• Title/Summary/Keyword: Waste Zero

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Study on the Solubility of U(VI) Hydrolysis Products by Using a Laser-Induced Breakdown Detection Technique (레이저유도파열검출 기술을 이용한 우라늄(VI) 가수분해물의 용해도 측정)

  • Cho, Hye-Ryun;Park, Kyoung-Kyun;Jung, Euo-Chang;Jee, Kwang-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.3
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    • pp.189-197
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    • 2007
  • The solubility of U(VI) hydrolysis products was determined by using a laser-induced breakdown detection (LIBD) technique. The experiments were carried out at uranium concentrations in range from $2{\times}10^{-4}\;M\;to\;4{\times}10^{-6}\;M$, pH values between 3.8 and 7.0, the constant ionic strength of 0.1 M $NaClO_4$ and the temperature of $25.0{\pm}0.1^{\circ}C$. The solubility product of U(VI) hydrolysis products was calculated from LIBD results by using the hydrolysis constants selected in NEA-TDB. The solubility product extrapolated to zero ionic strength, ${\log}K^{\circ}_{sp}=-22.85{\pm}0.23$ was calculated by using a specific ion interaction theory (SIT). The spectral features of ionic species in uranium solutions were investigated by using a conventional UV-visible absorption spectrophotometer and a fluorophotometer, respectively, $(UO_2)_2(OH)_2^{2+}\;and\;(UO_2)_3(OH)_5^+$ were dominant species at uranium concentration of $2{\times}10^{-4}\;M$.

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Safety evaluation of type B transport container for tritium storage vessel (B형 삼중수소 운반용기 안정성 평가)

  • Lee, Min-Soo;Paek, Seung-Woo;Kim, Kwang-Rag;Ahn, Do-Hee;Yim, Sung-Paal;Chung, Hong-Suk;Choi, Heui-Joo;Choi, Jeong-Won;Son, Soon-Hwan;Song, Kyu-Min
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.155-169
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    • 2007
  • A transport container for a 500 kCi tritium storage vessel was developed, which could be used for the transport of metal tritide from Wolsong TRF facility to a disposal site. The structural, thermal, shielding, and confinement analyses were performed for the container in a view of Type B. As a result of structural analysis, the developed container sustained its integrity under normal and accidental conditions. The maximum temperature increase of the inner storage vessel by radiation was evaluated at $134.8^{\circ}C at room temperature. In $800^{\circ}C$ fire test, The thermal barrier of container sustained the inner vessel at $405^{\circ}C after 30 min, which temperature was allowable for the container integrity since maximum design temperature of inner vessel was $550^{\circ}C. In the evaluation of the shielding, the activity of radiation was nearly zero on the outer surface of inner vessel. Consequently the transport container for a 500 kCi tritium was evaluated to pass all the safety tests including accidental condition, so it was concluded that the designed transport container is proper to be used.

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The Assessment of Toxicity on organic Sludge Using Acetylcholinesterase, Cytochrome P450, and Hsp70 Extracted from Earthworm (Eisenia fetida) (지렁이에서 추출한 Acetylcholinesterase, Cytochrome P450, and Heat Shock protein 70을 이용한 유기성슬러지 독성 평가)

  • Na, Young-Eun;Bang, Hae-Son;Kim, Myung-Hyun;Kim, Min-Kyoung;Roh, Kee-An;Lee, Jung-Taek;Ahn, Young-Joon;Yoon, Seong-Tak
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.274-279
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    • 2007
  • The toxicitiy of organic sludge such as municipal sewage sludge (MSS), industrial sewage sludge (ISS), alcohol fermentation processing sludge (AFPS) and leather processing sludge (LPS) were evaluated with three environmental biomarkers as acetylcholinesterase, cytochrome P450, and heat shock protein 70 extracted from earthworm (Eisenia fetida). Their toxicities were compared with those of pig manure compost (PMC). MSS, ISS, LPS, and AFPS did not significantly affect the acetylcolinesterase activity, whereas only the elutriate of PMC slightly was increased the activity. MSS, AFPS, and PMC tended to slightly inhibit the cytochrome $P_{450}$ activity, but ISS and LPS showed significantly the inhibitory effect on cytochrome $P_{450}$. The hsp70 expression began to increase after treatments and showed high induction at 6 hour, followed by zero level at around 12 hour. The quantity of the hsp70 expressed by elutriate treatments of PMC, AFPS, MSS, ISS, and LPS was 1.9, 3.0, 3.3, 4.4, and 4.7 fold higher than that of distilled water. These results indicate that in toxicity tests of five organic waste materials, four kinds of sludge materials appeared more toxic than PMC. Results of AChE, P450, and hsp70 of earthworm might be useful for expecting or assessing an effect by exposure of organic wastes to earthworms in soil.

