• 에너지공학
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• 제26권1호
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• pp.62-67
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• 2017

Limestone is an important commodity in Philippines. Limestone has numerous uses that range from agricultural applications to building materials to medicines. Many limestone products require rock with specific physical and chemical characteristics. Most limestone is biochemical in origin meaning the calcium carbonate in the stone originated from shelled oceanic creatures. In this paper, we reported the natural sources of limestone, geological formation of limestone and the oyster shell waste in Cebu, Bantayan, Philippines were reported. Due to the mining or quarrying in Cebu, Bantayan, in a limestone area poses the threat of groundwater pollution (since limestone is a porous geologic formation with a high transmissivity). The other environmental issue is oyster shell waste. The oyster shell waste is the major source of limestone. We developed and applied appropriate technologies for the extraction of limestone from oyster shell waste and utilizes as high value added material.

• 에너지공학
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• 제27권1호
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• pp.59-64
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• 2018

In this paper, we investigated the alternative sources of limestone. Oyster shell waste originated from aquaculture that causes a major disposal landfill problem in coastal sectors in southeast Korea. Their inadequate disposal causes a significant environmental problems araised. Bio mineralization leads to the formation of oyster shells and consists $CaCO_3$ as a major phase with a small amount of organic matter. It is a good alternative material source instead of natural lime stone. The utilization of oyster shell waste for industrial applications instead of natural limestone is major advantage for conservation of natural limestone. The present work describes the limestone and oyster shells hydraulic activity and chemical composition and characteristics are most similar for utilization of oyster shell waste instead of natural limestone.

• 한국건축시공학회지
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• 제7권1호
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• pp.85-90
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• 2007

According as industry develops rapidly, problem of resources exhaustion and environmental pollution is appearing. Way to use construction waste that is development of new compound material and Industry product is required. Limestone powder that is Industry product is $CaCO_3$. and vicosity is promotion effect because there is no damage to hydration of cement and powder is very thin and water tightness increases. This research purposed to analyze concrete property changing limestone fineness. According as the limestone powdered replacement ratio increases, slump and unit capacity mass increased, and the air content decreased according as the replacement ratio increases. Compressive strength and tensile strength decreased according as the limestone powder replacement ratio increases.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.107-108
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• 2021

In the global trend of countries around the world announcing the declaration of carbon neutrality, the development of low-carbon cement in the cement industry can be seen as a very important issue that can determine the future development of the cement industry in the future. Therefore, this study evaluated the strength characteristics of limestone cement paste with limestone powder of CaCO3 and refinery desulfurization waste catalyst of high Al₂O₃ content, and using a Minitab mixture design to optimize a limestone cement content. As a resuls it was confirmed that limestone cement paste with 5-10% of limestone powder and 1.25-2.5% of the waste catalyst exhibits similar compressive strength to that of OPC.

• 한국건축시공학회지
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• 제14권2호
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• pp.187-194
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• 2014

With environmental regulations continuously being strengthened internationally the need to control environmental pollution and environmental load is emerging in Korea. The purpose of this study is to seek methods or using waste cementitious powder as an alternative raw material for limestone through the optimization of raw material and to quantitatively analyze the resulting reduction of $CO_2$ emission in order to contribute to solving the issue of waste, which is the biggest issue in relation to construction and global warming. The results of the study, show that waste cementitious powder can be used as an alternative raw material for limestone at OPC level, but it was also found that mixing fine aggregate cementitious powder into waste cementitious powder significantly affected the substitution rate for limestone with waste cementitious powder and the reduction of greenhouse gas. In particular, when fine aggregate cementitious powder was used at a rate of 0~20%, the substitution rate for limestone and the reduction in the rate of greenhouse gas emission was significantly reduced. It is thought that a technique to efficiently separate and discharge the fine aggregate cementitious powder mixed in waste cementitious powder needs to be developed in the future.

