• Title/Summary/Keyword: Wall Impedance

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A Sensing of Glucose Solution and Diabetic Serum using Polypyrrole Nanotubules Enzyme Electrode Immobilized Glucose Oxidase (포도당 산화효소를 고정화한 Polypyrrole 나노튜뷸 효소전극의 포도당 용액 및 당뇨병 혈청에 대한 감응특성)

  • Kim, Hyun-Cheol;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.6-10
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    • 2001
  • We synthesized polypyrrole (PPy) nanotubules by oxidative polymerization of the pyrrole monomer on the pore of a polycarbonate membrane. The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. The redox potential was about -0.5 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for electro-synthesized PPy film. It is considered as the backbone grows according to the pore wall. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy nanotubules have improved in mass transport, or diffusion. That is because the diffusion occurs through a thin pore wall of PPy nanotubules. The kinetic parameter of PPy nanotubules enzyme electrode with glucose solution was evaluated. The formal Michaelis constant and maximum current calculated by computer were about 23.8 mmol $dm^{-3}$ and $440\;{\mu}A$ respectively. Obviously, an affinity for the substrate and current response of the PPy nanotubules enzyme electrode are rather good, comparing with that of PPy film. What is more, the enzyme electrode is sensitive to blood sugar of a diabetic serum despite an obstruction of ascorbic acid, oxygen, some protein and/or hormone.

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Photocurrent Improvement by Incorporation of Single-Wall Carbon Nanotubes in TiO2 Film of Dye-Sensitized Solar Cells

  • Jung, Kyoung-Hwa;Jang, Song-Rim;Vittal, R.;Kim, Dong-Hwan;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1501-1504
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    • 2003
  • Single-wall carbon nanotubes (SWCN) were integrated in $TiO_2$ film and the beneficial influence on the dyesensitized solar cells in terms of improved photocurrent was studied in the light of static J-V characteristics obtained both under illumination and in the dark, photocurrent transients, IPCE spectra and impedance spectra. Compared with a solar cell without SWCN, it is established that the photocurrent density of the modified cell increases at all applied potentials. The enhanced photocurrent density is correlated with the augmented concentration of electrons in the conduction band of $TiO_2$ and with increased electrical conductivity. Explanations are additionally corroborated with the help of SEM, Raman spectra and dye-desorption measurements.

Hydrodynamic Effect on the Inhibition for the Flow Accelerated Corrosion of an Elbow

  • Zeng, L.;Zhang, G.A.;Guo, X.P.
    • Corrosion Science and Technology
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    • v.16 no.1
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    • pp.23-30
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    • 2017
  • The inhibition effect of thioureido imidazoline inhibitor (TAI) for flow accelerated corrosion (FAC) at different locations for an X65 carbon steel elbow was studied by array electrode and computational fluid dynamics (CFD) simulations. The distribution of the inhibition efficiency measured by electrochemical impedance spectroscopy (EIS) is in good accordance with the distribution of the hydrodynamic parameters at the elbow. The inhibition efficiencies at the outer wall are higher than those at the inner wall meaning that the lower inhibition efficiency is associated with a higher flow velocity, shear stress, and turbulent kinetic energy at the inner wall of the elbow, as well as secondary flow at the elbow rather than the mass transport of inhibitor molecules. Compared to the static condition, the inhibition efficiency of TAI for FAC was relatively low. It is also due to a drastic turbulence flow and high wall shear stress during the FAC test, which prevents the adsorption of inhibitor and/or damages the adsorbed inhibitor film.

The Study on the Mutual Characteristics Between Transmitting Efficiency of Pulse Energy and Wall Plug Consumed Power of Non-Thermal Plasma (저온 플라즈마의 펄스에너지 전송효율과 Wall Plug 소비전력과의 상호 특성에 관한 연구)

  • Jeong, Jong-Han;Jeong, Hyeon-Ju;Kim, Hwi-Yeong;Jeong, Yong-Ho;Song, Geum-Yeong;Kim, Geun-Yong;Kim, Hui-Je
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.10
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    • pp.506-510
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    • 2002
  • In this paper, we study on the mutual characteristics between transmitting efficiency of pulse energy and wall plug consumed power of non-thermal Plasma for removing environmental pollutive gas of coal plant. To obtain high pulse energy of our system, we used MPC(magnetic pulse compressor) of power switch and tested their characteristics by adjusting electrode length of reactor and charging voltage in capacitor. As a result, we obtained consumed power of wall plug and a compressed pulse of voltage 110kV, rising time 500ns. Impedance of load on increasing electrode length was decreased, but electrical efficiency was increased. These results indicate we can control critical voltage of pulse corona and electrical efficiency of economic cost in power plant.

Void Fraction Measurement by the Improved Multi-Channel Impedance Void Meter (개량된 다채널 임피던스형 측정기에 의한 기포율의 측정)

  • Song, Cheol-Hwa;Jeong, Mun-Gi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.1
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    • pp.384-398
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    • 1996
  • An improved multi-channel Impedance Void Meter (IVM) is developed to measure an area-averaged void fraction. It consists of a main sensor, a reference sensor and a signal processor. The sensor was designed to be flush-mounted to the inner wall of the test section to avoid the flow disturbances. Guard electrodes are used to obtain evenly distributed electrical field in a measuring volume. A reference sensor is also installed to eliminate the drift in void signal caused by the changes in electrical properties of working fluid. The signal processor with three channels is specially designed so as to minimize the inherent error due to the phase difference between channels. As an example of applications, the mean and fluctuating components of void fraction are measured for bubbly and slug flow regime, and it is shown that IVM has good dynamic resolution which is required to investigate the structural developments of bubbly flow and the propagation of void waves in a flow channel.

