• Title/Summary/Keyword: Waste polyethylene

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Morphology and Mechanical Properties of Waste PVC Blends (I) -Morphology and Mechanical Properties of Waste PVC/PE Blends (폐 PVC계 고분자 블렌드의 구조 및 물성 연구(I) -폐 PVC/PE고분자 블렌드의 모폴로지 및 물성)

  • 박재찬;원종찬;최길영;이재흥;조성만;김명기
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.37-44
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    • 2002
  • The polymer blends of waste polyvinyl chloride (RPVC) and waste polyethylene(RPE) were prepared by melt mixing, and their morphology and tensile properties were evaluated after the copolymers having an ethylene group in backbone and ester group in side position were added as comptatibilizers. The blend compositions were varied as follows ; RPVC/RPE 85/15 wt%, where RPVC formed a continuous phase : 50/50, mid composition : 15/85, RPE a continuous phase. The blends revealed a very low compatibility between component polymers because they showed domain sizes greater than $10\mu\textrm{m}$ over all compositions, especially the worst compatibility around mid composition. The blends showed higher compatibility when ethylene vinylacetate copolymer(EVA) and ethylene ethylacrylate-graft-methyl methacrylate copolymers(EEA-MMA) were added.

CATALYTIC DEGRADATION OF WASTE HIGH-DENSITY POLYETHYLENE INTO LIQUID PRODUCT

  • Lee, Kyong-Hwan;Shin, Dae-Hyun;Suh, Jeong-Kwon
    • Environmental Engineering Research
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    • v.10 no.2
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    • pp.54-61
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    • 2005
  • Liquid-phase catalytic degradation of waste high-density polyethylene (HDPE) over ZSM-5 (powder type (PW)) and ZSM-5+binder (granule type (GR)) has been investigated with a stirred semi-batch operation at 400°C. Two ZSM-5 catalysts with a different crystal size were synthesized and also each ZSM-5 (25%) Catalyst was mixed with a same binder (kaolin: silica sol: alumina = 55%:10%:10%). The performance of prepared catalysts that has different physicochemical properties was discussed with the cumulative amount distribution, molecular weight distribution and also paraffin, olefin, naphthene and aromatic (PONA) distribution in liquid product. These liquid product quality and distributions were changed depending on the physicochemical properties of the catalyst. Moreover, the characteristic of ZSM-5 in the catalyst was strongly influenced on the activity and PONA distribution in liquid product.

Effects of Green Tea (Camellia sinensis) Waste Silage and Polyethylene Glycol on Ruminal Fermentation and Blood Components in Cattle

  • Nishida, T.;Eruden, B.;Hosoda, K.;Matsuyama, H.;Nakagawa, K.;Miyazawa, T.;Shioya, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.12
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    • pp.1728-1736
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    • 2006
  • The effects of green tea (Camellia sinensis) waste silage and supplemental polyethylene glycol (PEG) on rumen fermentation and blood components were studied in cattle. Six Holstein steers were fed three diets in a 3${\times}$3 Latin square design, replicated twice. One diet was a control with no added silage, and the other two diets were supplemented (20% of the dry matter) with green tea waste silage either with (PEG) or without PEG (tea). Most of the fermentation parameters including major volatile fatty acids (VFA) were not affected by the diet treatments. The concentrations of high density lipoprotein cholesterol in the PEG group and urea nitrogen in the tea and PEG groups were greater than those in the control before morning feeding. The plasma 6-hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid equivalent concentration was not different before morning feeding, but 3 h after morning feeding, its concentrations in both the tea and PEG groups were higher than in the control. Although the concentration of plasma vitamin A in the animals was not affected by feeding green tea waste silage, the concentrations of plasma vitamin E were significantly higher in the tea and PEG groups than in the control, both before and 3 h after morning feeding. The results from the present study suggest that feeding diets containing 20% of the dietary dry matter as green tea waste silage to Holstein steers has no negative impact on their ruminal fermentation, and increases their plasma antioxidative activity and concentration of vitamin E.

Morphology and Mechanical Properties of Recycled PVC Blends (III) - Morphologies and Mechanical Properties of Recycled PVC/PE Blends with Different Kinds of Compatibilizers and Mixing Conditions (폐폴리(염화 비닐)계 고분자 블렌드의 구조 및 물성 연구(III) -상용화제의 종류 및 혼합 조건에 따른 폐폴리(염화 비닐)/폴리에틸렌 고분자 블렌드의 형태학 및 물성)

  • 유영재;박재찬;원종찬;최길영;이재흥
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.468-477
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    • 2004
  • The polymer blends of waste poly(vinyl chloride) (RPVC) and waste polyethylene (RPE) were prepared by melt mixing. Various ethylene-vinyl acetate copolymers (EVA) and ethylene-methacrylic acid Na salt copolymer (ionomer) were used as compatibilizer. Their morphologies and mechanical properties were evaluated as a funtion of mixing sequence and time. EVA with high vinyl acetate contents showed a rapid increment of tensile properties when small amount was added. Tensile properties of the blends were gradually increased with the addition of ionomer. Morphologies of RPVC/RPE blends were analyzed by scanning electron microscopy. FT-IR data showed that EVA was a good compatibilizer in RPVC/RPE blend compared to ionomer. Mechanical properties of the blends were highly enhanced when RPVC and compatibilizer were mixed and first RPE was added later.

