• Title/Summary/Keyword: Waste gas

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온실가스 배출량 산정 방법에 따른 N2O 배출량 비교 (Comparison of N2O Emissions by Greenhouse Gas Emission Estimation Method)

  • 강소영;조창상;김승진;강성민;윤현기;전의찬
    • 한국기후변화학회지
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    • 제6권3호
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    • pp.175-184
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    • 2015
  • In this study GC and PAS were used to calculate $N_2O$ concentration of exhaust gas from Wood Chip combustion system. Fuel supplied to the incinerator was collected and analyzed and then the analysis result was used to calculate $N_2O$ emissions. Tier 3 and Tier 4 Method were used to calculate the $N_2O$ emissions. Plant's Specific emission factor of $N_2O$ by Tier 3 Method was 0.35 kg/TJ, while default emission factor of Wood?Wood Waste proposed by 2006 IPCC G/L was 4 kg/TJ. So the $N_2O$ emission factor of this study was 3.65 kg/TJ lower compared to the IPCC G/L. The total emissions calculated by Plant's specific emission factor was 4.22 kg during the measuring period, but by Tier 4 Method it was 7.88 kg. This difference in emissions was caused by the difference of continuous measuring and intermittent sampling. It would be necessary to apply continuous measuring to calculate emissions of $Non-CO_2$ gas whose the density distribution is relatively high. However currently, according to the target management guideline of greenhouse gas and energy, the continuous measuring method to calculate greenhouse gas emission is applied only to $CO_2$. Therefore for reliable greenhouse gas emission calculation it would be necessary to apply continuous measuring to calculate $Non-CO_2$ gas emission.

Application of Biofilter Using Fibril-form Matrix for Odor Gas Removal

  • Lee, Gwang-Yeon;Jeong, Gwi-Taek;Lee, Kyoung-Min;Snuwoo, Chang-Shin;Lee, Woo-Tae;Cha, Jin-Myoung;Jang, Young-Seon;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2005년도 생물공학의 동향(XVI)
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    • pp.247-251
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    • 2005
  • This research was performed for developing of biological treatment process of odor gas such as MEK, $H_{2}S$, and toluene, which is generated from the food waste recycling process. To establish the operational conditions of odor gas removal by small-scale biofiltration equipment, it was continuously operated by using toluene as a treating odor object. When the odor treating microorganisms were adhered to fibril form biofilter, high removal efficiency over 93% was obtained by biofilm formation. At 400 ppm of inlet odor gas concentration and 10 sec of retention time, the removal efficiency was 76% and 93% in 1st stage reactor and 2nd stage reactor, respectively. However, the removal efficiency remained over 97% at the operational conditions above 15 sec of retention time.

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도시가스와 혼합가스($H_2$, CO) 적용 시 점화시기 및 공연비에 따른 발전효율 및 질소산화물 배출량 비교 (Comparison of effects of spark timing and fuel ratio on engine efficiency and $NO_x$ emission for fuel of city gas and syngas($H_2$ and CO))

  • 정철영;이경택;송순호;전광민;남상익
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.817-820
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    • 2009
  • Research on usage of syngas produced by waste gasification is on going all around the world. Syngas which consists of $H_2$, CO, $CO_2$, $N_2$, has different combustion characteristics from current city gas; due to distinct flame propagation speed of the fuel, syngas has different spark timing and air fuel ratio at maximum generating efficiency. This is why finding both the optimum point of spark timing and air fuel ratio is so important in order to improve thermo efficiency and secure stable running of gas generated by relatively low heating value syngas. Moreover, since emission of $NO_x$ is strictly regulated, it is important to operate lean burn condition that reduces NOx emission.

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Gas Sensing Properties of Powder Prepared from Waste Thermoelectric Devices by Wet Reduction Process

  • So, Hyeongsub;Im, Dong-Ha;Jung, Hyunsung;Lee, Kun-Jae
    • 한국세라믹학회지
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    • 제55권1호
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    • pp.90-93
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    • 2018
  • In this study, n-type $Bi_2Te_3$ in thermoelectric scrap is recovered through a wet reduction process. The recovered powder (tellurium) is grafted onto gas sensor in a new application that is not a thermoelectric device. Bismuth-rich powder is prepared by adding hydrazine when pH of the solution is brought to 13 using NaOH. The pH of the filtered solution was reduced using $HNO_3$, and then hydrazine was added to perform the re-reduction reaction. The tellurium-rich powder can be obtained through this reaction. The elemental analysis for these powders is confirmed by energy dispersive X-ray spectroscopy (EDS) analysis ; the successful separation of bismuth and tellurium is confirmed. Separated tellurium powder is mixed with DMF solvent and ethyl cellulose binder to confirm gas sensing properties. The tellurium paste was exposed in $NO_x$ atmosphere and exhibited a rapid reaction rate and recovery rate of less than 3 minutes for the gas.

