• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.70-79
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• 2022

Biodiesel production has attracted attention as a sustainable source of fuel and is a competitive alternate to diesel engines. The glycerol that is produced as a by-product is generally discarded as waste and can be converted to green chemicals such as acetins to increase bio-diesel profitability. Acetins find application in fuel, food, pharmaceutical and leather industries. Batch experiments and analysis have been previously conducted for synthesis of acetins using glycerol esterification reaction aided by sulfated metal oxide catalysts (SO₄^2-/CeO₂-ZrO₂). The aim of this study was to optimize process parameters: effects of mole ratio of reactants (glycerol and acetic acid), catalyst concentration and reaction temperature to maximize glycerol conversion/acetin selectivity. The optimum conditions for this reaction were determined using response surface methodology (RSM) designed as per a five-level-three-factor central composite design (CCD). Statistica software 10 was used to analyze the experimental data obtained. The optimized conditions obtained were molar ratio - 1:12, catalyst concentration - 6 wt.% and temperature -90 ℃. A packed bed reactor was fabricated and column studies were performed using the optimized conditions. The breakthrough curve was analyzed.

• Journal of Biosystems Engineering
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• v.25 no.3
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• pp.221-226
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• 2000

Hot air heater with light oil burner is the most common heater for greenhouse heating in the winter season in Korea. However, since the thermal efficiency of the heater is about 80∼85%, considerable unused heat amount in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The heat recovery system is made for plant bed or soil heating in the greenhouse. The system consisted of a heat exchanger made of copper pipes, ${\Phi}12.7{\times}0.7t$ located in the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tank. The total heat exchanger area is 1.5$m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to the performance test it could recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690\ell$/hr from the waste heat discharged. The exhaust gas temperature left the heat exchanger dropped to $100^{\circ}C$ from $270^{\circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{\circ}C$ from $21^{\circ}C$ at the water flow rate of $690\ell$/hr. By the feasibility test conducted in the greenhouse, the system did not encounter any difficulty in operations. And, the system could recover 220,235kJ of exhaust gas heat in a day, which is equivalent of 34% of the fuel consumption by the water boiler for plant bed heating of 0.2ha in the greenhouse.

• Journal of the Korean Institute of Rural Architecture
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• v.20 no.1
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• pp.45-52
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• 2018

The purpose of this study is to investigate safety and dangerous awareness of environment on walking trails. For this purpose, questionnaire survey are carried out by people who had experience using walking trails during 2016. It is evaluated that environments of walking trails located inside big cities are inferior than ones located in small and medium-sized cities and countryside in air pollution, bed smell, water pollution, noise, and waste. Needs about management and number installed public restroom are high for hygienic environment of walking trails. With waste treatment, users of 2.4 percentage are showed improper behavior that they left their rubbish at the place out of view but others bring their trash. Accident likelihood is highly appreciated and possibility of physical accident like slipping is showed at the highest. The reasons of accident on walking trails are responded with carelessness of walkers and improper of installation or management of safety facility at the most. For safety environment of walking trails, needs of installation of safety fences and notices of dangerous area are requested. In order to separate prevention from paths of walking trails, signposts are needed at visual clearness, maintenance, installation with proper interval and location, and correct contents. Respondents of 2.4 percentage have experiences of accident on walking trails and physical accident like slipping is occurred at the most.

• Journal of Radiation Industry
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• v.18 no.3
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• pp.183-193
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• 2024

As part of the social response to the radon bed incident in 2018, the Nuclear Safety and Security Commission took measures to collect and dispose of all radon beds. The Waste Management Act provides landfill disposal as one of the disposal methods for natural radioactive product waste, which is one of the NORM wastes. When NORM wastes are landfilled, workers and the public at the landfill site are exposed to radiation through various pathways, such as leaching of radionuclides through soil and groundwater, and multiple exposure factors are involved simultaneously. In order to improve the reliability of radiological impact assessment, the values of main exposure factors should be selected more accurately. Therefore, before developing the main exposure factors for site characteristics, it is necessary to prioritize main exposure factors reflecting domestic characteristics of NORM waste landfills. Therefore, in this study, the main exposure factors for NORM waste landfill were derived using NDD analysis. To derive the main exposure factors, the analysis tool was first selected as RESRAD-ONSITE computer code, and the exposure scenarios were mainly selected as a resident farmer and suburban resident scenario, recreation scenario, and industrial worker scenario. Then, the priority 1 and 2 factors were selected for sensitivity analysis, and a Korean standard model was established to reflect Korean characteristics. Finally, the sensitivity analysis was conducted through NDD, and the main exposure factors were derived based on this. In the resident farmer scenario, the contaminated zone distribution coefficients of ²²⁶Ra, ²¹⁰Pb, ²³²Th, ²²⁸Ra, ²³⁴U, and ²³⁸U, as well as precipitation and evapotranspiration factors, were derived as the main exposure factors. In the suburban resident scenario, the contaminated zone distribution coefficients of ²²⁶Ra, ²¹⁰Pb, ²³²Th, ²²⁸Ra, ²³⁴U, and ²³⁸U, as well as precipitation and evapotranspiration coefficients, were derived as the main exposure factors. In the recreation scenario, the contaminated zone distribution coefficient of ²³²Th was derived as the main exposure factor. For the industrial worker scenario, the erosion rate was derived as the main exposure factor. The main exposure factors for each scenario were analyzed to be different depending on the scenario characteristics. The results of this study can be utilized as a basis for radiological environmental impact assessment of NORM waste landfill in Korea.

