• Title/Summary/Keyword: WO3

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Fabrication and Characterization of Portable Electronic Nose System for Identification of CO/HC Gases (CO/HC 가스 인식을 위한 소형 전자코 시스템의 제작 및 특성)

  • Hong, Hyung-Ki;Kwon, Chul-Han;Yun, Dong-Hyun;Kim, Seung-Ryeol;Lee, Kyu-Chung;Kim, In-Soo;Sung, Yung-Kwon
    • Journal of Sensor Science and Technology
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    • v.6 no.6
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    • pp.476-482
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    • 1997
  • A portable electronic nose system has been fabricated and characterized using an oxide semiconductor gas sensor array and pattern recognition techniques such as principal component analysis and back-propagation artificial neural network. The sensor array consists of six thick-film gas sensors whose sensing layers are Pd-doped $WO_{3}$, Pt-doped $SnO_{2}$, $TiO_{2}-Sb_{2}O_{5}-Pd$-doped $SnO_{2}$, $TiO_{2}-Sb_{2}O_{5}-Pd$-doped $SnO_{2}$ + Pd coated layer, $Al_{2}O_{3}$-doped ZnO and $PdCl_{2}$-doped $SnO_{2}$. The portable electronic nose system consists of an 16bit Intel 80c196kc as CPU, an EPROM for storing system main program, an EEPROM for containing optimized connection weights of artificial neural network, an LCD for displaying gas concentrations. As an application the system has been used to identify 26 carbon monoxide/hydrocarbon (CO/HC) car exhausting gases in the concentration range of CO 0%/HC 0 ppm to CO 7.6%/HC 400 ppm and the identification has been successfully demonstrated.

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A Study of the Inorganic Scintillator Properties for a Phoswich Detector (Phoswich 검출기 제작을 위한 무기 섬광체 특성 연구)

  • Lee, Woo-Gyo;Kim, Yong-Kyun;Kim, Jong-Kyung;Tarasov, V.;Zelenskaya, O.
    • Journal of Radiation Protection and Research
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    • v.29 no.4
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    • pp.251-256
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    • 2004
  • CsI(Tl), $CdWO_4(CWO),\;Bi_4Ge_3O_{12}(BGO)\;and\;Gd_2SiO_5:Ce(GSO)$ scintillators were studied to manufacture a phoswich detector. The maximum wavelengths of the CsI(Tl), CWO, BGO and GSO scintillators are 550 nm, 475 nm, 490 nm and 440 nm for the radioluminescence, and the absolute light outputs of the CsI(Tl), CWO, BGO and GSO scintillators are 54890 phonon/MeV, 17762 phonon/MeV, 8322 phonon/MeV and 8932 phonon/MeV with a neutral filter, and the decay time of the CsI(Tl), CWO, BGO and GSO scintillators is $1.3{\mu}s,\;8.17{\mu}s$, 213 ns and 37 ns by a single photon method. The phoswich detector which was manufactured with plastic and CsI(Tl) scintillators could separate the ${\beta}$ particle and ${\gamma}$ ray. The phoswich detector could also measure the pulse height spectra of the ${\beta}$ particle and ${\gamma}$ ray by a PSD method.

Recovery of the Vanadium and Tungsten from Spent SCR Catalyst Leach Solutions by Hydrometallurgical Methods (SCR 폐촉매 침출액으로부터 습식제련법에 의한 바나듐, 텅스텐의 회수)

