• Title/Summary/Keyword: Waste liquid

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Study on Oil Production from Pyrolysis of Mixed Plastic Waste Using Multidimensional Chromatography (Multidimensional Chromatography/Mass Spectrometry를 이용한 혼합 폐플라스틱의 열분해 오일 특성 평가에 관한 연구)

  • 김석완
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.375-382
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    • 2002
  • The total hydrocarbon distribution of oil products obtained from the pyrolysis of four kinds of mixtures of polyethylene-polystyrene waste has been studied by multidimensional chromatography(high performance liquid chromatography followed by capillary gas chromatography)/mass spectrometry. Saturated, unsaturated and aromatic hydrocarbons in oil products were selectively pre-separated according to structural groups by HPLC and the weight fraction of each group was estimated by analysis of each component using GC-FID response factors. The hydrocarbon distribution of aliphatic fraction consists of $C_{5}$ to $C_{25}$ saturated and unsaturated hydrocarbons. And that of aromatics fraction consists of benzene, toluene, xylene, styrene, propenyl benzene, naphthalene, and some of derivatives. Pyrolysis temperature did not affect the ratio of total weight fraction of aliphatic over aromatic hydrocarbon distribution in case of PS only and PE-PS mixtures (1:1 and 1:4 wt. ratio) as a feed while affected the ratio of total wt. fraction in case of PE only. The optimal temperature for the maximum oil production was $600^{\circ}C$ for pyrolysis of PS and 1:1 and 1:4 mixtures of PE and PS. The optimal condition for aromatic recovery was $600^{\circ}C$ with 1:1 mixture of PE and PS. In this condition, aromatic was produced up to 90% of total oil product. The maximum yield of toluene, xylene, styrene, and propenyl benzene were 8.6, 8.9, 51.0 and 7.4% of feed for pyrolysis PS at $700^{\circ}C$, respectively. However, only 1.3% naphthalene was recovered at $700^{\circ}C$ with 1:1 PE:PS(by wt.).

Numerical Study of the Post Combustion Chamber of Grate Type Incinerator in Daejon 4th Industrial Complex (대전 4공단 소각로 후연소로 모델 연구)

  • Kim Hey-Suk;Shin Mi-Soo;Jang Dong-Soon;Park Byung-Soo;Um Tae-In
    • 한국전산유체공학회:학술대회논문집
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    • 2002.10a
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    • pp.133-138
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    • 2002
  • A 3-D axisymmetric computer program is developed to predict the NO behavior in SNCR system for the stoker incinerator with the waste treatment capacity, 200ton/day. To this end a turbulent reacting flow field calculation is made using proper assumption and empiricism. The stoker bed is assumed to be a homogeneous waste-volatilized gaseous state. The initial composition or reactants are assumed based on the data of the ultimate analysis. Turbulent is resolved by k-e model and turbulent reaction is handled by eddy-breakup model harmonized with empirical chemistry data for gaseous combustion, NO and urea reaction. The liquid droplet is traced by Lagrangian method incorporated by aerodynamic drag, Coriolis and crntrifugal forces. Radiation is treated by sensible heat loss model. Calculation results are in good agreement with experimental data at the outlet of post combustion chamber in Daejon 4th industrial complex. The flue gas shows the temperature range of $900\sim1000^{\circ}C$, velocity of 5m/s and NO concentration of 140ppm at the exit while the measured temperature, flue gas velocity and NO concentration are $967^{\circ}C$, $3\sim4m/s$ and $100\sim200ppm$respectively. Using the developed computer program a parametric study has been made with the variation of heat content of waste, castable length and SNCR variables for the determination of proper injector location. In general, the calculated results are consistent and physically acceptable.

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The Properties of Livestock Waste Composts Tea Depending on Manufacturing Method and Their Effect on Chinese Cabbage Cultivation

  • Jang, Jae-Eun;Kang, Chang-Sung;Park, Jung-Soo;Kim, Sun-Jae;Kim, Hee-Dong
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.8-14
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    • 2015
  • Livestock waste compost tea is a liquid extract of compost obtained by mixing livestock compost. In this study, some chemical and microbiological characteristics of compost tea depending on the kind of raw materials used were examined, and several experiments to investigate the practical effects on Chinese cabbage cultivation were conducted. This experiment showed that livestock composts needed to be added into aerated water at the ratio between 1:100 and 1:10 (1 part compost to 10~100 parts water) to produce the high quality compost tea. Compost teas must be aerated more than 24 to 48 hours to be able to support aerobic organisms. In cultivation test with compost teas, swine manure compost teas were made by the extracting ratio of 50x, in the aerated condition for 24 hours in water and oil cake in the extracting ratio of 100x were added as supplements. Following the input of oil cake, the concentration of nitrogen and aerobic bacteria increased. Another experiment was conducted to determine the effect of different swine manure compost teas on plant growth and yield of Chinese cabbage. The fresh yield of Chinese cabbage was higher in the fertigated plots by compost tea with oil cake compared to those of N, $P_2O_5$, $K_2O$ fertilization plot with chemical fertilizer by soil test recommendation (Fert. NPK). The effect of compost tea on growth of Chinese cabbage was largely attributable to the increased number of microorganisms as well as nutrients.