Experimental Results on the Energy-bounding Approach to Robustly Stable Rate-mode Bilateral Teleoperation Systems (속도 모드 양방향 원격 제어의 안정화 에너지 제한 방법의 실험 결과)

  • Park, Sung-Jun;Seo, Chang-Hoon;Ryu, Je-Ha
    • Journal of Institute of Control, Robotics and Systems
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    • v.17 no.6
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    • pp.552-557
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    • 2011
  • This paper presents experimental results on the energy-bounding approach to a rate-mode bilateral teleoperation control that can guarantee the robust system stability in variable time-delayed telecommunication environments. Previously, rate-mode energy bounding approach [15] was proposed and verified with experimental results using the simulated remote slave model. In this paper, a real experimental setup using an industrial robot (Denso) as a remote slave robot composed and conducted similar experiments with previous paper. In order to guarantee stability of the Denso when contacting with high impedance wall, velocity based impedance control modified by position based is used. Experimental results show that the rate-mode energy bounding approach can guarantee stable bilateral teleoperation system in the free and contact motion with variable time delay.

A Study on the Fluid Flow by Change of Pressure & Flow in the Collapsible Tube (압출관에서의 압력 및 유형변화에 따른 유체유동에 관한 연구)

  • Kim, Jong-Eok;Lee, Han-Yeong;Hong, Gi-Bae
    • Journal of Biomedical Engineering Research
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    • v.5 no.1
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    • pp.47-54
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    • 1984
  • In order to research the flow in the thin wall compliant tube, this present study is attempt to measure the cross sectional area according to change of external pressure and flow by ultrasonic method different from willy used impedance technique for flow analysis about one dimensional Steads flow. The experimental results are as follows. 1) Measurement of cross sectional area ratio by ultrasonic method by comparison with experimental results of impedance technique & theoretical results were well consent. 2) Pressure difference of upstream and down stream is alwap's maximum range at 0.4 < $\alpha$ <0.5, and have no connection with changing external pressure. 3) when the external pressure is fixed and resistance is varied, Self excited oscillation occurs in the region at 0.5 < $\alpha$ <0.6, and oscillation disappear almost at R2>=1.2

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Degradation of Epoxy Coating due to Aging Acceleration Effects

  • Nah, Hwan Seon;Lee, Chul Woo;Suh, Yong Pyo
    • Corrosion Science and Technology
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    • v.5 no.3
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    • pp.99-105
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    • 2006
  • This paper is to investigate feasibility on quantitative aging state of epoxy coating on concrete wall in containment structure under operation of nuclear power plants. For evaluating the physical characteristics of the epoxy coating, adhesion strengths of two kinds of degraded epoxy coating systems on both steel surfaces and concrete surfaces were measured via accelerated aging. Comparatively impedance data taken by ultrasonic test were also taken to relate with adhesion data. After aging, in case of concrete, from half of specimens, aging of epoxy coating was developed. As for steel, on $4^{th}$ inspection day, adhesion force was failed. To improve reliability on quality degradation of epoxy, relationship between adhesion and impedance was analyzed. By tracing to co-respond to these data, it was possible to Fig. out physical state of as-built epoxy coating. The possibility to develop new methodology of time - dependent aging state on epoxy coating was found and discussed.

Measurement of Acoustic Properties and Prediction of Acoustic Performance of Porous Woven Hoses for Engine Intake Systems (엔진 흡기계에 쓰이는 다공형 직조관의 음향특성 측정 및 성능예측)

  • Park, C.M.;Ih, J.G.;Nakayama, Y.;Kitahara, S.;Takao, H.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.182-186
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    • 2000
  • The porous woven hose is recently considered as an effective element of automotive intake systems. In order to predict the acoustic performance of an intake system with a porous woven hose, the information on the acoustic wall impedance is required. In this article, a measurement technique that is valid over the low frequency range and without mean flow condition is presented. The measurement is performed in a cylindrical chamber with a concentric layout of the sample and the resistance is estimated from measured reactance and transmission loss data. It is observed that the measured transmission loss for a porous woven hose with an arbitrary length agrees well with the predicted one that uses the estimated impedance for a small sample length.

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Acoustic resonance and refrigerating capability of a Hofler type thermoacoustic refrigerating system (Hofler 타입 열음향 냉장시스템의 공진특성과 냉장성능)

  • Hah, Zae-Gyoo
    • The Journal of the Acoustical Society of Korea
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    • v.16 no.1
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    • pp.76-80
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    • 1997
  • Acoustic resonance characteristics were analyzed and their effect on the refrigerating capability were experimentally verified on a fabricated Hofler-type thermoacoustic refrigerating system. Factors governing the overall resonance are the resonator composed of a cavity and two pipes, the loudspeaker driving the resonator, and rear side impedance characteristics of speaker housing. All these are coupled with electric constants of the speaker to exhibit electric resonance. Also the 'wall-effect' within the resonator causes attenuation to reduce the sharpness of the resonance. Analysis and experiments showed housing and the wall-effect of the resonator reduce the sharpness of resonance. Maintaining the accuracy of the resonance is, therefore, very important for efficient refrigeration.

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