• Title/Summary/Keyword: Waste gas

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Comparison of N2O Emissions by Greenhouse Gas Emission Estimation Method (온실가스 배출량 산정 방법에 따른 N2O 배출량 비교)

  • Kang, Soyoung;Cho, Chang-Sang;Kim, Seungjin;Kang, Seongmin;Yoon, Hyeongi;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.175-184
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    • 2015
  • In this study GC and PAS were used to calculate $N_2O$ concentration of exhaust gas from Wood Chip combustion system. Fuel supplied to the incinerator was collected and analyzed and then the analysis result was used to calculate $N_2O$ emissions. Tier 3 and Tier 4 Method were used to calculate the $N_2O$ emissions. Plant's Specific emission factor of $N_2O$ by Tier 3 Method was 0.35 kg/TJ, while default emission factor of Wood?Wood Waste proposed by 2006 IPCC G/L was 4 kg/TJ. So the $N_2O$ emission factor of this study was 3.65 kg/TJ lower compared to the IPCC G/L. The total emissions calculated by Plant's specific emission factor was 4.22 kg during the measuring period, but by Tier 4 Method it was 7.88 kg. This difference in emissions was caused by the difference of continuous measuring and intermittent sampling. It would be necessary to apply continuous measuring to calculate emissions of $Non-CO_2$ gas whose the density distribution is relatively high. However currently, according to the target management guideline of greenhouse gas and energy, the continuous measuring method to calculate greenhouse gas emission is applied only to $CO_2$. Therefore for reliable greenhouse gas emission calculation it would be necessary to apply continuous measuring to calculate $Non-CO_2$ gas emission.

Application of Biofilter Using Fibril-form Matrix for Odor Gas Removal

  • Lee, Gwang-Yeon;Jeong, Gwi-Taek;Lee, Kyoung-Min;Snuwoo, Chang-Shin;Lee, Woo-Tae;Cha, Jin-Myoung;Jang, Young-Seon;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.247-251
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    • 2005
  • This research was performed for developing of biological treatment process of odor gas such as MEK, $H_{2}S$, and toluene, which is generated from the food waste recycling process. To establish the operational conditions of odor gas removal by small-scale biofiltration equipment, it was continuously operated by using toluene as a treating odor object. When the odor treating microorganisms were adhered to fibril form biofilter, high removal efficiency over 93% was obtained by biofilm formation. At 400 ppm of inlet odor gas concentration and 10 sec of retention time, the removal efficiency was 76% and 93% in 1st stage reactor and 2nd stage reactor, respectively. However, the removal efficiency remained over 97% at the operational conditions above 15 sec of retention time.

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Comparison of effects of spark timing and fuel ratio on engine efficiency and $NO_x$ emission for fuel of city gas and syngas($H_2$ and CO) (도시가스와 혼합가스($H_2$, CO) 적용 시 점화시기 및 공연비에 따른 발전효율 및 질소산화물 배출량 비교)

  • Jeong, Chul-Young;Lee, Kyung-Teak;Song, Soon-Ho;Chun, Kwang-Min;Nam, Sang-Ick
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.817-820
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    • 2009
  • Research on usage of syngas produced by waste gasification is on going all around the world. Syngas which consists of $H_2$, CO, $CO_2$, $N_2$, has different combustion characteristics from current city gas; due to distinct flame propagation speed of the fuel, syngas has different spark timing and air fuel ratio at maximum generating efficiency. This is why finding both the optimum point of spark timing and air fuel ratio is so important in order to improve thermo efficiency and secure stable running of gas generated by relatively low heating value syngas. Moreover, since emission of $NO_x$ is strictly regulated, it is important to operate lean burn condition that reduces NOx emission.

