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Sol-Gel 법으로 제작된 정공 수송층과 결합한 유기 태양전지 특성 연구

  • Lee, Se-Han;Choe, Jeol-Jun;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.453-453
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    • 2013
  • 유기 태양전지는 저비용으로 제작이 가능하고 제작이 용이한 장점을 가지고 있으므로 많은 그룹에서 관심을 가지고 있다. 정공 수송층으로 사용되는 PEDOT:PSS는 많이 사용되지만 강한 산성 특성 때문에 ITO 전극에 식각이 되므로 문제가 있다. 그러므로 산화물 반도체 $WO_3$, $MoO_3$, 그리고 $V_2O_3$ 등이 태양전지에 많이 만들어지고 있다. 특히 copper oxide는 높은 광흡수율을 가지고 있으므로 태양전지에 사용하는 데 많은 기대되는 물질이다. Copper oxide 박막은 열증착 법, 스프레이 필로시스, 전기화학 증착, 화학증착법, 그리고 솔-젤법 등 다양한 증착 방법이 있다. 넓은 면적의 소자를 제작할 경우 솔-젤 방법은 기존의 증착법에 비해 낮은 비용으로 제작, 높은 성장율, 그리고 높은 기계적 탄력성의 장점이 있다. 솔-젤법으로 만든 copper oxide는 P3HT의 HOMO (high occupied molecular orbital)와 비슷한 위치에 접하고 있으므로 정공수송층으로 적합하다. 본 연구에서 제작된 태양전지의 구조는 ITO/P3HT:PCBM/CuxO로 구성되어 있다. ITO가 $10{\Omega}$/sq의비저항을 가지고 있었고 UV 처리를 하였다. 그 위에 P3HT:PCBM (1:0.8 weight)를 스핀 코팅하였다. 마지막으로 0.1 M $Cu_xO$용액은 Cu (II) acetate monohydrate를 소스로 2-methoxyethanol ($C_3H_8O_2$)의 용제와 안정제로 monoethanolamine ($C_2H_7NO$)을 섞어서 만들었다. 그리고 P3HT:PCBM 위에 스핀 코팅하였고 열증착 방법으로 전극인 Ag 을 증착하여 최종 소자를 만들었다. Cu(II) acetate의 소스로 제작된 박막의 투과율 측정을 통해 에너지 밴드갭을 구할 수 있었다. Copper oxide 박막은 다결정구조 이므로 다중 밴드갭으로 구성되어지는 것을 알 수 있었다. 최종적으로 만들어진 소자를 열처리를 통해 소자 특성을 조사했더니 250도에서 가장 좋은 결과를 얻을 수 있었다.

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Development of Neutaribeosut Varieties (Pleurotus ostreatus) Chongpung, Myongwol

  • Lee, He-Duck;Kim, Hong-Kyu;Kim, Young-Gyun;Han, Kyu-Heng;Min, Kwang-Ho;Jeong, Tae-Wo;Lee, Jae-Jung;Jeon, Tae-Sun;Kim, Duck-wan;Kim, Hun-Sick;Han, Jong-Ku
    • Plant Resources
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    • v.3 no.2
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    • pp.105-109
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    • 2000
  • This study was carried out to find a useful mushroom at Chungnam Agricultural Research And Extention Service. Twenty materials used were collected from domestic and exotic area. These races were compared bontanical characteristics to leading varieties by PCR-RAPD methods. Mycelial growth temperature of Chongpung and Myongwol were at 20 to 25 $^{\circ}C$ and 25 to 30 $^{\circ}C$ at PDA medium, respectively mycelial growth of these varieties were similiar at pH 6.5 to 7.5. In case of mushroom cultivation temperature ranges, Chongpung was at 5 to 26$^{\circ}C$ and Myongwol was at 7 to 28$^{\circ}C$, but the optimum temperature range of these were appeared at 15 to 19$^{\circ}C$. Culture temperature of these was 23$^{\circ}C$ and period of mycelial culture was needed 23 to 24 days under 850cc/pp, while was needed 11 to 12 days at waste cotton medium. Cap color of these at first inducing mushroom was all dark blue, but at late growing stages Chongpung was shown as grey, and Myongwol was shown as dark grey. Yield of Chongpung was appeared as 46kg/3.3$m^2$ and that of Myongwol was 41kg /3.3$m^2$, while Chunchu No2 as check was 40kg/3.3$m^2$. Results from PDA medium and PCR-RAPD analysis two of these were different from others.

