• Title/Summary/Keyword: Waste products

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Rock Weathering and Geochemical Characteristics in the KURT (한국원자력연구소 지하처분연구시설(KURT)의 암석 풍화 및 지화학적 특성)

  • Lee, Seung-Yeop;Baik, Min-Hoon;Cho, Won-Jin;Hahn, Pil-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.4
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    • pp.321-328
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    • 2006
  • A basic research was conducted on the mineral weathering and geochemical characteristics in the KURT (KAERI Underground Research Tunnel), which was recently constructed at a site in KAERI. Some rock samples exposed during the KURT construction were examined using a microscope and chemical analysis for some micro-changes of the rocks caused by the chemical weathering. The weathered granite has some small and fine cracks around the rock-forming minerals. In particular, there are a characteristic weathering of feldspar mineral and a preferential leaching of Ca component from the mineral dissolution. In addition, by the dissolution of biotite containing $Fe^{2+}$ component there were iron-oxides precipitates as secondary products into the microcracks of around minerals. The results also show that the micro-cracks initiated from the mineral interior are extended and connected into the larger cracks along the grain boundary with the progress of the weathering. Thus, it is considered that some chemicals dissolved from the fresh rock would be involved in the formation of secondary minerals and migrate interacting with them.

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Feasibility about the Direct Measurement of 226Ra Using the Gamma-Ray Spectrometry (감마분광분석을 이용한 226Ra의 직접 측정방법에 대한 적용성 평가)

  • Ji, Young-Yong;Chung, Kun Ho;Lim, Jong-Myoung;Kim, Change-Jong;Jang, Mee;Kang, Mun Ja;Park, Sang Tae;Woo, Zuhee;Koo, Boncheol;Seo, Bokyun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.2
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    • pp.97-105
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    • 2014
  • In the case of the direct measurement of $^{226}Ra$ using a HPGe gamma-ray spectrometer, the interference between gammarays with 186.21 keV of $^{226}Ra$ and 185.7 keV of $^{235}U$ should be corrected to calculate the net peak area in the energy spectrum. In general, it is very difficult to conduct peaks stripping with difference of about 0.5 keV, although a HPGe with the superior resolution is applied and the maximum channels is applied to the spectrometer. In this study, several interference correction techniques in the direct measurement were surveyed to evaluate the feasibility for the measurement of $^{226}Ra$ using the gamma-ray spectrometery. Applying the interference corrections to the analysis of raw materials and by-products, the method validation for the direct measurement of $^{226}Ra$ was conducted by evaluating the measurement uncertainty, linearity, and range. As a result, the optimum method of the interference correction was selected by comparing with the indirect measurement of which progenies of $^{226}Ra$, such as $^{214}Pb$ and $^{214}Bi$, were analyzed in the secular equilibrium state.

Operating Parameters and Performance of Biotrickling Filtration for Air Pollution Control (대기오염물질 제어를 위한 생물살수여과법의 운전인자와 성능평가)

  • Won, Yang-Soo
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.474-484
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    • 2005
  • Biological treatment is a promising alternative to conventional air pollution control methods. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor compounds. They offer several advantages over traditional technologies such as incineration or adsorption. These include lower treatment costs, absence of formation of secondary pollutants, no spent chemicals, low energy demand and low temperature treatment. The most widely used bioreactor for air pollution control is biofilter, but it has several limitations. In the past years major progress has been accomplished in the development of vapor phase bioreactor, in particular biotrickling filters. Biotrickling filters are more complex than biofilters, but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. While the level of understanding of biotrickling filtration process for VOCs still remains limited, the evident success of biotreatment of VOC in air stimulated the pursue of acitve research. This paper presents fundamental and theoretical/practical aspect of air pollution control in biotrickling filter. Special emphasis is given to the operating parameters and the factors influencing performance for air pollution control in biotrickling filter.

