• Title/Summary/Keyword: Waste acid

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Neuroprotective Effects of Korean Red Pine (Pinus densiflora) Bark Extract and Its Phenolics

  • Kim, Ji-Won;Im, Sungbin;Jeong, Ha-Ram;Jung, Young Sung;Lee, Inil;Kim, Kwan Joong;Park, Seung Kook;Kim, Dae-Ok
    • Journal of Microbiology and Biotechnology
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    • v.28 no.5
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    • pp.679-687
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    • 2018
  • Korean red pine (Pinus densiflora) is one of the major Pinus species in Korea. Red pine bark is removed prior to the chipping process in the wood industry and discarded as waste. However, red pine bark contains a considerable amount of naturally occurring phenolics, including flavonoids, and therefore may have a variety of biological effects. In this study, we investigated if Korean red pine bark extract (KRPBE) could protect neuronal PC-12 cells from oxidative stress and inhibit cholinesterase activity. Analysis of reversed-phase high-performance liquid chromatography results revealed four phenolics in KRPBE: vanillin, protocatechuic acid, catechin, and taxifolin. The total phenolic and flavonoid contents of KRPBE were 397.9 mg gallic acid equivalents/g dry weight (DW) and 248.7 mg catechin equivalents/g DW, respectively. The antioxidant capacities of KRPBE measured using ABTS, DPPH, and ORAC assays were 697.3, 521.8, and 2,627.7 mg vitamin C equivalents/g DW, respectively. KRPBE and its identified phenolics protected against $H_2O_2$-induced oxidative cell death in a dose-dependent manner. Acetylcholinesterase and butyrylcholinesterase, which degrade the neurotransmitter acetylcholine to terminate neurotransmission in synaptic clefts, were inhibited by treatment with KRPBE and its identified phenolics. Taken together, these results suggest that KRPBE and its constituent antioxidative phenolics are potent neuroprotective agents that can maintain cell viability under oxidative stress and inhibit cholinesterase activity.

Comparison of Plant-derived Carbonaceous Components (Organic Molecular Markers and 14carbon) in PM2.5 in Summer and Autumn at Kazo, Japan

  • Sasaka, Kouki;Wang, Qingyue;Sakamoto, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.11 no.3
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    • pp.165-175
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    • 2017
  • In Japan, the primary carbonaceous particles emitted from motor vehicles and waste incinerators have been reduced due to strict regulations against exhaust gas. However, the relative contribution of carbonaceous particles derived from plants and biomass has been increasing. Accordingly, compositional analysis of carbonaceous particles has become increasingly important to determine the sources and types of particles produced. To reveal the sources of the organic particles contained in particulate matter with diameters of ${\leq}2.5{\mu}m$ ($PM_{2.5}$) and the processes involved in their generation, we analyzed molecular marker compounds (2-methyltetrols, cis-pinonic acid, and levoglucosan) derived from the plants and biomass in the $PM_{2.5}$ collected during daytime- and nighttime-sampling periods in summer (July and August) and autumn (November) in Kazo, which is in the northern area of Saitama prefecture, Japan. We also measured $^{14}C$ carbonaceous concentrations in the same $PM_{2.5}$ samples. The concentrations of 2-methyltetrols were higher in the summer than in the autumn. Because the deciduous period overlaps with this decrease in the levels of 2-methyltetrols, we considered the emission source to broad-leaved trees. In contrast, the emission source of the cis-pinonic acid precursor was considered to be conifers, because its concentration remained almost constant throughout the year. The concentration of levoglucosan was considerably increased in the autumn due to frequent biomass open burning. The ratio of plant-derived carbon to total carbon, obtained by measuring of $^{14}C$, in summer $PM_{2.5}$ sample was higher in the nighttime, and could be influenced by anthropogenic sources during the daytime.

The Extraction of Metal Contaminants using Supercritical CO2 (초임계이산화탄소를 이용한 방사성 금속이온 추출)

  • Ju, Minsu;Kim, Jung-Hoon;Kang, Se-Sik
    • The Journal of the Korea Contents Association
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    • v.16 no.5
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    • pp.660-667
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    • 2016
  • Conventional decontamination methods utilize water-based systems, which generate high amounts of secondary wastes. Herein, we describe an environmentally benign decontamination method using liquid and supercritical $CO_2$. The use of $CO_2$ as a solvent affords effective waste reduction by its ability to be recycled, thereby leaving be hind only the contaminants upon its evaporation. In this study, a $CO_2$ solution process was assessed using t-salen(t-butylsalen), DC18C6 (dicyclohexano-18Crown6), 8-HQN(8-hydroxyquinoline), NEt4PFOSA(perfluoro-1-octanesulfonic acid tetra-ethyl ammonium salt), and NEt4PFOA(pentadecafluorooctanoic acid ammonium salt) to extract spiked radioactive contaminants(Nb,Zr,Co,Sr) from an inert sample matrix, namely filter paper. With the static extraction method, Sr was extracted with a maximum extraction rate of 97%, and Nb was extracted with a maximum extraction rate of 75%. Additionally, we were also able to extract Co and Zr with maximum extract ion ratesof 73% and 64%, respectively.

