• Journal of the Korea Institute of Building Construction
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• v.14 no.1
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• pp.94-101
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• 2014

Approximately 240,000 tons of waste shells are produced annually in the south and west coast of South Korea. Some of these waste shells (oyster, cockle) are recycled as seeding collector and fertilizer, but most are dumped illegally near the coast. One of the alternative solutions that can economically utilize a large amount of these waste shells is to apply them to the production of construction materials. In this research, the basic physical properties of waste shells such as oyster, cockle, clam, manila clam were investigated, and were used to prepare cement mortar with a 25% replacement ratio of sand. According to the results, the 28 day compressive strength of cement mortar with cockle and manila clam shells was similar to that of plain cement mortar. The compressive strength decreased by about 18% when clam was used. However, the cement mortar with oyster shell showed about a 35% reduction in 28-day compressive strength, and two times the absorption capacity of plain cement mortar. The reduction in compressive strength and the increase in absorption capacity were mostly associated with the porous nature of the oyster shell.

• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.3
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• pp.89-96
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• 2000

Waste oyster shell was used to study the applicability on anaerobic composting of garbage. Experiment was conducted with five anaerobic reactors. After garbage and compost for inoculation were mixed, waste oyster shell was added into mixed waste in mesophillic temperature for 60 days with 30%, 60% respectively. The amount of produced methane gas, gas composition, organic removal efficiency and pH were measured. Result showed that the amounts of produced gas were 0.62 l /g-VS in R-1, 0.63 l /g-VS in R-2, 0.16 l /g-VS in R-3, 0.75 l /g-VS in R-4, 0.21 l /g-VS in R-5 and the amounts of produced methane gas were 0.32 l /g-VS in R-1, 0.37 l /g-VS in R-2, 0.04 l /g-VS in R-3, 0.42 l /g-VS in R-4, 0.05 l /g-VS in R-5. Proportion of mathane gas which determines the efficiency of anaerobic composting was over 55%. pH were 6.0~8.0 in R-2 and R-4 which contained 30% of waste oyster shell and pH were increased over 8.5 in R-3 and R-5 which contained 60% of waste oyster shell. Since pH were so high and it had a negative effect on microbial growth, anaerobic reaction were not well operated in R-3 and R-5.

• Journal of Environmental Health Sciences
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• v.26 no.3
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• pp.43-49
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• 2000

A laboratory experiments were performed to investigate the effects of several factors on the phosphorus removal by waste oyster shells. The waste oyster shells used in this experiments were crushed particle, calcined particle and extracted solution. A higher efficiencies of phosphorus removal were observed, when a particle size of crushed and calcined particle were smaller. The effluent concentration of phosphorus was around 1.6mg/ι in continuous column experiment which packed with crushed particle of waste oyster shell at the influent concentration of PO4-P of 10 mg/ι. But the clogging of column occurred with increasing of throughput volume of influent. The efficiency of phosphorus removal increased with increasing of dosage amount of crushed, calcined particle and extracted solution. When the calcined particle which contained only about 1/10~1/100 of crushed particle was used, the efficiency of phosphorus removal was correspondingly equivalent to the removal efficiency obtained from crushed particle. The efficiency of phosphorus removal by calcined particle after 9 runs repeated use was decreased about 21.5% as that of the first run. The removal efficiency of 100% could have been achieved at the HRT of 18 hours during the continuous treatment of phosphorus by the solution extracted from calcined particle.

• Clean Technology
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• v.24 no.4
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• pp.315-322
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• 2018

Industrial use of waste oyster shells is limited because of requiring excessive energy for converting natural oyster shells in the form of calcium carbonate ($CaCO_3$) into calcium oxide (CaO) for this purpose. This study aimed to develop energy-saving process for producing solidifying agent using waste oyster shells for backfill materials. It was suggested that oyster shells were converted to calcium sulfates which were mixed with sodium hydroxide solution and red clay, forming solid specimen. The optimal concentrations of sulfuric acid for sulfation of oyster shell and sodium hydroxide to generate calcium hydroxide ($Ca(OH)_2$), were determined. Unconfined compressive strength of solid specimen increased with increasing the content of solidifying agent while it increased also with increasing ratio of natural oyster shells to coal ash. The result clearly demonstrates that solidifying agent consisting of sulfuric acid-treated oyster shell, coal ash, and sodium hydroxide solution, can be effectively utilized for preparing backfill materials using natural oyster shell and coal ash. Sulfuric acid-treated oyster shell-based solidifying agent has not been previously developed and will contribute to broaden industrial application of waste oyster shells.