Glass Dissolution Rates From MCC-1 and Flow-Through Tests

  • Jeong, Seung-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.257-258
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    • 2004
  • The dose from radionuclides released from high-level radioactive waste (HLW) glasses as they corrode must be taken into account when assessing the performance of a disposal system. In the performance assessment (PA) calculations conducted for the proposed Yucca Mountain, Nevada, disposal system, the release of radionuclides is conservatively assumed to occur at the same rate the glass matrix dissolves. A simple model was developed to calculate the glass dissolution rate of HLW glasses in these PA calculations [1]. For the PA calculations that were conducted for Site Recommendation, it was necessary to identify ranges of parameter values that bounded the dissolution rates of the wide range of HLW glass compositions that will be disposed. The values and ranges of the model parameters for the pH and temperature dependencies were extracted from the results of SPFT, static leach tests, and Soxhlet tests available in the literature. Static leach tests were conducted with a range of glass compositions to measure values for the glass composition parameter. The glass dissolution rate depends on temperature, pH, and the compositions of the glass and solution, The dissolution rate is calculated using Eq. 1: $rate{\;}={\;}k_{o}10^{(ph){\eta})}{\cdot}e^{(-Ea/RT)}{\cdot}(1-Q/K){\;}+{\;}k_{long}$ where $k_{0},\;{\eta}$ and Eaare the parameters for glass composition, pH, $\eta$ and temperature dependence, respectively, and R is the gas constant. The term (1-Q/K) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_{0},\;{\eta}\;and\;E_{a}$ are the parameters for glass composition, pH, and temperature dependence, respectively, and R is the gas constant. The term (1-Q/C) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_0$, and Ea are determined under test conditions where the value of Q is maintained near zero, so that the value of the affinity term remains near 1. The dissolution rate under conditions in which the value of the affinity term is near 1 is referred to as the forward rate. This is the highest dissolution rate that can occur at a particular pH and temperature. The value of the parameter K is determined from experiments in which the value of the ion activity product approaches the value of K. This results in a decrease in the value of the affinity term and the dissolution rate. The highly dilute solutions required to measure the forward rate and extract values for $k_0$, $\eta$, and Ea can be maintained by conducting dynamic tests in which the test solution is removed from the reaction cell and replaced with fresh solution. In the single-pass flow-through (PFT) test method, this is done by continuously pumping the test solution through the reaction cell. Alternatively, static tests can be conducted with sufficient solution volume that the solution concentrations of dissolved glass components do not increase significantly during the test. Both the SPFT and static tests can ve conducted for a wide range of pH values and temperatures. Both static and SPFt tests have short-comings. the SPFT test requires analysis of several solutions (typically 6-10) at each of several flow rates to determine the glass dissolution rate at each pH and temperature. As will be shown, the rate measured in an SPFt test depends on the solution flow rate. The solutions in static tests will eventually become concentrated enough to affect the dissolution rate. In both the SPFt and static test methods. a compromise is required between the need to minimize the effects of dissolved components on the dissolution rate and the need to attain solution concentrations that are high enough to analyze. In the paper, we compare the results of static leach tests and SPFT tests conducted with simple 5-component glass to confirm the equivalence of SPFT tests and static tests conducted with pH buffer solutions. Tests were conducted over the range pH values that are most relevant for waste glass disssolution in a disposal system. The glass and temperature used in the tests were selected to allow direct comparison with SPFT tests conducted previously. The ability to measure parameter values with more than one test method and an understanding of how the rate measured in each test is affected by various test parameters provides added confidence to the measured values. The dissolution rate of a simple 5-component glass was measured at pH values of 6.2, 8.3, and 9.6 and $70^{\circ}C$ using static tests and single-pass flow-through (SPFT) tests. Similar rates were measured with the two methods. However, the measured rates are about 10X higher than the rates measured previously for a glass having the same composition using an SPFT test method. Differences are attributed to effects of the solution flow rate on the glass dissolution reate and how the specific surface area of crushed glass is estimated. This comparison indicates the need to standardize the SPFT test procedure.