• Journal of Environmental Health Sciences
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• v.30 no.4
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• pp.329-343
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• 2004

We conducted to investigate citizen's attitude to the treatment of food waste in Yongin city. The respondent of $41.81\%$ throws the food waste eliminate from home and store less than 1l in Yongin. When they dump the food waste, they speak out the inconvenience of damaged envelope by animals in case of home and store. This caused troubles for reason of sanitary. So a local autonomous entity must carefully consider of expand use specially designed container as like apartment house. They give an answer that the collecting time of food waste is suitable form dawn till morning. This answer shows the satisfaction of the period time to collect the food waste. They prefer to be appointed the exclusive place to collect food waste. The service interval of collect is suitable 1 time a day. They want to increase the number of washing of the collecting container. This is good method for sanitary condition, but the care of the period time to collect the food waste is more efficient than the care of the number of washing the collecting container. The care of the period time minimizes to incur the enmity of the people and to pollute in environment. The major of respondent handled the food waste after keeping the basket or a kit. This fact shows to us almost citizen doesn't feel the seriousness to remove the moisture of the food waste. Recently, many solutions which can be disposal efficiently are getting magnified and improved owing to increase utilities channel to loss in quantities and dry the food waste. We expect the reduction of food waste is solved getting easily step by step. The results of the awareness about the facility of food waste show citizen prefer recycling facility to the other facilities. If recycle facility and incineration facility are constructed, they were worried about bed smell. When some facility of the food waste is constructed, they have to maintain and to handle not to incur the enmity of the people. The spread rate of specially designed container already increased, the citizen set a high value on the use of specially designed container more than amount-rate vinyl envelope that people have used for several years. In the cost treatment about food waste, the major respondent answered the use cost of specially designed container is suitable price. So we can know the use charge is proper level. The majority of citizen more prefer autonomous plan which voluntary atmosphere creation and public information by mass media than levy system and rising treatment cost which forced plan. The citizens have pretty positive thinking of incineration, so the government needs more efforts for a public notice, which includes the incineration is no more than abandoned thing. Each of local self government has to sort the food waste and make kind of resource system related to collecting and carrying, constructing a suitable facility, proper disposal of the food waste and producing harmless in our surrounding in order to solve the invisible problems. To do above mentioned things, we have to analyze referred several problems till now. Also, to minimize the side effect, the government will have to improve through enforce the system.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.5
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• pp.507-516
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• 2008

This research was conducted to elucidate the effect of temperature on the nitrogen removal of municipal wastewater with waste-tire media. The experiments were carried out in laboratory-scale batch reactor and pilot-scale moving bed biofilm reactor filled at a 0.15 filling ratio with waste-tire media, respectively. In batch tests, specific nitrification rate(SNR) with media was 3.4 mg NH$_4^+$-N/g Mixed-Liquor Volatile Suspended Solid(MLVSS)$\cdot$hr, compared with 1.7 mg NH$_4^+$-N/g MLVSS$\cdot$hr without media. In pilot-scale test with media, total nitrogen removal efficiency increased from 53 $\pm$ 8% to 76 $\pm$ 5% as the temperature increased from 9$\sim$10$^{\circ}C$ to 20$\sim$24$^{\circ}C$. At the temperature of 9$\sim$10$^{\circ}C$, 10$\sim$20$^{\circ}C$, and 20$\sim$24$^{\circ}C$, the SNRs were 0.8 $\pm$ 0.5, 3.1 $\pm$ 1.9, and 3.4 $\pm$ 2.1 mg NH$_4^+$-N/g MLVSS$\cdot$hr and the specific denitrification rates(SDNR) were 0.6 $\pm$ 0.2, 1.1 $\pm$ 0.6, 1.4 $\pm$ 0.6 mg NO$_3^-$-N/g MLVSS.hr, respectively. The overall activities of biomass in anaerobic, anoxic, and oxic zones at 20$\sim$24$^{\circ}C$ increased to 22, 20, and 15%, compared with those at 9$\sim$10$^{\circ}C$, respectively. The activity distribution of Nitrosomonas and Nitrobacter also increased with the increase of temperature.

• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.3
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• pp.118-123
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• 2000

Food waste results in various problems such as decay, odors and leachate in collection, transportation and landfill due to the high volatile solids and moisture content. Acidogenic fermentation of food waste is influenced by the environmental conditions such as pH, retention time, etc. Each component of food waste is degraded under the different environmental conditions. Starch, cellulose and protein have their own optimum pHs and retention times for degradation. The degradation of starch increases at low pH, cellulose with increasing retention time, and protein with increasing retention time as well as approaching neutral pH. These mean that the degradation of food waste can be enhanced by adjusting the environmental conditions of acidogenic fermentation. The efficiency of acidification increased from 71.2 to 81.1% by controlling dilution(D) rate from 3.0 to $1.0d^{-1}$ depending on the state of the fermentation. The main component of the acidified product was shifted from butyric to acetic acid, indicating that the increase of acidification was mainly caused by the enhanced degradation of vegetables and meats.

• Journal of Energy Engineering
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• v.8 no.2
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• pp.248-255
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• 1999

Catalytic cracking of pyrolysed waste lubricating oil over solid acid catalysts (HY zeolite, ${\beta}$-zeolite, HZSM-5) has been carried out in a micro-fixed bed system. The feed oil for catalytic activity tests has been prepared by thermal cracking of waste lubricating oil under the reaction conditions of 480$^{\circ}C$, 60 min. Optimum reaction conditions for the maximum light oil yields($\_$21/) were WHSV(weight hourly space velocity)=1 at 375$^{\circ}C$. The amounts of total and strong acid sites appeared to be the largest in ${\beta}$-zeolite as determined by NH$_3$, TPD. It is seen that the catalytic activity order, in terms of the light fuel oil ($\_$21/) production, were HY zeolite)${\beta}$-zeolite>HZSM-5. Also, coke formation followed the same order. The highest activity in HY zeolite may be attributed from the fact that it has supercages facilitating the easy diffusion of larger molecules and also the effectiveness of the acid sites for cracking within the pore. This fact could be confirmed by the coke formation characteristics.

• Applied Chemistry for Engineering
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• v.29 no.2
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• pp.248-251
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• 2018

Catalytic pyrolysis of the waste paper cup containing coffee residual (WPCCCR) was performed using a fixed bed reactor and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). Non-catalytic pyrolysis of WPCCCR produced a large amount of oil together with gas and char. The use of both HZSM-5 and HY decreased the yields of oil and increased the yield of gas due to the additional catalytic cracking. Owing to the acidic catalytic properties of HZSM-5 and HY, catalytic Py-GC/MS analysis of WPCCCR increased the selectivity to aromatic hydrocarbons in product oil. Owing to properties of HZSM-5 having a stronger acidity and medium pore size, the catalytic pyrolysis of WPCCR over HZSM-5 produced much larger amounts of aromatic hydrocarbons than that of using HY.

• 한국전산유체공학회:학술대회논문집
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• 2002.10a
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• pp.133-138
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• 2002

A 3-D axisymmetric computer program is developed to predict the NO behavior in SNCR system for the stoker incinerator with the waste treatment capacity, 200ton/day. To this end a turbulent reacting flow field calculation is made using proper assumption and empiricism. The stoker bed is assumed to be a homogeneous waste-volatilized gaseous state. The initial composition or reactants are assumed based on the data of the ultimate analysis. Turbulent is resolved by k-e model and turbulent reaction is handled by eddy-breakup model harmonized with empirical chemistry data for gaseous combustion, NO and urea reaction. The liquid droplet is traced by Lagrangian method incorporated by aerodynamic drag, Coriolis and crntrifugal forces. Radiation is treated by sensible heat loss model. Calculation results are in good agreement with experimental data at the outlet of post combustion chamber in Daejon 4th industrial complex. The flue gas shows the temperature range of $900\sim1000^{\circ}C$, velocity of 5m/s and NO concentration of 140ppm at the exit while the measured temperature, flue gas velocity and NO concentration are $967^{\circ}C$, $3\sim4m/s$ and $100\sim200ppm$respectively. Using the developed computer program a parametric study has been made with the variation of heat content of waste, castable length and SNCR variables for the determination of proper injector location. In general, the calculated results are consistent and physically acceptable.