• Title/Summary/Keyword: Waste gas

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Effects of Surfactant on SF6 Gas Hydrate Formation Rate (가스 하이드레이트 형성 원리를 이용한 SF6 처리 기술에 관한 연구)

  • Lee, Bo-Ram;Lee, Hyun-Ju;Kim, Shin-Ho;Lee, Ju-Dong;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.18 no.2
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    • pp.73-76
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    • 2008
  • [ $SF_6$ ] gas has been widely used as an insulating, cleaning and covering gas due to its outstanding insulating feature and because of its inert properties. However, the global warming potential of $SF_6$ gas is extremely high relative to typical global warming gases such as $CO_2$, CFCs, and $CH_4$. For these reasons, it is necessary to separate and collect waste $SF_6$ gas. In this study, the effects of a surfactant (Tween) on the formation rate of $SF_6$ gas hydrates were investigated. The $SF_6$ gas hydrate formation rate increased with the addition of Tween and showed a nearly 6.5 times faster hydrate formation rate with an addition of 0.2 wt.% Tween compared to an addition of pure water. This is believed to be due to the increased solubility of $SF_6$ gas with the addition of the surfactant. It was also found that $SF_6$ gas hydrate in the surfactant solution showed two-stage hydrate formation rates with a formation rate that increased rapidly in the 2nd stage.

EXHAUST GAS HEAT RECOVERY SYSTEM FOR PLANT BED HEATING IN GREENHOUSE PRODUCTION

  • Kim, Y.J.;Ryou, Y.S.;Rhee, K.J.;Kang, G.C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.639-646
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    • 2000
  • Hot air heater with light oil combustion is the most common heater for greenhouse heating in the winter season in Korea. However, since the heat efficiency of the heater is about 80%, considerable unused heat in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust gas heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The system consists of a heat exchanger made of copper pipes, ${\phi}\;12.7{\times}0.7t$ located inside the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tame The total heat exchanger area is $1.5m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to performance test it can recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690{\ell}$/hr from the waste heat discharged. The exhaust gas temperature left from the heat exchanger dropped to $100^{circ}C$ from $270^{circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{circ}C$ from $21^{circ}C$ at the water flow rate of $690{\ell}$/hr. And, the condensed water amount varies from 16 to $43m{\ell}$ at the same water circulation rates. This condensing heat recovery system can reduce boiler fuel consumption amount in a day by 34% according to the feasibility study of the actual mimitomato greenhouse. No combustion load was observed in the hot air heater.

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Morphological study of $SF_6$ clathrate hydrate crystal ($SF_6$ 하이드레이트 결정 성장의 특성)

  • Lee, Yoon-Seok;Lee, Hyun-Ju;Lee, Eun-Kyung;Kim, Soo-Min;Lee, Ju-Dong;Kim, Yang-Do
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.711-711
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    • 2009
  • Global warming has been widely recognized as a serious problem threatening the future of human beings. It is caused by the buildup in the atmosphere of greenhouse gases, such as carbon dioxide, methane, hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF6). Particularly, SF6 has extremely high global warming potential compare to those of other global warming gases. One option for mitigating this greenhouse gas is the development of an effective process for capturing and separating these gases from anthropogenic sources. In general, gas hydrates can be formed under high pressure and low temperature. However, SF6 gas is known to form hydrate under relatively milder conditions. Therefore, technological and economical effects could be expected for the separation of SF6 gas from waste gas mixtures. In this study, we carried out morphological study for the SF6 hydrate crystals to understand its formation and growth mechanisms. The observations were made in high-pressure optical cell charged with liquid water and SF6 gas at constant pressure and temperature. Initially SF6 hydrate formed at the surface between gas and liquid regions, and then subsequent dendrite crystals grew at the wall above the gas/water interface. The visual observations of crystal nucleation, migration, growth and interference were reported. The detailed growth characteristics of SF6 hydrate crystals were discussed in this study.

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Study of Thermoelectric Generator with Various Thermal Conditions for Exhaust Gas from Internal Combustion Engine using Numerical Analysis (수치해석을 통한 엔진 배기가스의 조건 변화에 따른 열전소자 발전 특성에 관한 연구)

  • In, Byung Deok;Lee, Ki Hyung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.3
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    • pp.243-248
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    • 2013
  • Internal combustion engines typically expel 30%-40% of the energy supplied by fuel to the environment through their exhaust system. Therefore, further significant improvements in the thermal efficiency of IC engines are possible by recovering the waste heat from the engine exhaust gas. With this fact in mind, a numerical simulation was carried out to investigate the potential of using thermoelectric generation with an internal combustion engine for waste heat recovery. Physical parameters such as the exhaust temperature and mass flow rate were evaluated in the exhaust system, and the optimum location for inserting a thermoelectric generator (TEG) into the system was determined. The TEG will be located in the exhaust system and will use the energy flow between the warmer exhaust gas and the external environment. The optimum position of the temperature distribution and the TEG performance were predicted through numerical analysis. The experimental results obtained showed that the power output significantly increases with the temperature difference between the cold and hot sides of the TEG.