Study on the Correlation between Air Emission Gas and Alternative Fuels Used in Cement Sintering Process (시멘트 소성공정에 사용된 대체연료와 대기배출가스간 상관관계 연구)

  • Choi, Jaewon;Baek, Ju-Ik;Kwon, Sang-Jin;Won, Pil-Sung;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.286-293
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    • 2020
  • In this study, we tried to verify the correlation of the amount of combustible industrial by-products, household waste used as fuels on cement sintering process and the amount of NOx, and CO, harmful components in the exhaust gas. The analysis uses coal as natural fuel, soft plastics (plastics with properties that tend to be scattered by wind, such as vinyls), hard plastics (plastics with properties that are not scattered by wind, such as PETs, wate rubbers), and reclaimed oils as alternative fuels. Utilizing the response surface analysis (RSM) technique using the process data of 2019, such as the fuel input and combustion temperature of a domestic A cement manufacturer's sintering facilities as independent variables, and the NOx, and CO emissions to the stack as dependent variables. Correlation was analyzed. As a result, it was confirmed that the impact on the emission material differs for each waste. In particular, it was analyzed that the hard plastics increase the CO emission but have an excellent effect of reducing NOx.

Investigation on Material Flow Diagram for PVC(poly vinyl Chloride) Profile Based Production, Generation, Recycling and Treatment (PVC재질 프로파일의 생산, 발생 및 재활용, 처리에 기반한 물질흐름도 검토)

  • Phae, Chae-Gun;Jung, Oh-Jin
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.129-140
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    • 2012
  • The objective of this study was to estimate the practical recycling rate of plastic products, so that the study was conducted to build material flow diagram for PVC profile. For this objective, product generation, waste generation and recycling status were investigated. Using collected and analyzed status data, analysis of material flow by product and building material flow diagram were conducted. As result of estimating the recycling rate by product, The sum of domestic demand was 525,448 ton and waste generation was 105,853ton in PVC flooring and profile. The sum of generation of recycling product and raw material was investigated to be 76,004ton(14.46%), which is higher compared to recycling obligation(8.5%) in 2009. To build the material flow diagram in the years(5~20years) ahead, prediction of future demand was based on the assumption that there will be no difference in annual generation of current and future. As the recycling rate of flooring and profile increases, it is estimated to reach 20% in 2013 according to the material flow diagram.

Strength Characteristics on Sulfuric Acid Corrosion of Recycled PET Polymer Concrete with Different Fillers (충전재 종류에 따른 PET재활용 폴리머콘크리트의 황산부식에 대한 강도 특성)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.499-504
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    • 2005
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete Is drawing a strong interest as high-performance materials in the construction industry Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems Posed by plastics and save energy. An objective of this paper is to estimate the damage of sulfuric acid, through investigating recycled PET polymer concrete, immersed at sulfuric acid solution for 84 days. As a result of testing, recycled PET PC, used $CaCO_3$ as filler, makes a problem of appearance and strength if they are exposed for long term at corrosion environment. On the other hand, recycled PET PC, used fly-ash as filler, had less effect on decrease in weight and strength. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.

Analysis for Water Vapour Adsorption and Desorption Performance of Waste Paper-Mulberry according to Particle Size Control (폐닥나무의 입도제어에 따른 흡·방습 특성 분석)

  • Jo, Ki-Sic;Kim, Tae-Yeon;Seo, Sung-Kwan;Lee, Oh-Kyu;Chu, Yong-Sik
    • Resources Recycling
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    • v.29 no.2
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    • pp.8-17
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    • 2020
  • In this study, adsorption and desorption characteristics of pulverized waste paper-mulberry pellet and bast fiber were measured to confirm the applicability to humidity control products. Paper-mulberry powder was classified by 710-355㎛, 355-100㎛, 100-45㎛ and less than 45㎛ and used in experiment. Specific surface area increased from 1.02㎡/g to 1.35㎡/g as the particle size decreased from 710㎛ to under 45㎛. Adsorption and desorption performance decreased in the order of 355-100㎛, 710-355㎛, 100-45㎛, less than 45㎛ and bast fiber, adsorption content on each particle sizes were 141.1g/㎡, 147.1g/㎡, 135.7g/㎡, 129.0g/㎡ and desorption content were 117.2g/㎡, 123.6g/㎡, 110.2g/㎡, 93.3g/㎡. As a result, adsorption and desorption performance of paper-mulberry powder were superior to those of the bast fiber and these phenomenon can be considered that it caused by pore distribution in pellet and damage of fiber.