• 자원리싸이클링
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• 제31권6호
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• pp.3-17
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• 2022

이산화탄소 배출량 및 에너지 사용이 많은 시멘트 산업은 탄소중립 실현 및 지속적인 발전을 위한 전략이 필요하다. 에너지 효율 향상을 위해 국내 대부분의 시멘트 업체에서 폐열 회수 시스템을 구축하여 전력을 생산하고 있으나, 이와 관련된 에너지 재활용 연구는 거의 없는 실정이다. 시멘트 생산이 많은 국가에서는 기존의 폐열 회수 시스템을 보완하기 위해 온도에 따라 적용하는 랭킨사이클 변경, 작동유체 비교, 2단 이상의 랭킨 사이클 적용 및 타 산업과의 연계 등을 통해 폐열 회수를 극대화하기 위한 연구를 수행하는 것으로 확인되었다. 본 연구에서는 국내외 시멘트 산업에서의 폐열 회수 및 활용에 대해 정리하여 에너지 효율 향상을 위해 필요한 연구 방향을 도출하고자 하였다.

• 자원리싸이클링
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• 제12권2호
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• pp.11-20
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• 2003

폐석회석을 투수 콘크리트용 골재로 활용하여 콘크리트의 공극률, 연속공극률, 투수계수, 압축강도 및 휨강도 등을 측정하였으며,투수 콘크리트의 공극특성과 강도와의 관계에 대하여 고찰하였다. 투수 콘크리트의 공극 및 강도특성은 폐석회석 혼합률에 의한 영향 보다는 골재입자의 크기 및 골재입자 사이의 공극에 의한 영향이 크게 작용하였다. 투수 콘크리트의 공극률과 연속공극률과의 관계 및 공극특성과 강도와의 관계도 양호한 선형관계를 나타내었다. 또한, 폐석회석을 사용한 투수 콘크리트의 투수계수는 0.2cm/sec 이상의 양호한 결과로 보통골재에 비하여 투수성능이 우수하였으며, 강도결과와 종합해 보면 폐석회석을 보도용 콘크리트 또는 식생, 수자원 정화 콘크리트 등으로 활용될 수 있을 것으로 기대되었다.

• Advances in concrete construction
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• 제10권6호
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• pp.463-478
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• 2020

Multiple mathematical modeling for prediction of slump, compressive strength and depth of water penetration at 28 days were performed using statistical analysis for the concrete containing waste limestone powder as partial replacement of sand obtained from experimental program reported in this research. To extract experimental data, 180 concrete cubic samples with 20 different mix designs were investigated. The twenty non-linear regression models were used to predict each of the concrete properties including slump, compressive strength and water depth penetration of concrete with waste limestone powder. Evaluation of the models using numerical methods showed that the majority of models give acceptable prediction with a high accuracy and trivial error rates. The 15-term regression models for predicting the slump, compressive strength and water depth were found to have the best agreement with the tested concrete specimens.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.331-336
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• 2001

Aragonite type of precipitated calcium carbonate was synthesized by the successive reaction with hybridization of waste scallop shells with limestone. In the first step, carbonation was performed by using calcined limestone with low brightness, followed by the additional carbonation using calcined-hydrous scallop shells with high brightness. The temperature and the amount ratio of calcined limestone to calcined-hydrous scallop shells were examined as parameters in the experimental conditions. The products were characterized by XRD, SEM. in addition to measurements of brightness index. the specific surface area, and bulk density. The amount ratio of limestone to scallop shell affected not only the brightness but also morphologies of products. The increase in relative amounts of limestone leads to decrease in brightness and bumpy surface of particles. High temperature reaction produces aragonite particles with longer sizes and higher bulk densities. This study has made an attempt to establish the synthesis of aragonite with high brightness and high strength by utilization of waste scallop shells.

• 한국환경과학회지
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• 제11권10호
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• pp.1089-1096
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• 2002

The objectives of this study were to investigate the desulfurization kinetics of paper sludge and limestone in a fluidized bed reactor according to bed temperature and air velocity. The experimental results were presented as follows ; First, the bed temperature had a great influence on the desulfurization efficiency of limestone and paper sludge. In paper sludge, the optimum condition in desulfurization temperature was at 80$0^{\circ}C$ and in limestone, that was at 850 $^{\circ}C$ or 900 $^{\circ}C$ Second, as air velocity increased, the desulfurization efficiency(or the absorbed amount of sulfur dioxide) by limestone and paper sludge decreased. And the absorbed amount of sulfur dioxide by paper sludge was larger than that of by limestone. Third, as the velocity increased and the optimum desulfurization temperature became, ks and the removal efficiency increased. So, ks, kd highly depended on the air velocity and bed temperature.