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Gas Sensing Properties of Powder Prepared from Waste Thermoelectric Devices by Wet Reduction Process

  • So, Hyeongsub;Im, Dong-Ha;Jung, Hyunsung;Lee, Kun-Jae
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.90-93
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    • 2018
  • In this study, n-type $Bi_2Te_3$ in thermoelectric scrap is recovered through a wet reduction process. The recovered powder (tellurium) is grafted onto gas sensor in a new application that is not a thermoelectric device. Bismuth-rich powder is prepared by adding hydrazine when pH of the solution is brought to 13 using NaOH. The pH of the filtered solution was reduced using $HNO_3$, and then hydrazine was added to perform the re-reduction reaction. The tellurium-rich powder can be obtained through this reaction. The elemental analysis for these powders is confirmed by energy dispersive X-ray spectroscopy (EDS) analysis ; the successful separation of bismuth and tellurium is confirmed. Separated tellurium powder is mixed with DMF solvent and ethyl cellulose binder to confirm gas sensing properties. The tellurium paste was exposed in $NO_x$ atmosphere and exhibited a rapid reaction rate and recovery rate of less than 3 minutes for the gas.

Observation and Characteristics of Ozonizer using Injection Needle Electrode (주사바늘 전극형 오존발생기 특성 연구)

  • Park, Hyun-Mi;Kwon, Young-Hak;Park, Won-Zoo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.12
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    • pp.77-82
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    • 2015
  • Ozone is a powerful disinfectant and oxidizing agent, and it is used in a wide range of applications, such as waste water treatment, food processing, etc.. There is also a great potential of using ozone in new emerging medical applications, such as ozone dentistry and ozone oxygen therapy. For these purposes, simple, small, compact and efficient sources of ozone are needed. In this study, in order to increase the current-voltage range of the discharge and to avoid the overheating of the gas in the ozonizer we suggested ozonizer of injection needle and plate electrode type(INP Type) with the gas through the needle. A ozonizer of INP type have been investigated by focusing on ozone concentration and yield according to flow rates and Gap of two electrodes. The results of studies of ozone production for DC corona discharge in oxygen at atmospheric pressure about the ozonizer of INP type. The ozone concentration and the generation yield increased as the gap of two electrodes and gas flow were decreased. Also, when the gap of two electrodes and gas flow with no change, the ozone concentration and generation yield each have variation of direct proportion and inverse proportion with discharge voltage.

Characteristics and Economic Evaluation of a CO2-Capturing Repowering System with Oxy-Fuel Combustion for Utilizing Exhaust Gas of MCFC (MCFC 배기가스를 이용하는 순산소연소 $CO_2$ 회수형 발전시스템의 특성과 경제성 평가)

  • Pak, Pyong-Sik;Lee, Young-Duk;Ahn, Kook-Young;Jeong, Hyun-Il
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2940-2945
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    • 2008
  • The scale of 2.4 MW MCFC was taken to construct a high-efficiency and economical power generation system without CO2 emission into the atmosphere for utilizing its exhaust gas. The conventional steam turbine power generation system (STGS) was evaluated and the net generated power (NGP) was estimated to be only 133 kW and the STGS is not economically feasible. A CO2-caputuring repowering system was proposed, where low temperature steam (LTS) produced at HRSG by using exhaust gas from MCFC is utilized as a main working fluid of a gas turbine, and the temperature of LTS was raised by combusting fuel in a combustor by using pure oxygen, not the air. It has been shown that NGP of the proposed system is 264 kW, and CO2 reduction amount is 608 t-CO2/y, compared to 306 t-CO2/y of STGS. The CO2 reduction cost was estimated to be negligible small, even when the costs of oxygen production and CO2 liquefaction facilities etc. were taken into account.

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Boil-Off Gas Reliquefaction System for LNG Carriers with BOG-BOG Heat Exchange (BOG 내부 열교환을 이용한 LNG 선박용 Boil-Off Gas 재액화 시스템)

  • Lee, Yoon-Pyo;Shin, You-Hwan;Lee, Sang-Hoon;Kim, Kwang-Ho
    • Journal of the Society of Naval Architects of Korea
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    • v.46 no.4
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    • pp.444-451
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    • 2009
  • The price increase of natural resources and the worldwide growth of LNG demand led to save the waste of Boil-Off Gas evaporating from cargo tanks of LNG carriers during navigation. As one of the efforts, a BOG reliquefaction system with BOG-to-BOG heat exchanging method was newly devised. This study was also discussed on the process details such as some features and advantages including comparisons with conventional BOG reliquefaction system, non BOG-BOG heat exchange type. The thermodynamic analysis for the system were also performed. Through the cycle simulation, the process efficiency of the BOG reliquefaction system BOG-BOG heat exchange was estimated to be increased up to 21%.