Experimental Validation on Performance of Waste-heat-recovery Boiler with Water Injection (물분사 폐열회수 보일러의 효용성에 대한 실험적 검증)

  • Jaehun Shin;Taejoon Park;Hyunseok Cho;Junsang Yoo;Seoksu Moon;Changeon Lee
    • Journal of ILASS-Korea
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    • v.28 no.1
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    • pp.43-48
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    • 2023
  • The waste-heat-recovery boiler with water spray (HR-B/WS) applies the heat exchange between the inlet air and exhaust gas with the water spray into the inlet air. The evaporation of water in the inlet air promotes heat recovery from the exhaust gas so that thermal efficiency can be improved by the enhanced condensing effect. The NOx emission can also be reduced by lowering the flame temperature due to the dilution effect of the water. In this study, the validity of this concept is examined by the practical boiler test performed with a 24 kW condensing boiler under the full load condition according to the water injection amount. The theoretical amount of water injection is calculated under the assumption of full evaporation of the sprayed water, which is calculated as 50 g/min. Since the injected water cannot evaporate fully in the actual system, the maximum water spray amount is set as 100 g/min. The results showed that the water injection can increase the thermal efficiency up to 95.59% and reduce NOx and CO emissions simultaneously to 8.9 ppm and 35 ppm at 0% of O2. Although the heat energy loss increased due to the unevaporated water, the increase in water injection amount caused higher thermal efficiency due to the increased amount of the evaporated water.

Practical Radiation Safety Control: (II) Application of Numerical Guidance for the Discharges of Radioactive Gaseous and Liquid Effluents (방사선안전관리 실무: (II) 배기중 및 배수중 배출관리기준의 적용)

  • Kim, Hyun Kee
    • Journal of Radiation Protection and Research
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    • v.39 no.1
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    • pp.61-64
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    • 2014
  • Radioactive materials are in use and have many applications from the generation of electricity to the purposes of research, industry and medicine such as diagnosis and therapy. In the course of their use some of radioactive substances may be discharged into the environment from facilities using the unsealed radioactive materials, which are main artificial sources occurring the public exposure. Discharges are in the form of gases, particles or liquids. This paper provides procedures to estimate the level of the public exposure based on the conservative assumptions and simple calculations in the facility using unsealed liquid sources. They consist of two processes; (1) to calculate maximum concentration of gaseous effluents discharged through the exhaust pipe and average concentration of liquid effluents discharged through the drain of the storage tank, (2) to compare each of them to numerical guidances for the discharges of radioactive gaseous and liquid effluents mentioned in the related notification. For this purpose followings are assumed properly; daily usage, form and dispersion rate of radionuclides, daily amount of radioactive liquid waste and exhaust and drainage equipment. The procedures are readily applicable to evaluate environmental effects by planned effluent discharges from facilities using the unsealed radioactive materials. In addition they may be utilized to obtain practical requirements for radiation safety control necessary for the reductions of the public exposure.

The Development of Hemodialysis System Based on Embedded System (임베디드 시스템 기반의 혈액 투석기 시스템의 개발)

  • Ji, Jung-Ho;Lee, Kyoung-Joung;Kim, Young-Ho;Park, Kwang-Li
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.51 no.11
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    • pp.521-527
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    • 2002
  • The Hemodialysis system is the device for the patients who have suffered from end stage renal failure as the kidney which removes the waste products in a human body. The existing hemodialysis is based on a 8-bit micro-controller and it is not a touch-screen type but a manual type. This paper is focused on hemodialysis system based on high control and expension embedded system. The whole system consists of main control unit and sub control unit(dialysis control unit, blood control unit, monitoring control unit, networking unit). The dialysis control unit, blood control unit, monitoring control unit are processed by 3 microcontrollers and network unit is for monitoring a renal failure patient's condition. For the evaluation of the system performance, the saline was pured into blood unit and then water removal rate, conductivity and temperature of hemodialysis liquid were measured 10 times in an each state suing the UF pump in the fluid unit varing the quantity of saline to 1000cc, 2000cc, 3000cc and 4000cc. As a result, the rates of water removal are 98.6% in condition of 000cc saline, 96.9% in 2000cc, 98.9% in 3000cc and 98.3% in 4000cc. The conductivities of hemodialysis liquid are 99.6% in the first to third condition and 99.7% in the forth condition. The temperatures of hemodialysis liquid are 99.8% in the first to third condition and 99.6% in th forth condition.