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Green-Split Coordination Strategy in Oversaturated Signal System (과포화교통상태에서의 SPLIT COORDINATION신호제어전략)

  • 이광훈
    • Journal of Korean Society of Transportation
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    • v.11 no.1
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    • pp.87-103
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    • 1993
  • The subject this paper is the signal control strategy under oversaturated conditions. The nature of traffic control for oversaturation is essentially different from the standard control modes. While under non-saturated situation traffic control is needed for the sake of safety and efficiency, the throughput is essential under oversaturated conditions. Therefore berth objective and strategies differ. For an oversaturated stream the cycle time and the signal offset are thought to be of rather secondary importance. For this case the green split may well be the most important control variable to serve the excessive demand. Up to now, however, most efforts have concentrated on the strategy with the concept which lies just on the extension of Webster's. "Green-split Coordination Strategy for Over-Saturated Networks", presents newly contrived three types of strategies named Forward-coordination, Backward-coordination and Network-coordination respectively and describes the algorithms with the evaluations. The forward coordination strategy treats the forward wave of flow between two signals. The aim is to prevent the outbreak of queue due to the accumulation of temporary excess of demand in near-saturation or saturation flow. The backward coordination strategy treats the backward rave of flow between two signals. The goal is to prevent the waste of green time caused by the exit block at the upstream signal. for this purpose a feedback regulation is provided of the upstream green-split so that the inflow-outflow balance is kept zero. The resultant surplus of green time is alloted to other signal stages. Also here the examination is made of the appropriate value of the feedback control parameter. The network coordination strategy is operated to maximize the network throughput in a specific direction applying a bang-bang control at the bottleneck intersection. This is a type of intervenient control for policy reasons. For this strategy the green-split coordinations, particuarly the backward coordination, are essential as the tactical elements. In order to evaluate the preposed strategies those are compared with the latest existing strategy called saturation-degree-ratio control by the simulation experiments in an assumed 4$\times$4 grid network. The results are satisfactory showing a 10-15% reduction in delays and a 15% increase in network capacity.

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Impact of Media Type and Various Operating Parameters on Nitrification in Polishing Biological Aerated Filters

  • Ha, Jeong-Hyub;Ong, Say-Kee;Surampalli, R.
    • Environmental Engineering Research
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    • v.15 no.2
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    • pp.79-84
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    • 2010
  • Three biological aerated filters (BAFs) composed of a PVC pipe with a diameter of 75 mm were constructed and operated at a waste-water temperature at $13^{\circ}C$. The media used for each BAF were: 5-mm gravel; 5-mm lava rock; 12.5-mm diameter by 15-mm long plastic rings, all with a media depth of 1.7 m. The feedwater, which simulated the effluent of aerated lagoons, had influent soluble chemical oxygen demand (sCOD) and ammonia concentrations of approximately 50 and 25 mg/L, respectively. For a hydraulic retention time (HRT) of two hours without recirculation, ammonia percent removals were 98.5, 98.9, and 97.8%, for the gravel, lava rock, and plastic rings, respectively. By increasing the effluent recirculation from 100 to 200% for an HRT of one hour, respective ammonia removals improved from 90.1 to 96, 76.5 to 90, and 65.3 to 79.5% for gravel, lava rock, and plastic rings. Based on the ammonia and sCOD loadings for different HRTs, the estimated maximum ammonia loading was approximately 0.6 kg $NH_3-N/m^3$-day for the three BAFs of different media types. The zero-order biotransformation rates for the BAF with gravel were found to be higher than the lava rock and plastic ring media. The results ultimately showed that BAF can be used as an add-on system to aerated lagoons or as a secondary treatment unit to meet ammonia discharge limits.