Evaluation of Asphalt Mixtures Using Waste vinyl (폐비닐 아스팔트 콘크리트 혼합물의 특성(구조 및 재료 \circled2))

  • 김광우;이상범;도영수
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.259-265
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    • 2000
  • This study is a fundamental research for recycling waste vinyl in asphalt concrete mixture for roadway pavement. The mixing method and proper content of waste polyethylene(PE) film were determined through preliminary mix design. This study was performed mix designs using 2 type graduations of aggregate and used two types waste PE film. The asphalt concrete mixture was satisfied with the specification of the Ministry of Construction and Transportation. Its showed that dense grade asphalt concrete mixture containing waste vinyl were higher performance in comparision to other mixtures(common dense grade mixture and gap grade mixtures). From results of this study, it was confirmed that addition of waste vinyl improved on quality of asphalt concrete mixture.

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Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams (폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.316-325
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    • 2003
  • The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

A Study on the Mechanical and Rheological Properties of the Recycled Polyethylene Composites with Ground Waste Tire Powder (재생 폴리에틸렌/폐타이어 분말 복합체의 기계적 특성 및 유변학적 특성에 관한 연구)

  • Kye, H.;Shin, K.;Bang, D.
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.97-107
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    • 2006
  • The recycled polyethylene composites with various ratio of ground waste tire powder were manufactured by using a fully intermeshing co-rotating twin screw extruder for the reuse of waste tire scrap. In this investigation, the ground waste tire powders (GWTP) were blended with virgin HDPE and recycled polyethylene in the weight ratio of 0 to 50 wt.%. Mechanical properties such as tensile strength, elongation at break and impact strength were measured by using ASTM standard. The experimental results for the various composite showed that the tensile strength of composites decreased with increasing GWTP ratio, while elongation at break increased with the amounts of GWTP. On the other hand, the impact strength for the three kinds of composites showed maximum at the 30 wt.% of GWTP and then decreased. Morphology of the fracture surface tends to be rough with increasing waste tire powder content. Rheological properties were investigated by measuring the shear viscosity against shear rates and softening temperatures. They showed that melt viscosity of rubber composites in this study subsequently increased with increasing GWTP content as a result of increase of flow resistance against external stress and followed a Power-law behavior.

Activation Reduction Method for a Concrete Wall in a Cyclotron Vault

  • Kumagai, Masaaki;Sodeyama, Kohsuke;Sakamoto, Yukio;Toyoda, Akihiro;Matsumura, Hiroshi;Ebara, Takayoshi;Yamashita, Taichi;Masumoto, Kazuyoshi
    • Journal of Radiation Protection and Research
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    • v.42 no.3
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    • pp.141-145
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    • 2017
  • Background: The concrete walls inside the vaults of cyclotron facilities are activated by neutrons emitted by the targets during radioisotope production. Reducing the amount of radioactive waste created in such facilities is very important in case they are decommissioned. Thus, we proposed a strategy of reducing the neutron activation of the concrete walls in cyclotrons during operation. Materials and Methods: A polyethylene plate and B-doped Al sheet (30 wt% of B and 2.5 mm in thickness) were placed in front of the wall in the cyclotron room of a radioisotope production facility for pharmaceutical use. The target was Xe gas, and a Cu block was utilized for proton dumping. The irradiation time, proton energy, and beam current were 8 hours, 30 MeV, and $125{\mu}A$, respectively. To determine a suitable thickness for the polyethylene plate set in front of the B-doped Al sheet, the neutron-reducing effects achieved by inserting such sheets at several depths within polyethylene plate stacks were evaluated. The neutron fluence was monitored using an activation detector and 20-g on de Au foil samples with and without 0.5-mm-thick Cd foil. Each Au foil sample was pasted onto the center of a polyethylene plate and B-doped Al sheet, and the absolute activity of one Au foil sample was measured as a standard using a Ge detector. The resulting relative activities were obtained by calculating the ratio of the photostimulated luminescence of each foil sample to that of the standard Au foil. Results and Discussion: When the combination of a 4-cm-thick polyethylene plate and B-doped Al sheet was employed, the thermal neutron rate was reduced by 78%. Conclusion: The combination of a 4-cm-thick polyethylene plate and B-doped Al sheet effectively reduced the neutron activation of the investigated concrete wall.

The effects of half-section waste tire reinforcement on pipe deformation behavior

  • Erenson, Can;Terzi, Niyazi Ugur
    • Geomechanics and Engineering
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    • v.30 no.6
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    • pp.517-524
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    • 2022
  • Every year, millions of waste tires are discarded across the world. Storage of waste tires presents many problems such as fire threats, epidemics, and non-economic factors. Furthermore, the disintegration process of waste tires is not economical or practical due to its time-consuming, and disposal requirements. In this study, half-section waste tires (HSWTs) were integrated with high-density polyethylene (HDPE) pipes under different relative density conditions. The main aim of the study was to reduce the deformation values of embedded HDPE pipes in sandy soil and to evaluate the soil-pipe interaction. In comprehensive laboratory tests, half-section waste tires were integrated in two different ways: in the middle of the pipeline and along the pipeline. Accordingly, it was concluded that the effectiveness of waste tires reduces the deformation and bending moment values in the critical regions of pipes. As a result of reinforcement in the mid-point of the pipe defined as the most critical region, 52% and 36% less deformation was observed in the crown and springlines of the pipe, respectively. In addition, the bending moment values for the same critical section were determined to be 40% less in the crown and 28% less in the springline regions of the pipe.