주사바늘 전극형 오존발생기 특성 연구 (Observation and Characteristics of Ozonizer using Injection Needle Electrode)

  • 박현미;권영학;박원주
    • 조명전기설비학회논문지
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    • 제29권12호
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    • pp.77-82
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    • 2015
  • Ozone is a powerful disinfectant and oxidizing agent, and it is used in a wide range of applications, such as waste water treatment, food processing, etc.. There is also a great potential of using ozone in new emerging medical applications, such as ozone dentistry and ozone oxygen therapy. For these purposes, simple, small, compact and efficient sources of ozone are needed. In this study, in order to increase the current-voltage range of the discharge and to avoid the overheating of the gas in the ozonizer we suggested ozonizer of injection needle and plate electrode type(INP Type) with the gas through the needle. A ozonizer of INP type have been investigated by focusing on ozone concentration and yield according to flow rates and Gap of two electrodes. The results of studies of ozone production for DC corona discharge in oxygen at atmospheric pressure about the ozonizer of INP type. The ozone concentration and the generation yield increased as the gap of two electrodes and gas flow were decreased. Also, when the gap of two electrodes and gas flow with no change, the ozone concentration and generation yield each have variation of direct proportion and inverse proportion with discharge voltage.

MCFC 배기가스를 이용하는 순산소연소 $CO_2$ 회수형 발전시스템의 특성과 경제성 평가 (Characteristics and Economic Evaluation of a CO2-Capturing Repowering System with Oxy-Fuel Combustion for Utilizing Exhaust Gas of MCFC)

  • 박병식;이영덕;안국영;정현일
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2940-2945
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    • 2008
  • The scale of 2.4 MW MCFC was taken to construct a high-efficiency and economical power generation system without CO2 emission into the atmosphere for utilizing its exhaust gas. The conventional steam turbine power generation system (STGS) was evaluated and the net generated power (NGP) was estimated to be only 133 kW and the STGS is not economically feasible. A CO2-caputuring repowering system was proposed, where low temperature steam (LTS) produced at HRSG by using exhaust gas from MCFC is utilized as a main working fluid of a gas turbine, and the temperature of LTS was raised by combusting fuel in a combustor by using pure oxygen, not the air. It has been shown that NGP of the proposed system is 264 kW, and CO2 reduction amount is 608 t-CO2/y, compared to 306 t-CO2/y of STGS. The CO2 reduction cost was estimated to be negligible small, even when the costs of oxygen production and CO2 liquefaction facilities etc. were taken into account.

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BOG 내부 열교환을 이용한 LNG 선박용 Boil-Off Gas 재액화 시스템 (Boil-Off Gas Reliquefaction System for LNG Carriers with BOG-BOG Heat Exchange)

  • 이윤표;신유환;이상훈;김광호
    • 대한조선학회논문집
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    • 제46권4호
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    • pp.444-451
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    • 2009
  • The price increase of natural resources and the worldwide growth of LNG demand led to save the waste of Boil-Off Gas evaporating from cargo tanks of LNG carriers during navigation. As one of the efforts, a BOG reliquefaction system with BOG-to-BOG heat exchanging method was newly devised. This study was also discussed on the process details such as some features and advantages including comparisons with conventional BOG reliquefaction system, non BOG-BOG heat exchange type. The thermodynamic analysis for the system were also performed. Through the cycle simulation, the process efficiency of the BOG reliquefaction system BOG-BOG heat exchange was estimated to be increased up to 21%.

