• 한국환경보건학회지
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• 제26권4호
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• pp.38-44
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• 2000

Compared to other waste, waste tire has much discharge quantity and calorie. When we use waste heat from waste tire, it can be definitely better substitute energy than coal and anthracite in high oil price age. To use as a basic data for providing low cost and highly effective heating system, following conclusion was founded. Annual waste tire production was 19,596 million in 1999, Recycling ratio was almost 55% and more than 8.78 million was stored. Waste tire has lower than 1.5% sulfur contain ratio which is resource of an pollution, So it is a waste fuel which can be combustion based on current exhaust standard value without any extra SOx exclusion materials. Waste tire has 9,256Kcal/kg calorific value and it is higher than waste rubber, waste rubber, waste energy as same as B-C oil. When primary and second air quantity was 1.6, 8.0 Nm$^3$/min, dry gas production time was 270min and total combustion time was 360 min. In the SOx, NOx, HC of air pollution material density were lower than exhaust standard value at the back of cyclone and dusty than exhaust standard value without dust collector.

• 대한기계학회논문집
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• 제18권7호
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• pp.1833-1839
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• 1994

Experiments have been carried out to investigate the burning characteristics of waste tires in high temperature environments. The burning of waste tire chips consists of four stages ; evaporation of volatile matters, ignition, burning of volatile matters, and burning of solid carbon. Burning time of waste tire chips depends on the gas temperature and the initial weight of the chip. However, the environments. In the ceramic matrix burner with a ceramic radiation shield, the burning time of the waste tire chips becomes shorter than that without the shield. This is due to the increase in heat transfer to the tire chips by radiation.

• Journal of Biosystems Engineering
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• 제25권6호
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• pp.481-488
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• 2000

This study was initiated in order to find alternative fuel substituting for light oil the most common fuel for heating greenhouse. The tire oil used in this research was produced by pyrolysis process, one of the final products besides steel string and carbon black in which waste tires as a form of chopped pieces broken by shredding machine are heated up to 200~30$0^{\circ}C$ with maximum restraining of oxygen supply. In order to justify light oil equivalent qualities in tire oil combustion characteristics were defined in the way of comparing kinetic viscosities in the wide range of temperature flame sizes and exhaust gas components in the various combustion conditions. We found that kinetic viscosity of tire oil was lower than light oil by 1 to 2 cSt in the temperature range showing better flowing mobility in the fuel line of the burner and no significant difference in flame size between the two oils in the all combustion treatments. However much more NO and SO$_2$ were detected from the exhaust gases of tire oil than light oil combustions. In fact tire oil contains more nitrogen and total sulfur, by 25 times and 40 times respectively than light oil according to the composition analysis. Tolerable limit for SO$_2$discharge amount defined by the national air pollution standards is under 540ppm so tire oil combustion satisfies the requirement though. It is desirable if sulfur and nitrogen filtering process shall be added in the tire oil production line. Except the exhaust gas components all greenhouse heating qualities of tire oil including hot air temperature are very identical to those of light oil.

• 청정기술
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• 제5권1호
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• pp.42-48
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• 1999

폐타이어는 환경 문제와 관련하여 오염과 재활용의 양면성을 지니고 있다. 이와 같은 폐타이어를 재활용의 측면에서 고온의 열플라즈마를 이용하여 열분해하여 가연성 가스로의 전환을 시도하였다. 폐타이어를 산소가 배제된 상태에서 열분해하여 $CH_4$, $C_2H_2$, $C_4H_{10}$등과 같은 저분자량의 탄화수소가 주성분인 가연성 가스가 다량 발생함을 GC를 이용하여 확인할 수 있었다. 타이어의 공급량이 증가할수록 가연성 가스의 구성에서 $CH_4$의 비율이 증가하였으며, 플라즈마 전력이 증가할수록 $C_2H_2$가 증가함을 확인하였다. 발생가스는 $C_4H_{10}$ 또는 $C_2H_2$등의 탄화수소가 주를 이루었으며 그 비율은 70%이상이었다. 한편 char의 온도에 따른 질량 감소 경향을 TG로 분석하여 열플라즈마 내에서 타이어의 열분해 경향을 간접적으로 유추할 수 있었다.