Recovery of Nickel from sulfuric acid solution using Lewatit TP 220 ion exchange resin (황산용액(黃酸溶液)으로부터 이온교환수지(交換樹脂) Lewatit TP 220에 의한 니켈의 회수(回收))

  • Kang, Nam-Hee;Park, Kyung-Ho;Parhi, P.K.
    • Resources Recycling
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    • v.20 no.6
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    • pp.28-36
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    • 2011
  • The adsorption of nickel(Ni) from sulfuric acid solution was carried out by ion exchange method. A series of batch tests in synthetic solutions were carried out using Lewatit Monoplus TP 220 resin. The following experimental parameters, such as temperature, shaking rate, reaction time, pH, resin dosage and concentration of nickel ions etc. were investigated to establish the effective optimum conditions of nickel adsorption. The solution pH(2.0~5.0) and shaking rate had little effects on the adsorption of nickel and adsorption time of 72hours was required to reach equilibrium. The experimental results show a good agreement with Feundlich isotherm and pseudo-second order reaction. The adsorption behavior of Ni obtained from synthetic solution was compared with that of waste electroplating solution. Elution of nickel from loaded resin increased with increase in $H_2SO_4$ concentration.

Synthesis of Pan Fibrous ion-Exchanger by Hydrolysis and Their Adsorption Properties for Nickel Ion (가수분해에 의한 PAN섬유 이온교환체의 합성 및 Ni$^{2+}$ 흡착 특성)

  • 황택성;송해영;이철호;강경석;황의환
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.789-795
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    • 2001
  • In order to recover nickel ion from waste water containing heavy metals, the PAN fibrous ion-exchanger with primary, secondary amine groups and carboxyl group was synthesized by acid and base hydrolysis. The hydrolysis yield of PAN fiber in acid solution was higher than base solution. The swelling ratio and ion-exchange capacity of PAN fiber which was synthesized in 1N $H_2SO_4$ solution at $80^{\circ}C$ for 7 hrs appeared 71.2% and 1.95 meq/g respectively. We investigated that the adsorption of nickel ion was approached 1.44 meq/g at 50 min and the maximum adsorption capacity of ion-exchanger was 2.48 meq/g. We confirmed that the $Ni^{+2}$ adsorption ability of the synthesized PAN fibrous ion-exchanger in this study is excellent.

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Evaluation of Acid-treated Fish Sarcoplasmic Proteins on Physicochemical and Rheological Characteristics of Pork Myofibrillar Protein Gel Mediated by Microbial Transglutaminase

  • Hemung, Bung-Orn;Chin, Koo Bok
    • Food Science of Animal Resources
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    • v.35 no.1
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    • pp.50-57
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    • 2015
  • Fish sarcoplasmic protein (SP) is currently dumped as waste from surimi industry and its recovery by practical method for being the non-meat ingredient in meat industry would be a strategy to utilize effectively the fish resource. This study was aimed to apply pH treatment for fish SP recovery and evaluated its effect on pork myofibrillar protein (MP) gel. The pH values of fish SP were changed to 3 and 12, and neutralized to pH 7 before lyophilizing the precipitated protein after centrifugation. Acid-treated fish SP (AFSP) showed about 4-fold higher recovery yield than that of alkaline-treated SP and water absorption capacity was also about 1.2-fold greater. Because of the high recovery yield and water absorption capacity, AFSP was selected to incorporate into MP with/without microbial transglutaminase (MTG). The effects of AFSP and MTG on the physicochemical and rheological characteristics of MP and MP gel were evaluated. MTG induced an increase shear stress of the MP mixture and increase the breaking force of MP gels. MP gel lightness was decreased by adding AFSP. MP gel with MTG showed higher cooking loss than that without MTG. A reduction of cooking loss was observed when the AFSP was added along with MTG, where the insoluble particles were found. Therefore, AFSP could be contributed as a water holding agent in meat protein gel.

