• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.223-226
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• 2009

In this study, we investigated the recovery of copper and synthetic fuel from the waste wire by low temperature pyrolysis which can overcome problems of the recent incineration methods. Through thermal decomposition process of waste wire, we achieved the big advantage of getting usable resources as the forms of copper and fuel with a very high value. The TG/DTA and small-scale reaction experiments were carried out to determine an optimum temperature for waste wire pyrolysis. And the pyrolysis was done at 350, 450, and $550^{\circ}C$, respectively, and heating rate of the TG/DTA was $5^{\circ}C/min$ untill $700^{\circ}C$. The result shows that the optimum temperature range for dehydrochlorination of PVC was $280{\sim}350^{\circ}C$, as a lower temperature range than $400{\sim}550^{\circ}C$ of PE and PP. Practically over 95% of copper metal and synthetic fuel, which has the 8027 kcal/kg as a calorific value, were recovered from the waste wire samples.

• Plant Journal
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• v.4 no.4
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• pp.62-70
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• 2008

PGV(Plasma Gasification & Vitrification) system has been developed based on a pyrolysis melting gasification technology that provides the possibilities of acquiring renewable energy. As volume of wastes increases with the rapid industrialization and population growth, eco friendly disposal is drawing more social attention. Pyrolysis plasma technology is regarded as the best environmentally friendly process for the waste disposal among numerous waste disposal processes. Introduced in this paper is the behavior of the plasma torch and a computational fluid simulation dynamics is discussed for designing the melting furnace. Some PGV applications have also been discussed.

• Journal of environmental and Sanitary engineering
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• v.17 no.3
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• pp.60-66
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• 2002

Iksan city is planning to construct a waste incinerator on the site of about $110,000\textrm{m}^2$ in size that will be selected from a public bid(Oct.~Nov.2002)in the wake of expiration by June 2003 of use for Hamyeol fill-up ground. Science it has usually been difficult to find sites for filling-up or incinerating facilities owing to NIMBY phenomenon, it is badly requested to employ up-to-date technology for processing wastes without environmental pollution. The conflicts between the administrative authorities and community people with regard to construction of incineration facilities, fill-up ground and facilities for waste processing or recycling are not the matters of just today but are increasingly deepening and spreading countrywide. There seems to be no prospect for these conflicts to be amicably settled through dialogues. They rather become a social disease inflicting the whole country like an epidemic. It is therefore believed to be necessary to introduce measures to design and build environment-friendly facilities that may be accepted by residents as not abominable ones but be used as amusing place while they watch the daily operation of them as watchdogs. Iksan city's plan to construct environment-friendly waste incineration facilities of pyrolysis type without chimney has undergone the process of public hearings and explanatory gatherings from every class of Iksan citizens to get consensus but is still delayed due mainly to be the failure of inducing foreign investments. Pyrolysis technology has two advantages ; first, environment-friendly due to less emission of second pollutants ; second, production of by-products highly valuable as resources. It Is known that Germany has recently begun installation and operation of pyrolysis facility urban wastes, an evidence indicating that pyrolysis method will be widely applied to cope with the tightened regulation to preserve environment worldwide.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.601-607
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• 2023

Pyrolysis oil (C5-C20) produced using plastic non-oxidative pyrolysis technology produces naphtha oil (C5-C10) through a separation process, and naphtha oil produces hydrogen through a reforming reaction to secure economic efficiency and social and environmental benefits. In this study, waste plastic pyrolysis oil was subjected to a steam reforming reaction on a commercialized catalyst of 46-3Q And it was found that the 46-3Q catalyst reformed the pyrolysis oil to produce hydrogen. Therefore, an experiment was performed to increase hydrogen yield and minimize the byproduct of ethylene. The reaction experiment was performed using actual waste plastic oil (C8-C11) with temperature, steam/carbon ratio (S/C) ratio, and space velocity as variables. We studied reaction conditions that can maximize hydrogen yield and minimize ethylene byproducts.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.243-250
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• 2003

