• Title/Summary/Keyword: Waste containing cellulose

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A Case Study of SFR Disposal Facility in Sweden to Derive the Total Disposable Amount of Radioactive Waste Containing Cellulose in Low and Intermediate Level Radioactive Waste Disposal Facility in Gyeongju (경주 중저준위방폐물 처분시설 내 셀룰로오스 함유 방폐물 처분가능 총량 도출을 위한 스웨덴 SFR 처분시설 사례 분석)

  • JaeChul Ha;MyungGoo Kang;SeHo Choi
    • Journal of Radiation Industry
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    • v.17 no.4
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    • pp.501-508
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    • 2023
  • There are various factors that have a negative impact on safety over a long period of time after the closure of a radioactive waste disposal facility. In particular, it is important to limit substances that accelerate radionuclide migration while inhibiting adsorption between radionuclides and the subsurface medium. Through this study, a method for deriving a quantitative criteria evaluation method is proposed for cellulose among materials that accelerate the movement of these radionuclides after closure of the disposal facility. Since Sweden's SKB is representative worldwide for preparing criteria for cellulose in disposal facilities, it analyzed Sweden's acceptance criteria method and presented a method that can be applied domestically. The decomposition characteristics of cellulose and the adsorption and dissolution characteristics of ISA among degradation products were reviewed, and quantitative analysis of cement materials that create a high pH environment favorable for cellulose decomposition was also included. In addition, the total amount of the finally disposable cellulose material can be derived by using the volume information of the waste containing the cellulose material. Through this methodology for calculating the total amount of cellulose, it is expected that subsequent studies will be conducted to secure data reflecting the environmental conditions of radioactive waste disposal facilities in Korea. In addition, it is expected to be utilized as a good method to evaluate the impact of other complexing agents other than cellulose and to suggest the amount of disposal.

Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate (落綿의 精製 및 이를 原料로 하는 醋酸纖維素의 分子量 分配曲線에 關한 硏究)

  • Kim, Dong-Il;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.38-43
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    • 1957
  • Purified cellulosic materials suitable for the production of cellulose esters can be prepared from waste cotton (carding waste from textile mill). The most desirable conditions in purifying waste cotton were obtained. Waxy materials were removed by boiling in 2-3% soda ash solution for more than 30 minutes in open vessel at atmospheric pressure. As for bleaching, it is desirable to use the bleaching powder solution containing 1%, available chlorine for 60 minutes at 35 deg. C. Purified cellulosic material was acetylated to fibrous cellulose triacetate, which was fractionated in the solution of 70% monochloroacetic acid using water as a precipitant, and the degree of polymerizaion and molecular weight of each fraction were measured viscometrically, thereon, molecular weight distribution curve was drawn. Analyzing the shape of this curve, most of the polymers were concentrated on the part of higher degree of polymerization. Purified waste cotton was also analysed, the result was that this cellulosic material can be used as a raw material for cellulose esters and ethers.

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Development of Polymeric Adsorbents for the Treatment of Colored Waste Waters and It's Applications ―Diethylaminoethylated Cellulosic Adsorbents― (유색배수 처리를 위한 고분자흡착제의 개발과 그 응용(III) ―디에틸아미노에틸화 셀룰로오스계 흡착제―)

  • Choe, Ji Eun;Sung, Woo Kyung;Lee, Mee Kyung;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.42-48
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    • 1993
  • In the present work, decoloring of acid dye solution by the diethylaminoethylated cellulosic adsorbents($CA_{DASE}$) was studied with the aim of developing polymeric adsorbents for the treatment of colored wastewaters. To prepare the cellulosic adsorbents, the $CA_{DASE}$ cellulose and polyvinyl alcohol mixture(80 wt% cellulose content) were crosslinked by tryacryloyl hexahydro-s-tryazine(TAHHT), ammonium phosphate and then treated with solutions containing sodium hydroxide and 2-diethylaminoethyl chloride. Batch and flow method were employed to determine decoloring capacity of C $A_{DEAE}$ for C.I.acid yellow 49. $CA_{DASE}$ exhibited much better desorption capacity than activated carbon. Furthermore, the exhausted $$CA{DASE} could be readily regenerated by washing with dilute sodium hydroxide.