• 환경위생공학
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• 제15권4호
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• pp.98-104
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• 2000

Commercial rubber(IR, NR, BR), SBR, and tire were degraded by thermal degradation process. The oil yield of rubbers and tire ranges about 37~86%, it was increased with increase of operation temperature in pyrolysis. And the yield of pyrolytic oil was increased with increase of heating rate. The maximum oil yields of IR, NR, BR, SBR, and tire were 80, 73, 83, 86 and 55% each at $700^{\circ}C$ with a heating rate of $20^{\circ}C$/min, respectively. The pyrolytic oil components were consisted of about 50 aromatic compounds. The calorific value of purolytic oil of commercial rubber, SBR, and tire was measured by calorimeter, it was 39~40 kJ/g. The BET surface area of pyroblack was $47~63m^2/g$. The optimum condition of pyrolysis was operating temperature of $700^{\circ}C$ with heating rate of $20^{\circ}C$. Therefore, the pyrolytic oil and pyroblack are possible to alternative fuel and carbon black.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.157-160
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• 2008

본 연구에서는 디스크 이동식 폐타이어 열분해 실증 설비(10톤/일)를 설계, 제작 그리고 시운전을 통하여 열분해 설비의 안정적인 연속 운전이 가능함을 확인하였다. 시운전 결과 반응기 내부 온도는 $500{\sim}600^{\circ}C$, 내부 압력은 $-80{\sim}-100mmHg$, 체류시간은 $60{\sim}90min$ 범위에서 안정적인 열분해가 일어났다. 또한 이번 과제 수행을 통해NC 가스의 연소기를 개발 적용하여 NC 가스의 열분해 열원으로 사용 가능성을 확인하였으며, NC 가스 연소 시 대기 측정을 통하여 규제치도 만족함을 확인할 수 있었다. 지금까지 나온 결과는 장기 연속 운전과 scale-up을 위한 기초 자료가 될 것이다.

• 한국자원리싸이클링학회:학술대회논문집
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• 한국자원리싸이클링학회 1993년도 EARTH 발표논문초록
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• pp.13.1-13
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• 1993

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 2000년도 하계 학술대회 논문집
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• pp.124-129
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• 2000

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.471-474
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• 2008

The pyrolytic behavior of waste tire under microwave heating was investigated. Experiments were conducted using a lab- and bench-scale system to delineate the effects of microwave output power on the response. As the results of experiments, it was found that as the microwave output power was increased between 0.84 and 3.04 kW/kg, the oil yield and required time rapidly increased and decreased, respectively. With further increase of the microwave output power, the oil yield and required time did not change significantly.

• 자원리싸이클링
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• 제22권2호
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• pp.11-17
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• 2013

폐타이어를 열분해하여 오일을 회수하는 공정에서 배출되는 다량의 탄소 잔류물을 활용하는 기술은 환경과 경제성 측면에서 매우 중요하다. 본 연구에서는 폐타이어 열분해 과정에서 배출되는 탄소 잔류물을 활용하여 활성탄으로 재활용이 가능한지 파악하고자 하였다. 이를 위해서 폐타이어 열분해 상용화 공정에서 발생하는 탄소 잔류물의 특성을 분석하였다. 아울러 탄소 잔류물을 $600^{\circ}C$와 $800^{\circ}C$에서 1시간 탄화 한 후, $950^{\circ}C$에서 3시간 활성화하여 기공특성 변화를 살펴보았다. 탄소잔류물의 비표면적은 $8.0m^2/g$이었으나, 탄화와 활성화 과정을 거치면서 비표면적이 $548.3m^2/g$로 급격히 증가함을 확인할 수 있었다.