• Journal of the Korean Geotechnical Society
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• v.22 no.11
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• pp.143-149
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• 2006

An experimental study was carried out to investigate the stabilizing capability of oyster shell binder, which was developed using waste oyster shell inducing environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this paper is to compare stabilinzing capability of oyster shell binder and cement binder with treated soils. For this, a series of compressive laboratory tests were peformed to evaluate strength characteristics of treated soils by both oyster shell binder and cement binder with varing water content of dredged soils, different mixing rates of binder and curing days. Based on test results, eco-friendly binder manufactured by oyster shells showed more stabilizing capacity than cement binder and is estimated as good resource materials for soft soil improvements.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.439-444
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• 2008

The oyster shell adsorbents were prepared by steam activation method to evaluate their adsorption characteristics. Washed and pulverized waste oyster shells were prepared by steam activated process in converter at the temperature range of about $700{\sim}800^{\circ}C$ after carbonized at the range of $600{\sim}1000^{\circ}C$. The shell carbonized at $1000^{\circ}C$ showed the best performance among those of other temperature ranges. Also, comparison between gas and liquid phase adsorption was performed to verify adsorbent possibility of waste shell. In case of gas phase, the adsorbent showed lower performance than existing commercial adsorbents. On the other hand, the liquid phase, they showed similar adsorption performance to commercial adsorbents when benzene was used.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.148-149
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• 2013

Recently, the construction industry in South Korea, has experienced many difficulties in lack of supply with construction materials. Since waste shells can be possibly used as replacement materials of fine aggregate, the successful application can resolve, to some extent at least, the economic problems and environmental problems. In this research, the basic physical properties of the mortar which was used as fine aggregate substitute (clam, cockle, manila clam, oyster) were evaluated. According to the experimental results, the absorption rate and compressive strength of samples with various shells were equivalent to that of plain mortar. The mortar which replaced 25% of oyster shell with sand showed approximately 30% lower compressive strength and twice as much absorption as plain mortar. It was found that waste shells can be used as replacement materials of fine aggregate, but the oyster shell requires further experimental works in order for its successful application.

• Journal of Environmental Science International
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• v.15 no.11
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• pp.1053-1059
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• 2006

This study was performed to investigate the possible uses of waste sludge for the removal of heavy metal ions. The adsorption experiments were conducted with wastes such as sewage treatment sludge, water treatment sludge and oyster shell to evaluate their sorption characteristics. Heavy metals selected were cadmium, copper and lead. in the sorption experiments on the sewage treatment sludge, water treatment sludge, oyster shell and soil, sorption occurred in the beginning and it reached equilibrium after 40 minutes on the oyster shell and 4 hour on the sewage treatment sludge and water treatment sludge. Results of Freundlich isotherms indicated that sewage treatment sludge could be properly used as an adsorbent for heavy metals and sorption strength of heavy metals was in the order of Pb > Cu > Cd. In the influence of pH on the adsorbents, sorption rate was more than 80% in pH 4 and most of heavy metals were adsorbed in pH 9. Adsorption rate of Cd decreased with decreasing pH and then adsorption rate of Cu was lower in soil.

• Journal of Energy Engineering
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• v.27 no.3
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• pp.48-56
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• 2018

The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.1-6
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• 2016

In this year, Koreans have a shortage in agricultural and drinking water due to severe algal blooms generated in major lakes. Waste oyster shells were obtained from temporary storage near the workplace at which oysters were separated from their shells. Heating ($1000^{\circ}C$ for 1 h in air) was employed to convert raw oyster shell powders into calcium oxide powders that reacted efficiently with phosphorus and nitrogen to remove algal blooms from eutrophicated wastewater. As the dispersed amount of heated oyster shell powders was increased, water clarity and visual light penetration were improved. Coagulation, precipitation and carbonation process of the heated oyster shell powders in a water purifier facilitated removal of eutrophication nutrient such as phosphorus and nitrogen, which is both beneficial and economically viable. $CO_2$ implantation by carbonation treatment not only produced thermodynamically stable CaO in oyster shells to derive precipitated calcium carbonate (PCC) but also accelerated algal removal by activation of coagulation and precipitation process. The use of oyster shell powders led to a mean reduction of 97% in total phosphate (T-P), a mean reduction of 91% in total nitrogen (T-N) and a maximum reduction of 51% in chemical oxygen demand (COD), compared with the total pollutant load of raw algal solution. Remarkable water quality improvement of algal removal by heated oyster shell powders and PCC carbonation treatment will allow utilization as water resources to agricultural or industrial use.