Numerical Analysis of Off-Gas Flow in Hot Area of the Vitrification Plant (유리화공정 고온영역에서의 방사성 배기체 유동해석)

  • Park, Seung-Chul;Kang, Won-Gu;Hwang, Tae-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.3
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    • pp.213-220
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    • 2007
  • Appropriate numerical models for the simulation of off-gas flow in hot area of the vitrification plant have been developed in this study. The models have been applied to analyze the effect of design parameters of real plant and numerical analyses have been performed for CCM(Cold Crucible Melter), pipe cooler and HTF(High Temperature Filter). At first, the effect of excess oxygen and the ratio of oxygen distribution on combustion characteristics in the CCM has been studied. Next, solidification behavior of radio nuclide in the pipe cooler has been numerically modeled and scrutinized. Finally, flow pattern in accordance with the location of off-gas entrance of the HTF has been compared.

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Numerical Analysis of Off-Gas Flow in Hot Area of the Vitrification Plant (유리화공정 고온영역에서의 방사성 배기체 유동해석)

  • Park Seung-Chul;Kim Byong-Ryol;Shin Sang-Woon;Lee Jin Wook;Kang Won Gu;Hong Seok Jin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.69-78
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    • 2005
  • Appropriate numerical models for the simulation of off-gas flow in hot area of the vitrification plant have been developed in this study. The models have been applied to analyze the effect of design parameters of real plant and numerical analyses have been performed for CCM(Cold Crucible Melter), pipe cooler and HTF(High Temperature Filter) At first, the effect of excess oxygen and the ratio of oxygen distribution on combustion characteristics in the CCM has been studied. Next, solidification behavior of radio nuclide In the pipe tooler has been numerically modeled and scrutinized. Finally, flow pattern In accordance with the location of off-gas entrance of the HTF has been compared.

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A Study on Stabilization of Landfill by Air Ventilation in Field (공기주입방식을 통한 쓰레기 안정화의 현장적용에 관한 연구)

  • Lee, Hwan;Lee, Chae-young;Jeon, Yeon-ho;Kim, Kyung;Kim, Doo-il;Lee, Cheol-hyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.4
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    • pp.121-128
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    • 2000
  • Landfill and lysimeter experiments were conducted to estimate the optimum air injection method for the degradation of waste in landfill and the pre-stabilization. Continuous injection with low pressure and quantity can be effective for pre-stabilization of old landfill due to the lower contents of volatile solids in landfill. Air injection and landfill gas (LFG)extraction showed that the SVE (Soil Vapor Extraction) effect by air ventilation was more significant than the biodegradation of organics. Theses results suggested that they could accelerate the biological stabilization of organic waste in landfills. It is also expected that they would reduce the problems including gas emission during the landfill mining, separation and/or transportation to such levels that might be discharged directly to the atmosphere or with minimal treatment, if required.

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Corrosion Behavior of Inconel X-750 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.355-362
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    • 2020
  • The corrosion behavior of the Inconel X-750 alloy was investigated for its potential application under a Cl2-O2 mixed gas flow in an Ar atmosphere. The corrosion rate was found to be negligible at temperatures up to 400℃ under a flow rate of 30 mL·min-1 Cl2 + 170 mL·min-1 Ar, whereas an exponential increase was observed in the corrosion rate at temperatures greater than 500℃. The suppression of the corrosion reaction due to the presence of O2 was verified experimentally at flow rates of 30 mL·min-1 Cl2 (4.96 g·m-2·h-1), 20 mL·min-1 Cl2 + 10 mL·min-1 O2 (2.02 g·m-2 ·h-1), and 10 mL·min-1 Cl2 + 20 mL·min-1 O2 (1.34 g·m-2·h-1) under a constant Ar flow rate of 170 mL·min-1 at 600℃ for 8 h. The surface morphology analysis results revealed that porous surfaces with tunnel-type holes were produced under the Cl2-O2 mixed-gas condition. Furthermore, the effects of the Cl2 flow rate on the corrosion rate were investigated, indicating that its impact was negligible within the range of 5-30 mL·min-1 Cl2 at 600℃.

Reuse of Hydrogen Sulfide by Ferric Chelate Reaction of Food Waste Anaerobic Digestion Gas, Sulfur Recovery and its Economic Evaluation (킬레이트 착화학반응에 의한 음식물폐기물 혐기소화가스 중 황화수소의 제거와 황회수 및 경제성평가)

  • Park, Young G.;Yang, Youngsun
    • Clean Technology
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    • v.20 no.4
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    • pp.367-374
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    • 2014
  • Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.

Calculation and Projection of Methane Emissions from Waste Landfill for GHG Emission Reduction: Case Study of Puerto Cortes Landfill in Honduras (폐기물 매립지의 온실가스 감축을 위한 메탄가스 배출량 평가: 온두라스 Puerto Cortes 매립장 사례 분석)

  • Choong Gon Kim
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.1
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    • pp.13-19
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    • 2024
  • The objective of this study was to assess the feasibility of a landfill project aimed at reducing greenhouse gas (GHG) from Puerto Cortes Landfill in Honduras ("Project"). The feasibility study involved surveying the status, composition and amount of waste entering the landfill, and projecting GHG emissions from the landfill. A projection of the GHG emissions with the IPCC model and based on the survey results indicated that the period 2027 to 2041 would see a total GHG emission reduction of 506,835 ton-CO2/year, with a mean yearly GHG emission reduction of 33,789 ton-CO2, assuming landfill gas collection is implemented, The findings of the study are expected to serve as basic data for deciding about whether and how to proceed with the Project.