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A Comparative Study on Topic Modeling of LDA, Top2Vec, and BERTopic Models Using LIS Journals in WoS (LDA, Top2Vec, BERTopic 모형의 토픽모델링 비교 연구 - 국외 문헌정보학 분야를 중심으로 -)

  • Yong-Gu Lee;SeonWook Kim
    • Journal of the Korean Society for Library and Information Science
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    • v.58 no.1
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    • pp.5-30
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    • 2024
  • The purpose of this study is to extract topics from experimental data using the topic modeling methods(LDA, Top2Vec, and BERTopic) and compare the characteristics and differences between these models. The experimental data consist of 55,442 papers published in 85 academic journals in the field of library and information science, which are indexed in the Web of Science(WoS). The experimental process was as follows: The first topic modeling results were obtained using the default parameters for each model, and the second topic modeling results were obtained by setting the same optimal number of topics for each model. In the first stage of topic modeling, LDA, Top2Vec, and BERTopic models generated significantly different numbers of topics(100, 350, and 550, respectively). Top2Vec and BERTopic models seemed to divide the topics approximately three to five times more finely than the LDA model. There were substantial differences among the models in terms of the average and standard deviation of documents per topic. The LDA model assigned many documents to a relatively small number of topics, while the BERTopic model showed the opposite trend. In the second stage of topic modeling, generating the same 25 topics for all models, the Top2Vec model tended to assign more documents on average per topic and showed small deviations between topics, resulting in even distribution of the 25 topics. When comparing the creation of similar topics between models, LDA and Top2Vec models generated 18 similar topics(72%) out of 25. This high percentage suggests that the Top2Vec model is more similar to the LDA model. For a more comprehensive comparison analysis, expert evaluation is necessary to determine whether the documents assigned to each topic in the topic modeling results are thematically accurate.

The Results of Drilling in Weondong Mine Area, the Taebaegsan Mineralized District, Republic of Korea (강원도 태백산지역 원동광산 시추탐사연구)

  • Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.44 no.4
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    • pp.313-320
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    • 2011
  • The Taebaegsan Mineralized District is the most prospective region for the useful mineral commodities such as a coal, non-metallic, metallic mineral in South Korea. From a general point of view, Cambro- Ordovician limestone formations, Myobong slate and Pungchon (Daegi) limestone, are the most fertilizable formations in the Taebaegsan Mineralized District. The geology around Weondong mine area consists mainly of Carboniferous-Triassic formations and Cambro-Ordovician formations intruded by rhyolite/quartz porphyry. The great overthrusted fault of N40~$50^{\circ}E$ direction, so called Weondong overthrust fault, is observed in the central part of the mine area and the NS fault system cuts the overthrusted fault. By postulating from the favorable geological and structural condition around Weondong area, the possibility of deep seated hidden ore bodies is expected. In 2010, on the basis of the results of LOTEM and CSAMT survey, the cross-hole survey was performed for the investigation of the hidden polymetallic ore body in the deep parts of the Weondong mine area and the grade of the newly-discovered orebody is as follows; (1) The cut-off grade for lead-zinc 3%; an weighted average grade 5.50% (2.7 m), (2) The cutoff grade for copper 0.1%; an weighted average grade 0.91% (14.65 m), (3) The cut-off grade for iron 30%; an weighted average grade 38.18% (3.3 m), (4) $WO_3$ for each cut-off grade(0.01%, 0.05%, 0.1%); an weighted average grade 0.29 wt. % (8.8 m), 1.15 wt. % (2.1 m), 1.97 wt. % (1.2 m), (5) $MoS_2$ for each cut-off grade(0.01%, 0.1%); an weighted average grade 0.15 wt. % (6.3S m), 0.28 wt. % (3.15 m), (6) $Ta_2O_5$ for each cut-off grade (0.01%, 0.1%); an weighted average grade 0.13% (19.S m), 1.11% (1.8 m), (7) $Nb_2O_5$ for each cut-offgrade (0.01%, 0.1%); an weighted average grade 0.06% 11.5 m), 0.15% (3.0 m).