Long Term Affecting Factors on Major Water Quality Items of Landfill Leachate (매립장 침출수 주요 수질항목에 대한 장기 영향요소)

  • Chun, Seung-Kyu;Kim, Min Hyuk;Won, Jong Chul
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.24-33
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    • 2021
  • Analysis of long term affecting factors on water quality items of gas emission form (BOD, COD) and leachate emission form (T-N, non-bio-degradable COD (NBDCOD)) was performed for the SUDOKWON 1st Landfill Site (LS1) and 2nd Landfill Site (LS2). As landfill gas was generated, BOD and COD decreased from 6,887 and 20,025 mg/L in 1993 to 49.5 and 670.2 mg/L in 2019, respectively. TN and NBDCOD increased with waste decomposition but gradually decreased after landfill closure because of the precipitation infiltration effect. Due to the drastic decline of carbon in the leachate, the BOD/TN ratios of LS1 and LS2 declined from 13.0 and 17.0 during early stage of the landfill to 0.07 and 0.16 in 2019, respectively; LS2 and NBDCOD/COD increased from 0.25 to 0.65 during the same period. These conditions caused carbon deficiency in denitrification treatment and a chemical post-treatment request for NBDCOD. The different behaviors of gas emission and leachate emission items suggest the necessity of different strategic approaches in the long term perspective.

Leachate Behavior within the Domestic Seashore Landfill(I)- Hydrogeologic Property Identification through In-situ Tests - (폐기물 매립지 내에서의 침출수 거동(I)- 현장조사를 통한 수리지반 특성 -)

  • 장연수;조용주
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.99-109
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    • 1999
  • In the case of domestic general waste landfills, cumulated leachate level is often formed in the landfill due to the waste of high moisture content and it becomes important to characterize the hydraulic properties of the disposed waste. Although many hydrologic studies have been peformed for leachate barriers and pheriperal subsurface environments, few studies have been done to investigate the hydraulic property of the disposed waste and cover soils and to analyse the leachate flow behavior within landfills. In this paper, the geotechnical properties of the waste and buried cover soils are identified through the field experiment including pumping and slug tests. The results of various tests show that the field density of the cover soils is somewhat higher than the maximum laboratory density of cover soils and the vertical flow of leachate and gas in the landfill is prevented by the buried cover soils. The hydraulic conductivities of field pumping test and slug tests are well matched and stayed in the range of hydraulic conductivities of well compacted wastes in the literature.

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Fugitive Emission Characteristics of HFC-134a from Waste Kimchi Refrigerator (폐김치냉장고에서의 HFC-134a 탈루배출 특성에 대한 연구)

  • Kim, Eui-Kun;Kim, Seungdo;Lee, Young Phyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.1
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    • pp.59-67
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    • 2014
  • In 1995 Kimchi refrigerator was developed at first, and has used HFC-134a as refrigerant. Kimchi refrigerator has been made 1,044,694 on the basis of 2010, disposed about 160,000 per year. Although mobile air conditioning, commercial refrigerator, general refrigerator is regarded as a major source of HFC-134a, little information is available for its emission characteristics of HFC-134a. This paper addresses the fugitive emission factors of Kimchi refrigerator at use-phase and disposal-phase. The residual quantities of Korean-made fifty three waste Kimchi refrigerators were weighed using a commercial recover of refrigerants to determine the emission factors at the disposal-phase. On the other hand, the emission factors at use-phase were estimated from the residual quantities and operating times. The average residual rate of forty three scarp Kimchi refrigerators is determined to be $74.6{\pm}5.2%$. The emission factor at the use-phase is estimated to be $3.5{\pm}0.8%/yr$ as a result of using average age of 11.7 years and the average residual rate determined here. The emission factor at the disposal-phase is determined to be 31.3% after adopting 58% of the recycling rate of refrigerant reported by Recycling Center. We estimate 3.1 g/yr for the average emission quantity of HFC-134a per operating refrigerator, while 22.5 g for that per waste Kimchi refrigerator. Since the chemical compositions of refrigerant of waste Kimchi refrigerator were the same as those of new refrigerant, it is expected that the HFC-134a recovered from waste Kimchi refrigerator can be reused for refrigerant.