Effect of ultrasonication, light and liquid smoke treatment on germination of lettuce seeds

  • Park, Sunyeob;Kim, Young Ae;Kim, Min Geun;Kim, Du Hyun
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.217-217
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    • 2017
  • Seed priming leading to improved emergences, germination speed and uniformity under unfavorable conditions without loss of longevity are the best level of techniques. We studied the possibility to obtain primed seed with reduced mean germination time (MGT) and uniformity but with simple, fast and effective methods. The experiments were carried out at $15^{\circ}C$ for 16 hours with priming treatment. To compare the effects of each treatment, we used 200mM $CaCl_2$ priming or hydro priming or no imbibition after ultrasonication or red light treatment. The light treatment was performed by irradiating 2000 lux of red light for 15, 30, 60, and 120 minutes. Addition, in order to investigate the effect of the priming solution, treated at 200mM $CaCl_2$ for 8 hours. Ultrasonication treatment was performed for 5, 10, and 20 minutes at exposures of 13.0, 17.3, and 21.6 kHz during priming. For liquid smoke (LS) treatment, seed soaked in 0%, 0.5%, 1.0%, 5.0% and 10.0% of diluted water and 200mM $CaCl_2$ solution. After each treatment, the seeds were dried to moisture content ranged 5-8% at $25^{\circ}C$ for 24 hours. The effect of seed treatment was evaluated with germination percentage (GP), MGT, germination index(GI), germination rate(GR), Germination Uniformity(GU) and heath seed percentage(HS). For several factors tested, we found that the desired germination improvement could be obtained by treating the seed with ultrasonication at 17.3 kHz for 5 minutes in water or red light exposure at 2000 lux for 120 min in water that resulted very similar to those used to 200mM $CaCl_2$ priming for 16 hrs. However, LS treatment showed no improvement in all diluted solution. Therefore, the methods applied ultrasonication and red light treatment showed high potential for fast and easy treatment avoiding pollution of salt solution waste.

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An application of the electrostatic spray technology to increase scrubbing efficiency of SO$_{2}$ emitted from thermal systems (열시스템에서 생성된 SO$_{2}$ 가스의 배출저감을 위한 정전기 분무 원리의 응용)

  • Jeong, Jae-Yun;Byeon, Yeong-Cheol;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.8
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    • pp.1068-1076
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    • 1997
  • Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

Aerobic Liquid Fermentation of Food Wastes by Using Yeast (효모에 의한 남은 음식물의 호기성 액상발효)

  • Lee, Ki-Young;Yu, Sung Jin;Yu, Seung Yeung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.4
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    • pp.147-152
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    • 2000
  • For the probiotic feed production from residual food waste by using the yeast Kluyveromyces marxianus, aerobic liquid fermentation was attempted at $35^{\circ}C$. After grinding finely, optimal fermentation conditions of the substrate was investigated in shaking incubator. By controlling water content yeast growth was studied at each different solid content of 5, 10 and 15% respectively. The most active growth of the yeast was shown at 10%. For the stimulation of the cell growth, mixed culture with Aspersillus oryzae was conducted in a 2 litre-jar fermenter. As the results, the yeast growth rate was increased, but the maximum viable cell count amounted was slightly higher as $3.5{\times}10^9/ml$ than single culture.

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A Study on Improvement of Performance of Absorber in Absorption Heat Pump (흡수열펌프에서 흡수기의 성능 개선 연구)

  • Min, Byong-Hun
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.338-344
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    • 2008
  • The improvement of energy conservation is mandatory to decrease consumption of fossil fuels and to minimize negative impacts on the environment which originates from large cooling and heating demand. The absorption heat pump technology has a large potential for energy-saving in this respect. Absorption heat pump is a means to upgrade waste heat without the addition of extra thermal energy. The higher performance of absorber is of great importance for absorption heat pump cycle. In this study, in order to improve the performance of absorber, the absorber of tangential feed of a liquid phase with spiral tube has been investigated using methanol-glycerine as a working fluid. The spiral tube and tangential feeding generate the turbulence into the liquid flow while increasing the mass and heat transfer coefficients. The simultaneous heat and mass transfer were found to take place in a liquid turbulent film in the absorber with the spiral tube during the process of gas absorption. By calculating mass and heat transfer coefficients by measurement of the concentration and the temperature of each position in the absorber, the entrance was found to be more effective in enhancing mass and heat transfer.