A Sustainable and Viable Method to Recycle Oyster Shell Waste as an Alternative of Limestone in Limestone Calcined Clay Cement (LC3) (석회석 소성 점토 시멘트(LC3) 내 석회석 대체재로서 굴 패각의 친환경적인 재활용 방안)

  • Her, Sung-Wun;Suh, Heong-Won;Park, Jae-Yeon;Im, Su-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.219-226
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    • 2020
  • Over the last decades, great efforts have been devoted to reuse industrial wastes and by-products from various industries as supplementary cementitious materials in order to reduce carbon dioxide(CO2) emission by reducing the use of Portland cement in construction. Oyster shell waste, originating from the fishery industry, is available in huge quantities in certain areas, and is generally discarded or landfilled. In this study, we aimed to reuse oyster shell as an alternative to limestone in limestone calcined clay cement(LC3). The oyster shell calcined clay cement(OC3) paste were produced and were characterized via X-ray diffraction, isothermal calorimetry, compressive strength tests, and thermogravimetry. The results revealed that OC3 pastes exhibited similar strength development and reactivities by pozzolanic reaction with LC3, which implies that oyster shell could be used as a substitute for limestone in LC3.

Leaching Behavior of Gold from CPU chip Grinding Products in Iodide/Iodine Solution (Iodide/Iodine용액에서 CPU chip 분쇄물의 금 침출특성)

  • Jung, Insang;Joe, Aram;Choi, Joonchul;Song, Youjin;Park, Poongwon;Park, Kyungho;Lee, Sujeong;Park, Jaikoo
    • Resources Recycling
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    • v.25 no.1
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    • pp.3-9
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    • 2016
  • The leaching behavior of gold from waste CPU chip using Iodide/Iodine solution was studied. The direct leaching of gold with Iodide/Iodine solution for CPU chip under the size of 150 mesh showed leaching ratio of 20%. It was assumed that the copper film was produced on the gold particle during grinding process and the copper film prevents lodine/Iodide solution from contacting with leachable gold. Meanwhile, the extraction of gold was improved to 90% by pretreatment process with $HNO_3$ solution. In order to explain the result, EDS and ICP analysis for the leaching residue were conducted. It was found that the copper coated on the surface of the gold particle was removed about 80% by $HNO_3$, resulting in the increment of gold leaching rate.

Preparation of Instant Powdered Soup Using Oyster Wash Water and Its Characteristics (굴 세척액을 이용한 인스턴트 분말 수프의 제조 및 특성)

  • Kim, Jin-Soo;Heu, Min-Soo
    • Korean Journal of Food Science and Technology
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    • v.33 no.5
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    • pp.534-539
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    • 2001
  • To utilize oyster cannery processing waste water effectively, this study was carried out to prepare instant powdered soup using oyster wash water. Instant powdered soup from oyster hot-water extracts (HWE) was prepared by mixing oyster spray-dried hot-water extracts (15 g) with table salt (5 g), cream powder (19 g), milk replacer (12 g), wheat flour (20 g), corn flour (15 g), starch (5 g), glucose (7.5 g) and onion powder (1.5 g). In preparing instant powdered soup from oyster wash water (OWW), powder from oyster spray-dried wash water instead of the spray-dried hot water extracts, was added and other additives were added in proportion to those in the HWE. The OWW consists mainly of carbohydrates (71.1%). It was not different from the instant powdered soup from hot-water extracts. The volatile basic nitrogen, vaible cell counts, coliform group of instant powdered soup from oyster wash water contains 29.4 mg/100g, $4.6{\times}10^4\;CFU/g$, <18 MPN/100g, respectively and its water activity has 0.246. So it was a hygienically safe and conservable instant food. The main fatty acid of OWW was 16 : 0 and 18 : 1n-9. Its chemical score of protein was 59.4% and its main inorganic matter was iron. According to a sensory evaluation, in contrast to the HWE, the OWW had a slightly lower aroma but better taste. It was concluded from the above chemical and sensual evaluation that the oyster wash water can be used as a flavor enhancer for instant powdered soup.

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