The Degradation Patterns of Benzimidazole Pesticides in Korean Lettuce by Cultivation (시설재배 상추에서 Benzimidazole계 농약의 분해특성)

  • Kim, Jong-Pil;Seo, Jung-Mi;Lee, Hyang-Hee;Oh, Mu-Sul;Ha, Dong-Ryong;Shin, Hyeon-Wo;Kim, Eun-Sun
    • Journal of Food Hygiene and Safety
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    • v.23 no.2
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    • pp.129-136
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    • 2008
  • Three benzimidazole pesticides commonly used in korean lettuce were subjected to a field residue trial to ensure safety of terminal residue in the harvest. The residual patterns of three benzimidazole pesticides, which were carbendazim, benomyl and thiophanate-methyl were examined after applying with the recommended dose in two types of korean lettuce (Chima and Chuckmeon) and their DT50 were calculated. In Chima lettuce, biological half-lives of carbendazim, benomyl and thiophanate-methyl were 2.56, 1.37 and 2.54 days, respectively and their required time under MRL(5.0 mg/kg as carbendazim) were 4.5, 2.2 and 1.0days. In Chuckmeon lettuce, biological half-lives of them were 3.41, 1.70 and 4.20 days, respectively and their required time under MRL were 5.4, 1.9 and 0.5days.

Taxonomic Position of Korean Isolates of Rhizoctonia solani Based on RAPD and ITS Sequencing of Ribosomal DNA

  • Jeon, Young-Ah;Kim, Wan-Gyu;Kim, Dae-Ho;Kwon, Soon-Wo;Hong, Seung-Beom
    • The Plant Pathology Journal
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    • v.26 no.1
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    • pp.83-89
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    • 2010
  • Taxonomic position of 46 Korean isolates of Rhizoctonia solani which were classified into nine intraspecific groups by anastomosis and cultural characteristics was analyzed by randomly amplified polymorphic DNA (RAPD) and sequence analyses of the internal transcribed spacer (ITS) regions of ribosomal DNA. All the isolates within each group showed highly similar band patterns in RAPD. The ITS regions of the isolates within the same groups showed a high level of sequence similarity above 96.0% whereas similarities among different groups were below 94.4%. When compared with several reference strains of R. solani from foreign countries, all the Korean isolates were clustered with the foreign isolates belonging to the same groups in the phylogenetic tree. All six Korean strains of AG-4 were identified as HG-1 out of 3 subgroup of AG-4. We discussed taxonomic position of Korean isolates of R. solani and showed that sequence analysis with ITS regions could be a rapid and useful method for identification of intraspecific group of R. solani.

The Characteristics of Solar Thermochemical Methane Reforming using Ferrite-based Metal Oxides (페라이트계 금속산화물을 이용한 태양 열화학 메탄 개질 특성)

  • Cha, Kwang-Seo;Lee, Dong-Hee;Jo, Won-Jun;Lee, Young-Seok;Kim, Young-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.45-48
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    • 2007
  • Thermochemical 2-step methane reforming, involving the reduction of metal oxide with methane to produce syn-gas and the oxidation of the reduced metal oxide with water to produce pure hydrogen, was investigated on ferrite-based metal oxide mediums and $WO_{3}/ZrO_{2}$. Thermochemical 2-step methane reforming were accomplished at 900 $^{\circ}C$(syn-gas production step) and 800 $^{\circ}C$(water-splitting step). In syn-gas production step, it appeared carbon deposition on metal oxides with increasing react ion time. Various mediums showed the different starting point of carbon deposition each other. To minimize the carbon deposition, the reaction time was controlled before the starting point of carbon deposition. As a result, $CO_{x}$ were not evolved in water-splitting step, Among the various metal oxides, $Mn-ferrite/ZrO_{2}$ showed high reactivity, proper $H_{2}/CO$ ratio, high selectivity of undesired $CO_{2}$ and high evolution of $H_{2}$.

