• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.3
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• pp.207-215
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• 2015

In the last decade, increasing national research fund for recycling the waste FRP (fiber reinforced plastics) ships which has caused environmental problems, improves the technology making concrete-reinforcing fibers out of the waste FRP. Furthermore, the concrete with recycled FRP fiber was tested for the structural performance. Experimental strength tests show that use of recycled FRP powder does not reduce the compressive strength of high strength concrete, and does increase the fire resistance performance of high strength concrete significantly. But, the study in investigating the properties of recycled fiber powder from waste FRP has not been completed because of the absence of the method of separation of mat layer from the waste FRP. This study is to propose a new extracting method of the mat layer from waste FRP, which is the efficient and environment friendly system. and thus it is considered to be the useful recycling method for fire resistance high concrete products or structures.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.46-51
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• 2014

Increasing of waste FRP (fiber reinforced plastics) has caused environmental problems. Recently, the technology of making fibers from waste FRP, which can be used to reinforce the concrete, was developed and the reinforced concretes were tested to study the structural performance. The purpose of this study is to investigate the effect of the powder, obtained together with F-fiber from the waste FRP, on the compressive strength and the fire resistance performance as in the high strength concrete. Strength tests show that the use of recycled FRP powder does not reduce the compressive strength of high strength concrete if the volume fraction of FRP powder is less than 0.7%. Electric furnace test results also show that the use of recycled FRP powder may increase the fire resistance performance of high strength concrete significantly.

• Journal of the Society of Naval Architects of Korea
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• v.41 no.1
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• pp.82-87
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• 2004

The purpose of this paper is to obtain the data for manufacturing of microbe carriers as a method of FRP waste recycling technology. Since FRP waste is polymer, the experiment of the thermogravity analyzing was carried out to find thermal behavior. After that, microbe carriers were prepared from waste FRP powder, which had been decomposed, milled, and mixed with clay as a binder and CaCO3 as a flux and a loaming agent, respectively. finally it was made by filing of the sample up to 1,05$0^{\circ}C$. It was investigated how the variation of the additives and firing temperature effect apparent density, water absorption and micro structure.

• Applied Chemistry for Engineering
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• v.21 no.2
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• pp.217-223
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• 2010

In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.1
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• pp.50-54
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• 2008

There are several basic classes of recycling methods for FRP boats. The main one is 'Mechanical recycling' which involves shredding and grinding of the scrap FRP in a new product. That is one of the simpler and more technically proven methods. It recently has been reported that FRP can be recycled by separating into layers instead of crushing into powder. Many researchers should be more interested in these mechanical recycling for the eligibility. Nevertheless, because resins is very useful renewable energy, most of waste FRP regenerating methods depend on incineration (reclamation) or thermal recycling (pyrolysis). FRP is made up of laminated glass- fiber (roving cloth layer) which is also very unlikely to break into each layer. If there is an extracting method which is efficient and environment friendly removing glass fiber from waste FRP, it should also solve the another urgent problem. Laminated glass-fiber which is very limited renewable, is a serious barrier to wast FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly waste FRP regenerating system. And it should be applied to renewable energy applications with the waste resins of FRP. Also recycling glass fiber obtained by the separation of the roving layer from waste FRP will be consider to be useful for concrete products or structures.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.1
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• pp.23-28
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• 2009

There is several ways of recycling methods for waste FRP boats. The main one is mechanical recycling that is one of the simple and technically proven methods. It recently has been reported that FRP can be recycled by separating into laminated glass fiber layers instead of crushing into powder. Even though the mechanical recycling is a good way for the eligibility of laminated glass fiber reinforced material, the system should have another option which can collect resin of FRP. Because the resin is still very useful renewable energy source, that cannot be discarded, But FRP is made up of laminated glass fiber(roving cloth layer) which is fire retardant substances and very hard to break into each layer. Due to the high cost of fossil energy the waste plastics should be regenerated to the source of renewable energy. Laminated glass fiber which is recyclable in a very limited way, is currently a serious barrier to waste FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly FRP waste regenerating system. The recycled glass fiber which is obtained by the separation of the roving layer from FRP waste has been found to be useful for concrete(FRC) products or concrete(FRC) structures as fiber reinforced material. And it can be successively applied to renewable energy applications using the waste resins of FRP residue without laminated glass fiber.

