• Title/Summary/Keyword: WO3

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Removal of NOx from Graphene based Photocatalyst Ceramic Filter (그래핀 기반 광촉매 담지 세라믹필터에서 질소산화물(NOx)의 제거)

  • Kim, Yong-Seok;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.600-605
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    • 2022
  • In this study, nitrogen oxide (NOx) removal experiments were performed using a graphene based ceramic filter coated with a V2O5-WO3-TiO2 catalyst. Graphene oxide (GO) was prepared by Hummer's method using graphite, and the reduced graphene oxide was produced by reducing with hydrazine (N2H4). Vanadium (V), Tungsten (W), and Titanium (Ti) were coated by the sol-gel method, and then a metal oxide-supported filter was prepared through a calcination process at 350 ℃. A NOx removal efficiency test was performed for the catalytic ceramic filters with UV light in a humid condition. When graphene oxide (GO) and reduced graphene oxide (rGO) were present on the filter, the NOx removal efficiency was superior to that of the conventional ceramic filter. Most likely, this is due to an improvement in the adsorption properties of NOx molecules on graphene coated surfaces. As the concentration of graphene increased, higher NOx removal efficiency was confirmed.

Optical Hydrogen Sensor Based on Gasochromic $RuO_2{\cdot}xH_2O$ Thin Film ($RuO_2{\cdot}xH_2O$ 박막의 가스채색 현상을 이용한 수소검지 광센서)

  • Cheong, Hyeon-Sik;Jo, Hyun-Chol;Kim, Kyung-Moon
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.1
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    • pp.9-16
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    • 2005
  • We studied the electrochromic properties of hydrated amorphous ruthenium oxide ($RuO_2{\cdot}xH_2O$) thin films using in-situ Raman spectroscopy during electrochemical charging/discharging cycles. We have found that the principal effect of hydrogen insertion into $RuO_2{\cdot}xH_2O$ is reduction of $Ru^{4+}\;to\;Ru^{3+}$, and not formation of new bonds involving hydrogen. We compared the changes in the Raman spectrum of a gasochromic $Pd/RuO_2{\cdot}xH_2O$ film as it is exposed to hydrogen gas with that of electrochemical hydrogen insertion. We tested the changes in the optical transmission of the $Pd/RuO_2{\cdot}xH_2O$ film when exposed to hydrogen gas.

The Impact of Word of Mouth on Customer Perceived Value for the Malaysian Restaurant Industry

  • Oluwafemi, Adebusoye Shedrack;Dastane, Omkar
    • Asian Journal of Business Environment
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    • v.6 no.3
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    • pp.21-31
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    • 2016
  • Purpose - The purpose of this research is to determine the impact of word of mouth on customer perceived value for restaurants in Malaysia. The objectives of this research include determining how word of mouth (WoM) factors - frequency of word of mouth messages, reputation of word of mouth messenger, richness of word of mouth message, dispersion of word of mouth conversations and manner of word of mouth delivery impact customer perceived value in Malaysian restaurant industry. Research Design, Data, and Methodology - The research follows causal / explanatory research method based on quantitative data. A sample of 150 restaurant customers in Kuala Lumpur, Malaysia was selected using convenience sampling technique. Likert scale questionnaire is used to collect data and data is analysed using regression analysis through SPSS 22. Results - The statistical analysis revealed that independent variable 'manner of delivery' significantly and positively impacts customer perceived value for restaurants in Malaysia. Conclusions - To build strong positive customer perception, Malaysian restaurants can enhance word of mouth campaigns' 'manner of delivery' by making them passionate, exciting and with high emotional appeal.