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Preparation of Insoluble Dietary Fiber from Forest Waste and Its Physiological Function in Rat Fed High Cholesterol Diets

  • Chai, Young-Mi;Lim, Bu-Kug;Lee, Jong-Yoon;Rhee, Soon-Jae
    • Preventive Nutrition and Food Science
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    • v.7 no.1
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    • pp.78-87
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    • 2002
  • This study investigated the production of insoluble dietary fiber using forest waste and the dietary effect of manufactured insoluble fiber on physiological function in rat fed high cholesterol duets. Insoluble dietary fiber was prepared from the wood chips of oak (Quercus mongolica). The best condition for steam-explosion treatment for the preparation of insonuble dietary fiber was 25 kg/cm$^3$pressure for 6 minutes. In the chemical analysis of insoluble dietary fiber pretreated by 1% sodium hydroxide solution with steam-exploded wood, $\alpha$-cellulose content was 61.7% in the insoluble dietary fiber which contained 7.6% residual lignin. In order to compare insoluble dietary fiber with commercial $\alpha$-cellulose of physiological function, Sprague-Dawley male rats weighing 100$\pm$10 g were randomly assigned to one normal diet and five high cholesterol diet containing 1% cholesterol. The high cholesterol diet groups were classified as fiber free diet (FF group), 5% commercial $\alpha$-cellulose diet (5C group), 10% commercial $\alpha$-cellulose (l0C group), 5% insoluble dietary fiber dict (5M group), and 10% insoluble dietary fiber (10M group). The rats were fed ad libidum for 4 weeks. Food intake, weights gain, and food efficiency ratio in high cholesterol groups were higher than those of normal group, but there were no significant differences between the experimental groups. There were not any significant differences in the weights of livers, kidneys and small intestine of insoluble dietary fiber supplemented groups, but weight of cecum in all insolube dietary fiber group were significantly higher than those of FF group. A gstrointestinal transit time was decreased by supplementation of insoluble dietary fiber. Weight and water contents of feces in the insoluble dietary fiber supplemented groups were significantly higher than those of the FF group. There were not any significant differences in the activities of the glutamic pyruvic transaminase (GPT) and glutamic oxaloacetic transaminase (GOT) between the experimental groups. In conclusion, the manufactured insoluble dietary fiber and commercial insoluble fiber have the same physiological effects. The preparation method of the insoluble dietary fiber from the oak chips suited its purpose.

Antioxidant Effect of Histidine-Containing Low-Molecular-Weight Peptides Seperated from Tuna Meat (다랑어 육으로부터 분리한 Histidine 함유 저분자 Peptide의 항산화 효과)

  • Kim, Hong Kil;Song, Ho-Su
    • Journal of Food Hygiene and Safety
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    • v.35 no.5
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    • pp.513-520
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    • 2020
  • Here, we evaluated the functional properties of histidine-containing low-molecular-weight (LMW) peptides obtained from tuna waste meats. As with histidine-related components composed of histidine, 1-methyl histidine and anserine, histidine-containing LMW peptides exhibited high α,α-diphenyl-β-picrylhydrazyl (DPPH) radical scavenging effect in a dose-dependent manner. Among the histidine-related dipeptides, anserine exhibited the highest reducing power followed by carnosine. By comparison with dipeptides, tuna extracts also showed similar reducing power and the activity was in a dose-dependent manner. In addition, the antioxidant activities of tuna extracts such as DPPH radical scavenging effect, reducing power, superoxide dismutase activities, and peroxide value of linoleic acid were affected by the various extraction methods.

Studies on the Manufacture of Concentrated Feed by the Use of Farm Product Waste Materials (농산물(農産物) 폐물(廢物)을 이용(利用)한 농후사료(濃厚飼料) 제조(製造)에 관(關)한 연구(硏究))

  • Kim, Sam-Soon;Lee, Ji-Yul;Park, Sung-Oh;Kim, Ki-Joo
    • The Korean Journal of Mycology
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    • v.1 no.2
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    • pp.15-23
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    • 1973
  • Mold producing cellulase were isolated from rotten woods, and identified as the three species: Aspergillus niger van Tieghem, Aspergillus schiemanni Thom and Trichoderma viride Pers. In this paper, culture conditions in the media and characteristics of these strains were investigated. Using these strains, we have conducted a research concerning the utilization of farm product waste materia's. 1. Optimum conditions for the cellulase formation were as follows. KM 10-1; pH 5.2-5.5, $35^{\circ}C$, incubation time 6 days. OL 11-1; pH 5.5, $30-35^{\circ}C$, incubation time 6 days. SH 9-2; pH 5.5, $30^{\circ}C$, incubatoin time 6 days. 2. Their cellulase activities in their optimum condition were as follows: KM 10-1; CMC-LP 78.5% CMC-SP 4.0 glucose mg/gm of the cultures/min. OL 11-1; CMC-LP 89.9%, CMC-SP 4.9 glucose mg/gm of the cultures/min. SH 9-2; CMC-I.P 77.4%, CMC-SP 3.9 glucose mg/gm of the cultures/min. 3. Hydrolysis of animal feed containing a large quantity (23-30%) of cellulose by means of the crude enzyme in the selected strains resolved 30% of the cellulose contained in the animal feed.

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