A Case Study and Product Planning Characteristics of Global Eco-fashion Brands (글로벌 에코패션 브랜드의 현황과 상품기획 특성)

  • Ha, Seung-Yeon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.16 no.3
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    • pp.219-238
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    • 2014
  • This study attempted to investigate present condition and product planning of global eco-fashion brands that harmonize fashion and sustainability. As research subjects, this study selected 97 oversea fashion brands mentioned in books related to eco-fashion, Black(2011), Brown(2010), Fuad-luke(2009). As for research methods, materials and ethical practices of these selected 97 brands through literature data and their internet site homepages. This study analyzed oversea eco-brands collected 26 British brands, 22 American brands, 36 European brands such as Germany, France, Italy, Sweden, Spain, Finland and so on, except Britain and 13 other regions including Japan, India, Canada, Mexico, and New zealand. In conclusion, the product planning characteristics of these oversea eco-fashion brands can be summarized as follows; community and fair trade, ecological and slow design, recycle, reuse, redesign, and new eco-models. Firstly, brands of 'community and fair trade' manufactured products through fair trade and local community's artisan by ethical practices with organic fabrics. Secondly, brands of 'ecological and slow design' pursued timeless design and multi-functional design as luxury eco-fashion styles. They used organic textiles, hemp, bamboo, soya, tencell, sea cell, and self-sustaining plants. Thirdly, brands of 'recycle, reuse, redesign' aimed for upcycling high-end fashion and used vintage clothes, textile scraps, PET, parachutes, tires, safety belts, advertising banner and so on. In addition, brands of 'new models as eco-fashion' suggested zero-waste cutting, recycling over-printing technology, new sustainable business model, and ethical practices in the supply chain of the fashion industry.

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Characteristic of Cabin Temperature According to Thermal Load Condition of Heat Pump for Electric Vehicle (전기자동차용 히트펌프의 열 부하 조건에 따른 캐빈온도 특성)

  • Park, Ji Soo;Han, Jae Young;Kim, Sung-Soo;Yu, Sang Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.2
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    • pp.85-91
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    • 2016
  • The Positive Temperature Coefficient (PTC) is used for cabin air heating of a battery electric vehicle, which is different from conventional vehicles. Since the PTC heater consumes a large quantity of power in a parasitic manner, many valuable studies have been reported in the field of alternative heat pumps. In this study, a model for an R134a heat pump taking into account the thermal environment of the cabin was developed for a MATLAB/SIMULINK(R) platform. Component and cabin models are validated with reference values. Results show that the heat pump is more competitive for parasitic power consumption over all ambient temperature conditions. Additionally, the method of waste heat recovery to overcome disadvantages when temperatures are below zero is applied to efficiently operate the heat pump.

Simulation of Particle Behaviors within a Multi-stage Impact Crusher using Discrete Element Method (이산요소법을 이용한 다단 임팩트 파쇄기 내 입자 거동 모사)

  • Yu, Myoungyuol;Lee, Hoon
    • Resources Recycling
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    • v.27 no.3
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    • pp.86-92
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    • 2018
  • The amount of construction waste generated is steadily increasing every year, and the Law for Promotion of Recycling is enacted. However, it is difficult to use it as a recycled aggregate for concrete, which is presented in the quality standard of recycled aggregate with high water uptake and low density due to low separation of aggregate between concrete and cement paste. Therefore, in this study, a multi-stage impact crusher was used to remove mortar, which is essential for improving the quality of recycled aggregate. In analyzing the characteristics of the equipment, the spectrum of energy generated in each part between the particle and the equipment was calculated by using DEM. In order to generate an effective separation phenomenon, it was confirmed that the operation condition of 900 RPM was appropriate based on the ratio of the number of collisions (L/H) of the low energy group (L) to the number of collisions of the high energy group (H).

Legal and Regulating Improvement for Distribution of Used Medical Equipments (중고 의료기기의 유통에 대한 법적 규제 개선)

  • Choi, Yong Jeon;Kwon, Jun Cheol;Jung, Yong Gyu
    • Journal of Service Research and Studies
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    • v.4 no.1
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    • pp.109-121
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    • 2014
  • Used medical equipment utilized in medical technology, most are not human or environmental risks likely to in normal medical technology. Therefore, the risk is close to zero so that medical devices are classified into Class 1 medical device, such as little or no risk by treating. It can be minimized without arising unnecessary and waste of time. As handlers in the medical device vendors are expanding the area of the business, we can uplift operators' commitment to the business and for the people's choice. In this paper, our research are presented to improve the legal and regulatory directions for the distribution of used medical devicesin in order to establish and promote a fair deal of diversity.

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