Practical Method for Generating Surface Mesh using Offset Table (기본 오프셋을 이용한 상선의 선체표면 격자계 생성방법)

  • Wo-Joan Kim;Suak-Ho Van
    • Journal of the Society of Naval Architects of Korea
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    • v.36 no.1
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    • pp.61-69
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    • 1999
  • To promote the usability of CFD techniques for the basic hull form design, a hull surface mesh generating program, based on given station offsets and centerline profile, is developed. The new method employs non-uniform parametric splines with predetermined waterline end-shapes of natural spline, normal spline, ellipse, parabola hyperbola, and their combinations. Generated hull surface meshes can be utilized for potential panel method immediately and can be also used as a boundary grid surface for 3-D field grid system. Mesh topology chosen to represent hull surface can be transformed into a rectangle, which he1ps the flow solvers to transform surface meshes for the nonlinear free surface condition or to define the turbulence quantities. To prove the applicability, a container ship with bow and stem bulb is chosen, and the procedures generating hull surface meshes are described.

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The Role of Lattice Oxygen in the Selective Catalytic Reduction of NOx on V2O5/TiO2 Catalysts (V2O5/TiO2 촉매의 선택적 환원촉매반응에서 격자산소의 역할)

  • Ha, Heon-Phil;Choi, Hee-Lack
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.323-328
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    • 2006
  • In situ electrical conductivity measurements on $V_2O_5WO_3/TiO_2$ catalysts were carried out at between 100 and $300^{\circ}C$ under pure oxygen, NO and $NH_3$ to investigate the reaction mechanism for ammonia SCR (selective catalytic reduction) de NOX. The electrical conductivity of catalysts changed irregularly with supply of NO. It was, however, found that the electrical conductivity change with ammonia supply was regular and the increase of electrical conductivity was mainly caused by reduction of the labile surface oxygen. The electrical conductivity change of catalysts showed close relationship with the conversion rate of NOx. Variation of conversion rate in atmosphere without gaseous oxygen also showed that labile lattice oxygen is indispensable in the initial stage of the de NOx reaction. These results suggest that liable lattice oxygen acts decisive role in the de NOx mechanism. They also support that de NOx reaction occurs through the Eley?Rideal type mechanism. The amount of labile oxygen can be estimated from the measurement of electrical conductivity change for catalysts with ammonia supply. This suggests that measurement of the change can be used as a measure of the de NOx performance.

Formation of Coatings on SKD11 Core Mold Steel by Plasma Electrolytic Oxidation (코어금형용강 SKD11의 플라즈마 전해산화에 의한 피막 형성)

  • Kim, S.M.;Lee, T.H.;Kang, S.J.;Cho, Y.H.;Koo, J.M.
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.4
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    • pp.209-216
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    • 2011
  • Surface coatings were prepared on SKD11 core mold steel by plasma electrolytic oxidation (PEO). The coatings were investigated about the formation condition of core mold steel. SKD11 were coated by PEO in a mix solution of Sodium Aluminate $NaAlO_2$ (10 g/l), Sodium Silicate powder $Na_2SiO_3$ (0.5 g/l), Sodium tungstate dihydrate $Na_2WO_42H_2O$ (0.5 g/l) at less than $30^{\circ}C$. The electrical condition were voltage : 500~600 V; Pulse : 600~1800 Hz; current density 15~20 $A/dm^2$ various time : 3 min~40 min. The coatings surface morphology, cross-section, friction coefficient, hardness were investigated. The PEO coatings on SKD11 core mold steel showed the extended service life.

A Study on the degradation mechanism of PAN-LiCLO$_4$ Polymer Electrolyte EC windows (PAN-LIClO$_4$ 계 고분자전해질 EC창의 열화 기구에 관한 연구)