The present study discuss about numerical methods to analyze design parameters of pyrolysis-melting incineration system. Various numerical methods of different viewpoint are introduced to simulate the performance of the system. Process analysis of the overall system is the beginning procedure of basic design process. Heat and material flow of each element are connected and are influential to each other, hence, an appropriate process modeling should be executed to prevent from unacceptable process design concepts that may results in system failure. Models to simulate performance of each elementary facility generate valuable informations on design and operation parameters, and, derive the basic design concept to be optimized. A pyrolysis model derived from waste bed combustion model is introduced to simulate the mass conversion and heat transfer in the pyrolysis process. CFD(Computational fluid dynamics) is an effective method to optimize the thermal reacting flow in various reactors such as combustor and heat exchanger. Secondary air jets arrangement and the shape of the combustor could be optimized by CFD technology.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.36-43
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• 2024

Fishing net waste (FNW) constitutes over half of all marine plastic waste and is a major contributor to the degradation of marine ecosystems. While current treatment options for FNW include incineration, landfilling, and mechanical recycling, these methods often result in low-value products and pollutant emissions. Importantly, FNWs, comprised of plastic polymers, can be converted into valuable resources like syngas and pyrolysis oil through pyrolysis. Thus, this study presents a process for generating high-purity hydrogen (H₂) by catalytically pyrolyzing FNW in a CO₂ environment. The proposed process comprises of three stages: First, the pretreated FNW undergoes Ni/SiO₂ catalytic pyrolysis under CO₂ conditions to produce syngas and pyrolysis oil. Second, the produced pyrolysis oil is incinerated and repurposed as an energy source for the pyrolysis reaction. Lastly, the syngas is transformed into high-purity H₂ via the Water-Gas-Shift (WGS) reaction and Pressure Swing Adsorption (PSA). This study compares the results of the proposed process with those of traditional pyrolysis conducted under N₂ conditions. Simulation results show that pyrolyzing 500 kg/h of FNW produced 2.933 kmol/h of high-purity H₂ under N₂ conditions and 3.605 kmol/h of high-purity H₂ under CO₂ conditions. Furthermore, pyrolysis under CO₂ conditions improved CO production, increasing H₂ output. Additionally, the CO₂ emissions were reduced by 89.8% compared to N₂ conditions due to the capture and utilization of CO₂ released during the process. Therefore, the proposed process under CO₂ conditions can efficiently recycle FNW and generate eco-friendly hydrogen product.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.8
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• pp.4028-4032
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• 2013

Recycling method for pyrolyzed carbon black from pyrolysis process of waste tires is needed. Carbon black from pyrolysis of waste tires was used to modify and improve the permanent deformation properties of asphalt binder. 0%, 5%, 10%, 15% and 20% of pyrolyzed carbon black was mixed. Couple of laboratory tests, such as softening point, flash point test, rotational viscometer test and dynamic shear rheometer test, were carried out. The use of pyrolyzed carbon black incresed the softening point, rotational viscosity at 135oC, and resistance of permanent deformation.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.4
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• pp.29-35
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• 2009

Pyrolysis is recently used as one of alternative methods of animal waste treatment. In this study bio-oil was produced at $550^{\circ}C$ in an auger reactor through pyrolysis process. Two pig waste mixtures were used, pig feces mixed with rice husks and pig feces mixed with sawdust. The main compositions of hemicellulose, lignin, cellulose, protein, and fat were analyzed chemically. Based on the main composition results obtained, the contents of holocellulose (the sum of hemicellulose and cellulose) and lignin had a significant positive effect on bio-oil production, and there was a significant negative effect of ash content on bio-oil yield. The interactions between the different feedstocks were evaluated, and it was concluded that the interaction between pig feces and rice husks was minimal, whereas the interaction between pig feces and sawdust was significant.

• Proceedings of the Materials Research Society of Korea Conference
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• 2001.05a
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• pp.24-24
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• 2001

• Polymer Science and Technology
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• v.9 no.6
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• pp.473-478
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• 1998