  • Choi, In-Hyeok;Moon, Gyeonghye;Jeon, Jong-Hyuk;Lee, Jin-Young;Jyothi, Rajesh Kumar
    • Resources Recycling
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    • v.29 no.2
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    • pp.62-68
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    • 2020
  • In new millennium, wide-reaching demands for selective catalytic reduction (SCR) catalyst have been increased gradually in new millennium. SCR catalyst can prevent the NOx emission to protect the environment. In SCR catalyst the main composition of the catalyst is typically TiO2 (70~80%), WO3 (7~10%), V2O5 (~1%) and others. When the SCR catalysts are used up and disposed to landfills, it is problematic that those should exist in the landfill site permanently due to their extremely low degradability. A new advanced technology needs to be developed primarily to protect environment and then recover the valuable metals. Hydrometallurgical techniques such as leaching and liquid-liquid extraction was designed and developed for the spent SCR catalyst processing. In a first stage, V and W selectively leached from spent SCR catalyst, then both the metals were processed by liquid-liquid extraction process. Various commercial extractants such as D2EHPA, PC 88A, TBP, Cyanex 272, Aliquat 336 were tested for selective extraction of title metals. Scrubbing and stripping studies were tested and optimized for vanadium and tungsten extraction and possible separation. 3rd phase studies were optimized by using iso-decanol reagent.

Digital Transformation: Using D.N.A.(Data, Network, AI) Keywords Generalized DMR Analysis (디지털 전환: D.N.A.(Data, Network, AI) 키워드를 활용한 토픽 모델링)

  • An, Sehwan;Ko, Kangwook;Kim, Youngmin
    • Knowledge Management Research
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    • v.23 no.3
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    • pp.129-152
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    • 2022
  • As a key infrastructure for digital transformation, the spread of data, network, artificial intelligence (D.N.A.) fields and the emergence of promising industries are laying the groundwork for active digital innovation throughout the economy. In this study, by applying the text mining methodology, major topics were derived by using the abstract, publication year, and research field of the study corresponding to the SCIE, SSCI, and A&HCI indexes of the WoS database as input variables. First, main keywords were identified through TF and TF-IDF analysis based on word appearance frequency, and then topic modeling was performed using g-DMR. With the advantage of the topic model that can utilize various types of variables as meta information, it was possible to properly explore the meaning beyond simply deriving a topic. According to the analysis results, topics such as business intelligence, manufacturing production systems, service value creation, telemedicine, and digital education were identified as major research topics in digital transformation. To summarize the results of topic modeling, 1) research on business intelligence has been actively conducted in all areas after COVID-19, and 2) issues such as intelligent manufacturing solutions and metaverses have emerged in the manufacturing field. It has been confirmed that the topic of production systems is receiving attention once again. Finally, 3) Although the topic itself can be viewed separately in terms of technology and service, it was found that it is undesirable to interpret it separately because a number of studies comprehensively deal with various services applied by combining the relevant technologies.

Mechanical Synthesis and Rapid Consolidation of Nanostructured W-Al2O3 Composite

  • Lee, BooRak;Jeong, GeolChae;Park, GeunO;Shon, In-Jin
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.343-348
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    • 2018
  • Recently, the properties of nanostructured materials as advanced engineering materials have received great attention. These properties include fracture toughness and a high degree of hardness. To hinder grain growth during sintering, it is necessary to fabricate nanostructured materials. In this respect, a high-frequency induction-heated sintering method has been presented as an effective technique for making nanostructured materials at a lower temperature in a very short heating period. Nanopowders of W and $Al_2O_3$ are synthesized from $WO_3$ and Al powders during high-energy ball milling. Highly dense nanostructured $W-Al_2O_3$ composites are made within three minutes by high-frequency induction-heated sintering method and materials are evaluated in terms of hardness, fracture toughness, and microstructure. The hardness and fracture toughness of the composite are $1364kg/mm^2$ and $7.1MPa{\cdot}m^{1/2}$, respectively. Fracture toughness of nanostructured $W-Al_2O_3$ is higher than that of monolithic $Al_2O_3$. The hardness of this composite is higher than that of monolithic W.

Thermal Performance Evaluations of Tungsten/Yttria as Nozzle Throat Insert Material for Long Duration Firing (장시간 연소 텅스텐/이트리아 노즐목 삽입재의 내열성능 평가)

  • Kang, Yoon-Goo;Park, Jong-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.2
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    • pp.200-205
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    • 2010
  • Heat-resistance of W/$Y_2O_3$ as throat insert material was evaluated to develop rocket motor keeping thrust uniformly under condition of high-temperature, high-pressure and long-burn time. Test was conducted with varying burn time, and test results were compared with CIT. Test showed that ablation rate was decreased according as burn time was increased, and that ablation rate of W/$Y_2O_3$ was about 55 % of CIT. Macro/micro structures of throat insert did not show a peculiar phenomenon by increased burn time. In addition, the vacuum heat treatment is effective for the prevention of crack in throat insert.