  • 김용혁;김형선;조원일;조병원;윤경석;박인철
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.223-230
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    • 1997
  • Tungsten oxide and nickel oxide thin films were deposited onto ITO(Indium Tin Oxide) transparent glass by the E-beam evaporation and were used as a cathode and an anode for the EC(Electrochromic) smart window, respectively. Stoichiometric structures of the deposited films were investigated by the implementation of XPS(X-ray Photoelectron Spectroscopy) analysis and the results were $WO_{2.42}$ and $NiO_{0.44}$. This oxygen deficincy might affect affect the transparency of the thin films. The electrolyte for the EC smart windows was PAN-$LiCIO_4$ conducting polymer. EC(Ethylene Carbonate)and PC(Propylene Carbonate) were added as plasticizer to enhance ion conductivity. When the weight ratio of the EC : PC was 3 : 1, transmission difference and cycle life performance were tested. Polymer EC windows showed 40% $\Delta$T at 1.5V operating volage for 3,200 cycles. Structural degradation was observed by the SIMS(Secondary Ion Mass Spectroscopy) analysis and it was confirmed that structural degradation of polymer caused by the solvent evaporation was the main cause to degrade EC smart windows.

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An Experimental Study on the Settling Behavior of Marine Fluid Mud In the West Seaside of Korea (Banweol area) (반월식역 해성토의 침강특성에 관한 실험적 연구)

  • 김수삼
    • Geotechnical Engineering
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    • v.3 no.3
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    • pp.49-62
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    • 1987
  • The settling behavior of marine fluid mud in the west seaside of Korea has been studied with theoretical analysis and experimental technique. This paper describes laboratorial experiments on the sedimentation and the deposition of soil particles in seawater, with measurement of velocity of interface, the water contents, the settlement. And the reseults are compared with an earlier theoretical research, the hindered settling theory of Kynch, McRoberts and Nixon. According to the results the process of Banweol mud sedimentation showed the typical mode of the hindered settling under the condition of initial water content, wo=1000%. Also, the falling rates of fluid mud interface from initial settling height vs. the rising rates of soil deposit from the bottom of the test tub were measured by the function of time, the correlati tranship of them demonstrated as a straight line and obtained an experimental formula.

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Chemical Degradation of Tungsten Oxide Thin Films (텅스텐 산화물 박막의 화학적 퇴화)

  • Lee, Kil-Dong
    • Solar Energy
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    • v.15 no.3
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    • pp.141-149
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    • 1995
  • The tungsten oxide thin films were prepared on $s_i$ wafer by using an electron-beam evaporation technique. Thickness and structure of tungsten oxide film degraded in various electrolytes were analyzed by Rutherford backscattering spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. Thickness of $WO_3$ film was the most dissolved in 1M $H_2SO_4$ electrolytye. We have confirmed that the degradation of this films was accelerated by $H_2O$ in electrolytes. But the electronic structure of film degraded by electrolyte contained of glycerol was not changed as comparision with as-deposited film. The degradation may be attributed to a change of thickness and the surface morphology of the film.

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Fabrication and characterization of a small-sized gas identification instrument for detecting LPG/LNG and CO gases

  • Lee Kyu-Chung;Hur Chang-Wu
    • Journal of information and communication convergence engineering
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    • v.4 no.1
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    • pp.18-22
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    • 2006
  • A small-sized gas identification system has been fabricated and characterized using an integrated gas sensor array and artificial neural-network. The sensor array consists of four thick-film oxide semiconductor gas sensors whose sensing layers are $In_{2}O_{3}-Sb_{2}O_{5}-Pd-doped\;SnO_2$ + Pd-coated layer, $La_{2}O_{5}-PdCl_{2}-doped\;SnO_2,\;WO_{3}-doped\;SnO_{2}$ + Pt-coated layer and $ThO_{2}-V_{2}O_{5}-PdCl_{2}\;doped\;SnO_{2}$. The small-sized gas identification instrument is composed of a GMS 81504 containing an internal ROM (4k bytes), a RAM (128 bytes) and four-channel AD converter as MPU, LEDs for displaying alarm conditions for three gases (liquefied petroleum gas: LPG, liquefied natural gas: LNG and carbon monoxide: CO) and interface circuits for them. The instrument has been used to identify alarm conditions for three gases among the real circumstances and the identification has been successfully demonstrated.