• Journal of Energy Engineering
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• v.26 no.1
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• pp.62-67
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• 2017

Limestone is an important commodity in Philippines. Limestone has numerous uses that range from agricultural applications to building materials to medicines. Many limestone products require rock with specific physical and chemical characteristics. Most limestone is biochemical in origin meaning the calcium carbonate in the stone originated from shelled oceanic creatures. In this paper, we reported the natural sources of limestone, geological formation of limestone and the oyster shell waste in Cebu, Bantayan, Philippines were reported. Due to the mining or quarrying in Cebu, Bantayan, in a limestone area poses the threat of groundwater pollution (since limestone is a porous geologic formation with a high transmissivity). The other environmental issue is oyster shell waste. The oyster shell waste is the major source of limestone. We developed and applied appropriate technologies for the extraction of limestone from oyster shell waste and utilizes as high value added material.

• Journal of Energy Engineering
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• v.27 no.1
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• pp.59-64
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• 2018

In this paper, we investigated the alternative sources of limestone. Oyster shell waste originated from aquaculture that causes a major disposal landfill problem in coastal sectors in southeast Korea. Their inadequate disposal causes a significant environmental problems araised. Bio mineralization leads to the formation of oyster shells and consists $CaCO_3$ as a major phase with a small amount of organic matter. It is a good alternative material source instead of natural lime stone. The utilization of oyster shell waste for industrial applications instead of natural limestone is major advantage for conservation of natural limestone. The present work describes the limestone and oyster shells hydraulic activity and chemical composition and characteristics are most similar for utilization of oyster shell waste instead of natural limestone.

• Journal of the Korea Institute of Building Construction
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• v.7 no.1 s.23
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• pp.85-90
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• 2007

According as industry develops rapidly, problem of resources exhaustion and environmental pollution is appearing. Way to use construction waste that is development of new compound material and Industry product is required. Limestone powder that is Industry product is $CaCO_3$. and vicosity is promotion effect because there is no damage to hydration of cement and powder is very thin and water tightness increases. This research purposed to analyze concrete property changing limestone fineness. According as the limestone powdered replacement ratio increases, slump and unit capacity mass increased, and the air content decreased according as the replacement ratio increases. Compressive strength and tensile strength decreased according as the limestone powder replacement ratio increases.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.107-108
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• 2021

In the global trend of countries around the world announcing the declaration of carbon neutrality, the development of low-carbon cement in the cement industry can be seen as a very important issue that can determine the future development of the cement industry in the future. Therefore, this study evaluated the strength characteristics of limestone cement paste with limestone powder of CaCO3 and refinery desulfurization waste catalyst of high Al₂O₃ content, and using a Minitab mixture design to optimize a limestone cement content. As a resuls it was confirmed that limestone cement paste with 5-10% of limestone powder and 1.25-2.5% of the waste catalyst exhibits similar compressive strength to that of OPC.

• Journal of the Korea Institute of Building Construction
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• v.14 no.2
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• pp.187-194
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• 2014

With environmental regulations continuously being strengthened internationally the need to control environmental pollution and environmental load is emerging in Korea. The purpose of this study is to seek methods or using waste cementitious powder as an alternative raw material for limestone through the optimization of raw material and to quantitatively analyze the resulting reduction of $CO_2$ emission in order to contribute to solving the issue of waste, which is the biggest issue in relation to construction and global warming. The results of the study, show that waste cementitious powder can be used as an alternative raw material for limestone at OPC level, but it was also found that mixing fine aggregate cementitious powder into waste cementitious powder significantly affected the substitution rate for limestone with waste cementitious powder and the reduction of greenhouse gas. In particular, when fine aggregate cementitious powder was used at a rate of 0~20%, the substitution rate for limestone and the reduction in the rate of greenhouse gas emission was significantly reduced. It is thought that a technique to efficiently separate and discharge the fine aggregate cementitious powder mixed in waste cementitious powder needs to be developed in the future.