• Polymer(Korea)
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• v.24 no.6
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• pp.829-836
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• 2000

In order to recyle the FRP waste from SMC bathtubs and rock-crush sludge obtained as a byproduct of stones, the composite consisting of the FRP and rock-crush sludge and the unsaturated polyester matrix resin were prepared. To enhance the interfacial bonding force between the reinforcements and the matrix resin, the rock-crush sludge was treated with silane coupling agent, ${\gamma}$-methacryloxypropyltrimethoxysilane (${\gamma}$-MPS) and their mechanical properties and interface phenomena were examined. The flexural modulus of the composite containing 10 wt% rock-crush powder treated with 3 wt% silane coupling agent showed the maximum value. And also the initial thermal degradation temperature of composites were in the range of 352~359$^{\circ}C$. From these results, we observed that the weight loss of composites was almost constant regardless of the concentration of silane coupling agent. It is confirmed that the interface of the composites containing filler treated with ${\gamma}$-MPS was improved in that there were no pull-out phenomena between the reinforcement and matrix resin.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.1
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• pp.42-45
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• 2008

It has been reported that FRP (fiber reinforced plastic) can be recycled by separating into layers instead of crushing into powder. F-fiber obtained from roving layer separated from FRP, has bigger tensile strength than the bundle of glass fibers of which FRP was made (more than 90%). SEM image of F-fiber shows the presence of some resin. Under the proposition of usage of F-fiber in the concrete material, tensile strength is examined after soaking in a basic solution (NaOH+KOH). The reaction mechanism of strength loss may be considered as an attack of hydroxide ion ($OH^-$) on a chemical bond of Si-O-Si of glass fiber. The simulation graph of the strength loss data implies certain reaction mechanism. While in the early stage kinetically controlled reaction results in a fast drop of tensile strength, after 30 days dispersion rate of hydroxide ion plays a major role in strength loss. This result is similar to the one for the AR glass. An extrapolation of the graph would make an assumption about the lift time of F-fiber possible.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.6
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• pp.646-652
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• 2014

Data of pollution incidents which occurred in shipyards of South Korea for 10 years from 2004 to 2013 were collected and analyzed in order to propose the plans for the prevention of pollution incidents in shipyards. Total number of pollution incidents in shipyards was 103 cases over the nation of Korea for the recent 10 years and the average annual number was about 10 cases, and annual cases tended to increase from 8 cases in 2004 to 23 cases in 2010 and then to decrease to 9 cases in 2013. The location data of pollution incidents showed 32 cases in Busan metropolitan city (31%), 30 cases in Jeonnam (29%), 21 cases in Gyeongam (21%), 5 cases in Jeju (5%), 4 cases in Gangwon (4%), 4 cases in Gyeongbuk (4%), 3 cases in Chungnam (3%) and 3 cases in Incheon metropolitan city (3%). According to the data of work types of shipyards, 60 cases happened during the work of ship repair (58%), 25 cases during the work of ship breakup (24%), 10 cases in the course of ship building (10%) and 8 cases by others (8%). The data of pollutant type showed oil and oily mixtures to be 59 cases (57%), waste paint dust to be 22 cases (21%), iron dust and welding slag to be 13 cases (13%), wastes to be 4 cases (4%), waste FRP powder to be 3 cases (3%), and others to be 2 cases (2%). The plans for the prevention of pollution incidents in shipyards of Korea were proposed as follows; (1) Observance of the related laws and regulations, (2) Establishment and implementation of action plans to prevent areas dense with shipyards from causing pollution incidents, (3) Establishment and implementation of oil pollution prevention plans in shipyards, especially during the ship repair and breakup works, (4) Preparation of measures to solve civil complaints against pollution incidents in shipyards, and (5) Improvement in national management for the control of shipyards.