죽초액의 첨가가 재래닭의 생산성 및 육질에 미치는 영향

  • Kook, Gil;Lee, Jong-Bong;Koh, Hong-Beom;Kim, Gwang-Hyeon
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2001.11a
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    • pp.77-79
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    • 2001
  • This experiment was conducted to investigate the effects of Bamboo Vinegar Liquid(BVL) on performance and meat quality of Korean native chicken(KNC) for 8 weeks. One hundreds KNC were divided into 4 groups with 5 replicates per treatment and placed in pens. Dietary levels of food waste 0%, 1%, 2% and 4% were included in experimental diets. The growth performance and carcass weight of KNC fed BVL supplement diet were significantly different(P<0.05) from the control group. The lipid content, cholesterol content and TBA in breast meat were significantly(P<0.05) decreased by addition of BVL. However, the addition of BVL did not affect the meat color. The saturated fatty acid composition of breast meat was decreased(P<0.05), whereas unsaturated fatty acid was increased(P<0.05) by addition of BVL 1% and 2%. Taste of sensory evaluation was improved by addition BVL. The results of this study indicate that dietary supplemental BVL 1% and 2% may improve the performance and meat quality of KNC. The prevention effect of KNC which challenged with Salmonella gallinarum (1${\times}$10$\^$9/ CFU/ml) was evaluated. A reisolation of S.gallinarum in liver, pathological index of villus and colon were evaluated. There was no reisolation of S.gallinarum in liver and a few pathological index of colon in 4% BVL supplement fed KNC than 1 and 2%. These results indicate that dietary supplemental BVL 4% may improve the prevention effect to salmonellosis in chickens.

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Microbial Conversion of Woody Waste into Sugars and Feedstuff (I) - Optimal Delignification condition with alkaline peroxide for enzymatic hydrolysis of poplar wood (미생물(微生物)에 의한 목질자원(木質資源)의 당화(糖化) 및 사료화(飼料化)에 관(關)한 연구(硏究) (I) - alkaline peroxide에 의한 현사시나무의 효소가수분해를 위한 탈리그닌화의 적정조건)

  • Kim, Yoon-Soo;Bang, Joo-Wan;Chung, Ki-Chul;Myung, Kyu-Ho;Kim, Youn-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.3
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    • pp.23-29
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    • 1986
  • Alakline peroxide pretreatment for the delignification of poplar wood was performed. sinceit is a simple and efficent method for enhancing the enzymatic digestibility of wood residues. Approximately one-half of their lignin and most of the hemicellulose present in poplar wood were removed when the wood sawdust was reacted at 25$^{\circ}C$ for 100 hrs in an alkaline solution (pH 11.5) of 1% peroxide. The rate of decomposition as well as the saccharification efficiency were enhanced up to 350% and 260% respectively in comparision with those of the controll. This enhancement is comparable with that pretreated with 1% sodium hydroxide and 20% peracetic acid successively. The advantages of alkaline peroxide as delignifying agents against other chemicals were also discussed.

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Strengths and Permeability Properties of Porous Polymer Concrete for Pavement with Different Fillers (충전재 종류에 따른 포장용 포러스 폴리머 콘크리트의 강도 및 투수 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.4
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    • pp.51-59
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    • 2007
  • Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.

Synthesis of nano Cerium(IV) oxide from recycled Ce precusor (재생 세륨 전구체로부터 나노산화세륨(IV)합성)

  • Kang, Tae-Hee;Koo, Sang-Man;Jung, Choong-Ho;Hwang, Kwang-Taek;Kang, Woo-Kyu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.101-107
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    • 2013
  • Cerium compounds such as Cerium hydroxide ($Ce(OH)_3$), Cerium chloride ($CeCl_3{\cdot}nH_2O$), Cerium carbonate hydrate ($Ce_2(CO_3)_3{\cdot}8H_2O$), Cerium oxide ($CeO_2$) were synthesized using recycled Ce precursor. Cerium(IV) oxide of nanoparticles were obtained by Ultra-sonication. Cerium-sodium- sulfate compound was synthesized through acid-leaching and addition of sodium sulfate from 99 wt% purity of Ce precursor as a starting material that was recycled from the waste polishing slurry. Moreover Cerium hydroxide was obtained from Cerium-sodium-sulfate compound by adding to sodium hydroxide solution. Then Cerium chloride was synthesized by adding of hydrochloric acid to Cerium hydroxide. Needle-shaped Cerium carbonate hydrate was synthesized in the continuous process and Cerium(IV) oxide with 30~40 nm size was subsequently obtained by the calcinations and dispersion.