Characterization of Oxide Scales Formed on TiAl-W-Zr Alloys (TiAl-W-Zr 합금에 생성된 고온산화막 분석)

  • Woo Sung-Wook;Lee Dong-Bok
    • Korean Journal of Materials Research
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    • v.14 no.6
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    • pp.394-398
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    • 2004
  • A Ti47Al1.7W-3.7Zr alloy was oxidized between $900^{\circ}C$ and $1050^{\circ}C$, and the oxide scales formed were studied. The oxide scales consisted primarily of an outer$TiO_2$ layer, an intermediate $Al_2$$O_3$-rich layer, and an inner mixed ($TiO _2$ + $Al_2$$O_3$) layer. Besides $TiO_2$ and $Al_2$$O_3$, oxidation led to the formation of some $Ti_2$AlN and TiN. Both W and Zr were preferentially segregated below the intermediate $Al_2$$O_3$-rich layer. Tungsten in the oxide scale was present as $WO_3$ and ${Ti}_{x}$$W_{1-x}$, whereas zirconium as monoclic-$ZrO_2$ and tetragonal-$ZrO_2$.

A Study on the Optical Bench for LEO Earth Observation Satellite (저궤도 지구관측위성의 광학탑재체 지지구조물 설계 연구)

  • Kim, Kyung-Won;Kim, Jin-Hee;Rhee, Ju-Hun;Jin, Ik-Min;Kim, Jong-Wo
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.805-808
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    • 2005
  • This paper is a study on an optical bench satisfying stiffness and thermal pointing error requirements for LEO earth observation satellite. According to shape and stiffness requirements, optical bench type 1 is designed. Because type 1 does not satisfy the thermal pointing error requirement, an optical bench type 2 is suggested. Although the type 2 has better results than type 1, it still does not meet the thermal pointing error requirement. Using the results of optical bench type 1&2, the optical bench type 3 is finally designed, which satisfies both the stiffness and thermal pointing error requirements.

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Microstructure of W-Cu Composite Powders with Variation of Milling Method during Mechanochemical Process (기계화학적 공정의 밀링 방법에 따른 W-Cu 복합분말의 미세조직)

  • 이강원;김길수;김대건;김영도
    • Journal of Powder Materials
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    • v.9 no.5
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    • pp.329-335
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    • 2002
  • Recently, the fabrication process of the W-Cu nanocomposite powders has been studied to improve the sinterability through the mechanical alloying and reduction of W and Cu oxide mixtures. In this study. the W-Cu composites were produced by mechanochemical process (MCP) using $WO_3-CuO$ mixtures with two different milling types of low and high energy, respectively. These ball-milled mixtures were reduced in $H_2$ atmosphere. The ball-milled and reduced powders were analyzed through XRD, SEM and TEM. The fine W-Cu powder could be obtained by the high energy ball-milling (HM) compared with the large Cu-cored structure powder by the low energy ball-milling (LM). After the HM for 20h, the W grain size of the reduced W-Cu powder was about 20-30 nm.

Developement of Electrochromic Mirror for Automobiles (자동차용 Electrochromic Mirror의 개발)

  • 서동규;김영호;조봉희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.336-339
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    • 1995
  • There has been considerable interest in electrochromic devices because of its potential application in automobiles including mirrors and windows. The electrochromic(EC) mirror can automatically control the amount of glare produced by headlights or other light source on either inside or outside mirrors. Therefore, the EC mirror can be a better alternative to todays day-night mirrors for automobiles. In this paper we have fabricated all solid state EC mirrors with glass-ITO / a-WO$_3$/ polymer electrolyte / a-V$_2$O$\sub$5/ / ITO-glass / Al structure and investigated their spectral reflectance as a function of applied voltage.

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