to 10 cc/min., the average particle size of the powder greatly increased, and the fraction of the Ni-ferrite phase was on the rise. As the inlet speed of solution increased to 100 cc/min., the average particle size of the powder decreased slightly and the distribution of the particle size appeared more irregular. Along with the increase of the inlet speed of solution more than 10 cc/min., the fraction of the Ni-ferrite phase was decreased. As the air pressure increased up to 1 $kg/cm^2, the average particle size of the powder and the fraction of the Ni-ferrite phase was almost constant. In case of 3 $kg/cm^2 air pressure, the average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased.

Temperature and Concentration Dependencies of Chemical Equilibrium for Reductive Dissolution of Magnetite Using Oxalic Acid

  • Lee, Byung-Chul;Oh, Wonzin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.187-196
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    • 2021
  • Chemical equilibrium calculations for multicomponent aqueous systems involving the reductive dissolution of magnetite (Fe3O4) with oxalic acid (H2C2O4) were performed using the HSC Chemistry® version 9. They were conducted with an aqueous solution model based on the Pitzer's approach of one molality aqueous solution. The change in the amounts and activity coefficients of species and ions involved in the reactions as well as the solution pH at equilibrium was calculated while changing the amounts of raw materials (Fe3O4 and H2C2O4) and the system temperature from 25℃ to 125℃. In particular, the conditions under which Fe3O4 is completely dissolved at high temperatures were determined by varying the raw amount of H2C2O4 and the temperature for a given raw amount of Fe3O4 fed into the aqueous solution. When the raw amount of H2C2O4 added was small for a given raw amount of Fe3O4, no undissolved Fe3O4 was present in the solution and the pH of the solution increased significantly. The formation of ferrous oxalate complex (FeC2O4) was observed. The equilibrium amount of FeC2O4 decreased as the raw amount of H2C2O4 increased.

Hazardous Substances in the old Personal Computer (구식PC에 함유된 유해물질에 관한 고찰)

  • 이성호
    • Journal of Korea Society of Industrial Information Systems
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    • v.5 no.4
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    • pp.47-54
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    • 2000
  • In general, computer industry is known as clean sector, but computer is a complicated assembly which is highly hazardous substances such as lead, cadmium, mercury, Hexavalent chromium, plastics etc. This paper was presented the quantity of hazardous substances in the personal computer and the problem of its disposition-incinerating, landfilling, recycling. Also EPR which is the solution of e-waste was introduced.

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A Study on Electrochemical Characteristics Aluminum Multi Matrix Compound (Al-MMC) of Neutron Absorber Material

  • Lee, Jung Hwan;Lee, Yunju;Yoo, Seung Chang;Kim, Seunghyun;Kim, Ji Hyun
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.11a
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    • pp.179-180
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    • 2018
  • Al - MMC, used as a neutron absorber, shows pitting corrosion and/or galvanic corrosion in 3.5wt.% NaCl solution. If pitting corrosion penetrates the core, neutron absorption performance could be affected. Galvanic corrosion was observed between Al 5052 and Al 1070, and pitting corrosion was observed around $B_4C$.

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Strength, Absorption and Interfacial Properties of Mortar Using Waste Shells as Fine Aggregates (잔골재를 패각으로 치환한 모르터의 강도, 흡수율 및 계면 결합형태)

  • Moon, Hoon;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.6
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    • pp.523-529
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    • 2014
  • Large amounts of waste shells have been produced each year from shellfish raising industries located in Korean costal areas. Due to the limited space for the waste shell disposal, the related environmental problem has been a serious issue. It is believed that using the waste shells as a source of aggregate for mortar, concrete or bricks can be a good solution. In this research, possibility of utilizing waste shells as an aggregate of mortar is investigated. Waste shells of manila clam, cockle, clam, sea mussel, and oyster were properly crushed, sieved, and sorted to meet the requirements of the grading of standard fine aggregate. After that, the waste shells were used as partial and total replacement of the fine aggregate, and their absorption and 28-day compressive strengths of mortar were measured. In general, replacement of waste shells increased the absorption and decreased the strength. However, one specimen with cockle increased compressive strength as replacement ratio increased. Mortar with cockle of 50% and 100% replacement showed higher compressive strength than that of control mortar. This increase of compressive strength was found to be affected by the strong interfacial bonding properties of the cockle and a cement matrix.