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Modeling Method for the Force and Deformation Curve of Energy Absorbing Structures to Consider Initial Collapse Behaviour in Train Crash (열차 충돌에너지 흡수구조의 초기붕괴특성을 고려하기 위한 하중-변형 곡선 모델링 방법)

  • Kim, Joon-Wo;Koo, Jeong-Seo;Lim, Jong-Soon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.3
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    • pp.116-126
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    • 2010
  • The Korean rolling stock safety regulation stipulates that the collision deceleration of a car body should be maintained under average 5g and maximum 7.5g during train collisions. One-dimensional dynamic model of a full rake train, which is made up of nonlinear springs/bars-dampers-masses, is often used to estimate the collision decelerations of car bodies in a basic design stage. By the way, the previous studies have often used some average force-deformation curve for energy absorbing structures in rolling stock. Through this study, we intended to analyse how much the collision deceleration levels are influenced by the initial peak force modeling in the one-dimensional force-deformation curve. The numerical results of the one-dimensional dynamic model for the Korean High-Speed Train show that the initial peak force modeling gives significant effect on the collision deceleration levels. Therefore the peak force modeling of the force-deformation curve should be considered in one-dimensional dynamic model of a full rake train to evaluate the article 16 of the domestic rolling stock safety regulations.

The Odontogenic Keratocysts : A Consideration of the Clinical and Radiologic Features (치성각화낭 : 임상 및 방사선학적 고찰)

  • Lee Ji-Youn;Lee Jang- Yeol;Kim Kee-Deog;Park Chang-Seo
    • Imaging Science in Dentistry
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    • v.30 no.3
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    • pp.199-205
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    • 2000
  • Purpose: To determine whether the significant relationship exists between radiographic appearance, whether it is unilocular or multilocular, and its corresponding clinical and histologic features by examining the odontogenic keratocyst clinically, radiologically and histologically. Materials and Methods: This study was conducted on 48 cases of odontogenic keratocyst from the files of Dental Hospital, Yonsei University for the years 1982 through 1995. Results and Conclusions : The mean age of patients was 30.5 years in the unilocular group and 35.5 years in the multilocular group. The male to female ratio was 1 : 1.06 in the unilocular group and 1 : 1.75 in the multilocular group. The chief complaint was swelling in both groups(unilocular 35.1 %, multilocular 54.5%). In the occurrence site, the border of the lesion, the displacement and external root resorption of the adjacent teeth, there were no statistically significant difference between the unilocular group and multilocular group, but in the border type, there was statistically significant difference (x²-test, p<0.05)wo recurred cases were observed among 11 cases of odontogenic keratocyst. One was unilocular case and the other was multilocular case.

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The Study of Thermal Decomposition of Polyacids by Differential Thermal Analysis: Ammonium Paratungstate (示差熱分析에 依한 Poly 酸의 熱分析의 硏究)

  • YungPil Ahn
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.1-5
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    • 1963
  • The thermal decomposition process of ammonium paratungstate $5(NH_4)_2O{\cdot}12WO_3{\cdot}5H_2O$ was analysed by the methods of thermogravimetric analysis, differential thermal analysis, quantitative analysis of the ammonia which is released during heating and X-ray powder diffraction in air and in vacuo. There are several endothermic peaks which indicate release of ammonia and exothermic peaks which indicate crystal growth and oxidation of decomposed prodects in air. After water is driven off the ammonia is released at intervals corresponding to the endothermic peaks. The highest temperature at which ammonia is released is about $420^{\circ}C$ in air and $480^{\circ}C$ in vacuo. In air the crystal structure of paratungstate is conserved up to a temperature of $300^{\circ}C$ at which the remaining ammonia is about 4 mols. At $320^{\circ}C$ the remaining ammonia becomes less than 2 mols and the paratungstate structure changes into the amorphous state. After that ${\gamma}$ oxide is produced and is oxidized to ${\alpha}$ oxide in the temperature range of 400-$500^{\circ}C$ in air. In vacuo however the endothermic peaks and structural changes occur at lower temperatures and the structure of ${\gamma}$ oxide is conserved up to temperatures higher than $500^{\circ}C$.

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