• Resources Recycling
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• v.31 no.6
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• pp.3-17
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• 2022

The cement industry, which is an energy-intensive and high carbon dioxide emission industry, requires strategy for carbon neutrality and sustainable development. Most domestic cement companies are generating electricity by waste heat recovery system to improve energy efficiency during cement processes; however, few studies exist on recycling of energy related to this. Certain countries with high cement production researched on modifying the conventional waste heat recovery system to maximize waste heat recovery using various methods such as applying the Rankine cycle depending on the temperature, comparing working fluids, applying two or more Rankine cycles, and combining with other industries. In this study, we reviewed the research direction for energy efficiency improvement by summarizing waste heat recovery and utilization methods in the domestic and overseas cement industries.

• Resources Recycling
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• v.12 no.2
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• pp.11-20
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• 2003

Limestone mine waste was used as a aggregate far permeable concrete. Void ratio, continuous void ratio, coefficient of permeability, compressive strength and flexural strength of concrete were measured and then the relationship between porosity and strength properties was investigated. Void ratio, continuous void ratio and strength properties of permeable concrete were greatly influenced by the grain size of aggregate and void filling ratio in comparison with the containing ratio of limestone mine waste. Furthermore, void ratio showed a good relation with continuous void ratio, and porosity of permeable concrete indicated a good relation with strength properties also. The coefficient of permeability of permeable concrete using limestone waste was over 0.2 cm/sec and was excellent result in comparison with normal concrete. Therefore, it could be expected that the limestone mine waste would be utilized as aggregate for pavement concrete, green concrete and water resource specie concrete in the results of this study.

• Advances in concrete construction
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• v.10 no.6
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• pp.463-478
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• 2020

Multiple mathematical modeling for prediction of slump, compressive strength and depth of water penetration at 28 days were performed using statistical analysis for the concrete containing waste limestone powder as partial replacement of sand obtained from experimental program reported in this research. To extract experimental data, 180 concrete cubic samples with 20 different mix designs were investigated. The twenty non-linear regression models were used to predict each of the concrete properties including slump, compressive strength and water depth penetration of concrete with waste limestone powder. Evaluation of the models using numerical methods showed that the majority of models give acceptable prediction with a high accuracy and trivial error rates. The 15-term regression models for predicting the slump, compressive strength and water depth were found to have the best agreement with the tested concrete specimens.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.331-336
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• 2001

Aragonite type of precipitated calcium carbonate was synthesized by the successive reaction with hybridization of waste scallop shells with limestone. In the first step, carbonation was performed by using calcined limestone with low brightness, followed by the additional carbonation using calcined-hydrous scallop shells with high brightness. The temperature and the amount ratio of calcined limestone to calcined-hydrous scallop shells were examined as parameters in the experimental conditions. The products were characterized by XRD, SEM. in addition to measurements of brightness index. the specific surface area, and bulk density. The amount ratio of limestone to scallop shell affected not only the brightness but also morphologies of products. The increase in relative amounts of limestone leads to decrease in brightness and bumpy surface of particles. High temperature reaction produces aragonite particles with longer sizes and higher bulk densities. This study has made an attempt to establish the synthesis of aragonite with high brightness and high strength by utilization of waste scallop shells.

• Journal of Environmental Science International
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• v.11 no.10
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• pp.1089-1096
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• 2002

The objectives of this study were to investigate the desulfurization kinetics of paper sludge and limestone in a fluidized bed reactor according to bed temperature and air velocity. The experimental results were presented as follows ; First, the bed temperature had a great influence on the desulfurization efficiency of limestone and paper sludge. In paper sludge, the optimum condition in desulfurization temperature was at 80$0^{\circ}C$ and in limestone, that was at 850 $^{\circ}C$ or 900 $^{\circ}C$ Second, as air velocity increased, the desulfurization efficiency(or the absorbed amount of sulfur dioxide) by limestone and paper sludge decreased. And the absorbed amount of sulfur dioxide by paper sludge was larger than that of by limestone. Third, as the velocity increased and the optimum desulfurization temperature became, ks and the removal efficiency increased. So, ks, kd highly depended on the air velocity and bed temperature.