• Title/Summary/Keyword: Waste acid

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Preparation of Alum for Water Treatment Product Using Waste Aluminum Dross (알루미늄 폐드로스로부터 수처리응집제용 황산알루미늄 제조)

  • Park, Hyung-Kyu;Choi, Young-Yoon;Eom, Hyung-Choon;Bae, Dong-Su
    • Resources Recycling
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    • v.15 no.4 s.72
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    • pp.60-63
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    • 2006
  • Waste aluminum dross was leached with sulfuric acid to prepare alum used for water treatment product. The remained metallic aluminum in the waste aluminum dross was extracted into the solution to make aluminum sulfate solution. The solution could be used as alum for water treatment product after adjusting the required alumina concentration and the basicity. Comparing to the conventional method for alum using aluminum hydroxide, material cost could be saved in this method. Also, there is an additional merit in view of recycling of the waste aluminum dross by reducing the amount of waste dross to be landfilled.

Selective Leaching of Zinc from Zinc Oxide Waste and Preparation of Zinc Oxide (유기추출제를 이용한 산화아연 페기물로부터 아연의 선별 침출 및 산화아연 제조)

  • 주창식;천재기
    • Journal of Environmental Science International
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    • v.7 no.3
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    • pp.401-408
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    • 1998
  • An experimental research was preformed for the development of an effective process for zinc oxide waste(zinc ash) reuse. Zinc was selectively leached from zinc ash by 30 vol.% D2EHPA In kerosine solution, and the leaching velocity was quite fast. Zinc leached was stripped by sulfuric acid solutions, and the amount of zinc stripped was linearly Increased with the amount of sulfuric acid used. Zinc oxide fine particles were obtained by dropwise adding of sodium hydroxide solution to the resultant aqueous zinc solution at 85$^{\circ}C$.

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Recovery of Metallurgical Silicon from Slurry Waste (Wafer Sawing 공정의 폐슬러리로부터 금속 실리콘 회수에 관한 연구)

  • Kim, Jong-Young;Kim, Ung-Soo;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.189-194
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    • 2011
  • Metallurgical grade silicon was recovered from slurry waste for ingot sawing process by acid leaching and thermal treatment. SiC abrasive was removed by gravity concentration and centrifugation. Metal impurities were removed by the acid leaching using HF/HCl. The remaining SiC was separated by the thermal treatment at $1600^{\circ}C$ in an inert atmosphere by the difference in melting points. The purity of the obtained silicon was found to be around 99.7%.

The Properties of Magnetic Ferrofluid for the removal of oil from water surface (수면 유포 유류의 제거에 미치는 자성유체의 특성)

  • 신학기;신세건
    • Journal of Environmental Science International
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    • v.12 no.1
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    • pp.41-45
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    • 2003
  • Magnetite powder for kerosene-based ferrofluid was synthesized by air oxidation of waste acid containing $Fe^{2+}$ and $Fe^{3+}$ ions in the pH=11 at $60^{\circ}C$. Stable kerosen-based ferrofluid was prepared by addition of polyoxyethylene nonylphenyl ether(POENPE) to the magnetite containing water. Dispersion mechanism of an addition POENPE to the magnetite was examined by means of the fraction of solid dispersed FT-IR spectrum. And magnetic properties of kerosen-based ferrofluid were examined by method of Vibrating Sample Magnetometer. In order to remove oil on the water surface by an addition of kerosen-based ferrofluid, the optimum conditions were examined.

Acid Fermentation Characteristic of Food Wastes According to the Organic Loading Rate (유기물부하에 따른 음식물찌꺼기의 산발효 특성)

  • Park, Jin-Sik;Ahn, Chul-Woo;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.975-982
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    • 2006
  • This study has been conducted to optimum operating conditions for effective acid fermentation according to OLR(organic loading rate) in the mesophilic and thermophilic acid fermentation process. The results are summarized as follows. In order to obtain reasonable acid fermentation efficiency in performing acid fermentation of food wastes in thermophilic condition, organic loading rate was required below 20 gVS/L.d. As $SCOD_{Cr}/TKN,\;SCOD_{Cr}/T-P$ of thermophilic acid fermented food wastes In organic loading rate 20 gVS/L.d were 18.9, 73.4 respectively, it was possible to utilize as external carbon source for denitrification in sewage treatment plant after solid-liquid separation as well as co-digestion of fermented food wastes and sewage sludge.

Study on Recovery of Separated Hydrofluoric Acid, Nitric Acid and Acetic Acid Respectively from Mixed Waste Acid Produced during Semiconductor Wafer Process (반도체 웨이퍼 제조공정(製造工程) 중 발생혼합폐산(發生混合廢酸)으로부터 불산, 질산 및 초산의 각 산 회수(回收)에 관한 연구(硏究))

  • Kim, Ju-Yup;Kim, Hyun-Sang;Bae, Woo-Keun
    • Resources Recycling
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    • v.18 no.4
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    • pp.62-69
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    • 2009
  • We researched separation of mixed waste acids with HF, $CH_3COOH$, $HNO_3$ that were produced during a semiconductor wafer process to recycle these acids. At first, we manufactured the fluoride compound in form of $Na_2SiF_6$ by precipitating HF using $NaNO_3$ and Si powder. The concentration of HF was reduced from the initial concentration of 127 g/L to 0.5 g/L with an HF recovery ratio of 99.5%. After the manufacture of $Na_2SiF_6$, the concentration of $HNO_3$ and $CH_3COOH$ demonstrated 502 g/L and 117 g/L respectively. Following these findings we added NaOH in this $CH_3COOH/HNO_3$ mixed acid in order to obtain pH=4. Next we separated the $CH_3COOH$ and recoverd it through the use of vaccum evaporation at -440 mmHg, $95^{\circ}C$. The concentration of the recovered $CH_3COOH$ was approximately 15% and the recovery ratio of $CH_3COOH$ was over 85%. We precipitated the $NaNO_3$ by cooling the concentrated solution to $20^{\circ}C$ with a $HNO_3$ recovery ratio of over 93%. We confirmed that only $Na_2SiF_6$ and $NaNO_3$ were manufactured by XRD analysis after drying these precipitants at $90^{\circ}C$. The precipitants demonstrated a purity of approximately 97% and 98% respectively. Therefore, the purity of the precipitants proved to be similar to that of commercial products.

Bioleaching of valuable metals from electronic scrap using fungi(Aspergillus niger) as a microorganism (곰팡이균(Aspergillus niger)을 이용(利用)한 전자스크랩중 유가금속(有價金屬)의 미생물(微生物) 침출(浸出) 연구(硏究))

  • Ahn, Jae-Woo;Jeong, Jin-Ki;Lee, Jae-Chun;Kim, Dong-Gin
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.24-31
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    • 2005
  • In order to recover valuable metals from fine-grained electronic waste, bioleaching of Cu, Zn, Al, Co, Ni, Fe, Sn and Pb were carried out using Aspergillus niger as a leaching microorganism in a shaking flask. Aspergillus niger was able to grow in the presence of electronic scrap. The formation of organic acids(citric and oxalic acid) from Aspergillus niger caused the mobilization of metals from waste electronic scrap. In a preliminary study, in order to obtain the data on the leaching of Cu, Zn, Al, Fe, Co and Ni from electronic scrap, chemical leaching using organic acid(Citric acid and Oxalic acid) was accomplished. At the electronic scrap concentration of 50 g/L, Aspergillus niger were able to leach more than 95% of the available Cu, Co. But Al, Zn, Pb and Sn were leached about 15-35%. Ni and Fe were detected in the leachate less than 10%.