매립장 침출수 주요 수질항목에 대한 장기 영향요소 (Long Term Affecting Factors on Major Water Quality Items of Landfill Leachate)

  • 천승규;김민혁;원종철
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권1호
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    • pp.24-33
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    • 2021
  • Analysis of long term affecting factors on water quality items of gas emission form (BOD, COD) and leachate emission form (T-N, non-bio-degradable COD (NBDCOD)) was performed for the SUDOKWON 1st Landfill Site (LS1) and 2nd Landfill Site (LS2). As landfill gas was generated, BOD and COD decreased from 6,887 and 20,025 mg/L in 1993 to 49.5 and 670.2 mg/L in 2019, respectively. TN and NBDCOD increased with waste decomposition but gradually decreased after landfill closure because of the precipitation infiltration effect. Due to the drastic decline of carbon in the leachate, the BOD/TN ratios of LS1 and LS2 declined from 13.0 and 17.0 during early stage of the landfill to 0.07 and 0.16 in 2019, respectively; LS2 and NBDCOD/COD increased from 0.25 to 0.65 during the same period. These conditions caused carbon deficiency in denitrification treatment and a chemical post-treatment request for NBDCOD. The different behaviors of gas emission and leachate emission items suggest the necessity of different strategic approaches in the long term perspective.

폐기물 매립지 내에서의 침출수 거동(I)- 현장조사를 통한 수리지반 특성 - (Leachate Behavior within the Domestic Seashore Landfill(I)- Hydrogeologic Property Identification through In-situ Tests -)

  • 장연수;조용주
    • 한국지반공학회논문집
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    • 제15권6호
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    • pp.99-109
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    • 1999
  • 국내 일반폐기물 매립지의 경우 함수비가 높은 쓰레기의 특성으로 인하여 매립지 내부에 누적수위가 발생하는 경우가 많고 따라서 매립된 복토재와 쓰레기의 수리특성의 파악은 매우 중요하다. 폐기물 매립지의 설계시공 과정에서 매립지 하부차수재와 주변지반의 수리특성에 대해서는 많은 지반조사와 연구가 되어있으나 매립지내부 쓰레기와 복토재의 수리적특성 및 흐름거동에 대한 조사 및 해석은 국내외적으로 되어있지 않다. 본 논문에서는 국내 대표적 폐기물 매립지에 대한 현장 지반조사로부터 쓰레기와 복토재의 지반공학적 특성을 파악하고 양수시험(pumping test)과 순간충격시험(slug test)을 이용하여 매립된 쓰레기와 복토재의 수리특성을 파악하였다. 현장지반조사 결과 매립된 쓰레기의 다짐정도는 실내시험의 최대 단위중량 값을 상회하는 것으로 나타났으며 쓰레기에 의하여 덮여진 중간 저투수성 복토재는 침출수와 가스의 수직 흐름을 방해하고 있는 것으로 보여진다. 현장 양수시험과 순간충격시험의 투수계수는 상호간에 잘 일치하고 문헌에서 나타난 잘 다져진 쓰레기의 투수계수 범위에 있는 것으로 나타났다.

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폐김치냉장고에서의 HFC-134a 탈루배출 특성에 대한 연구 (Fugitive Emission Characteristics of HFC-134a from Waste Kimchi Refrigerator)

  • 김의건;김승도;이영표
    • 한국대기환경학회지
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    • 제30권1호
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    • pp.59-67
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    • 2014
  • In 1995 Kimchi refrigerator was developed at first, and has used HFC-134a as refrigerant. Kimchi refrigerator has been made 1,044,694 on the basis of 2010, disposed about 160,000 per year. Although mobile air conditioning, commercial refrigerator, general refrigerator is regarded as a major source of HFC-134a, little information is available for its emission characteristics of HFC-134a. This paper addresses the fugitive emission factors of Kimchi refrigerator at use-phase and disposal-phase. The residual quantities of Korean-made fifty three waste Kimchi refrigerators were weighed using a commercial recover of refrigerants to determine the emission factors at the disposal-phase. On the other hand, the emission factors at use-phase were estimated from the residual quantities and operating times. The average residual rate of forty three scarp Kimchi refrigerators is determined to be $74.6{\pm}5.2%$. The emission factor at the use-phase is estimated to be $3.5{\pm}0.8%/yr$ as a result of using average age of 11.7 years and the average residual rate determined here. The emission factor at the disposal-phase is determined to be 31.3% after adopting 58% of the recycling rate of refrigerant reported by Recycling Center. We estimate 3.1 g/yr for the average emission quantity of HFC-134a per operating refrigerator, while 22.5 g for that per waste Kimchi refrigerator. Since the chemical compositions of refrigerant of waste Kimchi refrigerator were the same as those of new refrigerant, it is expected that the HFC-134a recovered from waste Kimchi refrigerator can be reused for refrigerant.